• Title/Summary/Keyword: Solution viscosity

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Use of Cationic PAM as a Surface Sizing Additive to Improve Paper Properties

  • Seo, Man-Seok;Lee, Hak-Lae;Youn, Hye-Jung
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.245-250
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    • 2006
  • This study was focused on the use of cationic PAM (Polyacrylamide) as a surface sizing additive to improve the surface sizing properties of paper. Effects of the ionic property, viscosity and charge density of PAM on bending stiffness of surface sized papers were investigated. Use of cationic PAM as a surface sizing additive improved bending stiffness while addition of anionic PAM did not show any effect. Increase of starch holdout with the addition of cationic PAM was attributed as a prime reason of stiffness increase. Viscosity of PAM was one of the most important factors affecting surface sizing due to its influence on the interaction between cationic PAM and oxidized starch solution. Greater improvement of bending stiffness of paper was obtained when high charged PAM was used as an additive. The order of addition was found to have significant influence on the effect of additives since it influences the formation of network structure among starch, cationic PAM, and SA (styrene acrylic acid copolymer). Investigation on the penetration of starch solution was carried out with CLSM (Confocal Laser Scanning Microscopy), and it was shown that the addition of cationic PAM to oxidized starch solution made starch molecules stay on the paper surface rather than penetrating into the paper structure because of the electrostatic interaction between negatively charged fibers and positively charged cationic PAM.

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A Study on fabrication of the Ag fine pattern using Near Field Electro Spinning(NFES) (근접장 전기방사 방식을 이용한 Ag 미세 패턴 형성)

  • Sim, Hyo-Sun;Seo, Hwa-Il;Youn, Doo-Hyeb
    • Journal of the Semiconductor & Display Technology
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    • v.10 no.4
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    • pp.65-70
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    • 2011
  • These days, printed electronics attract attention from electronics industry. In this paper, the fabrication of the fine patterns by Near Field Electro Spinning (NFES) was studied by using Ag ink on silicon wafer (substrate). Two types of ink, the high viscous ink Ag-200 and low viscous ink Ag-15, were used. The fine and uniform patterns were easily fabricated by using Ag-200 because jet breakup is less occurred in high viscosity solution. As increasing flow rate of solution, aspect ratio of Ag pattern decreased. And there was optimum applied voltage for fine pattern. In case of Ag-200, the optimum applied voltage was about 2.02KV. When pattern was fabricated by NFES, the pattern width and height were affected by many factors such as viscosity, flow rate of solution, applied voltage etc.

The Effects of the Heat-set web Ink Emulsification on Printability (Heat-set 윤전 잉크의 유화가 인쇄 적성에 미치는 영향)

  • Ha, Young-Baeck;Choi, Jae-Hyuk;Lee, Won-Jae;Oh, Sung-Sang
    • Journal of the Korean Graphic Arts Communication Society
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    • v.28 no.2
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    • pp.31-44
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    • 2010
  • Ever since the introduction of offset lithography, an operator have looked for ways to improve the process by reducing need for dampening solution. Lithography like off-set printing is processed using the repellent properties between water and oil, so all inks for lithography printing must work with dampening solution. The dampening solution may cause the emulsification of ink by the printing pressure in the printing nip. Emulsified ink changed viscosity, tack and causes problems such as bad transfer, uniform density and printed mottle. For a high quality web printing, we studied the effect of emulsified heat-set web inks on the printability, such as amount of ink transfer, printed density and uniformity. For this study, we were carried out by using IGT printability tester C1. For determination of ink properties using the spread meter and Thwing Albert Ink-o-meter, and using the densitometer and image analysis for printed quality determination. The experimental results of this study, we look forward to can be used as the basis for improve of the web print quality.

Characteristics of Non-ionic Micellar and O/W Microemulsion Systems and Solubilization of Sudan IV (비이온성 미셀용액과 수중유형 마이크로에멀젼계의 특성 및 수단 IV의 가용화)

  • 지웅길;황성주;장은옥;현종목
    • YAKHAK HOEJI
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    • v.39 no.5
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    • pp.495-505
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    • 1995
  • The O/W microemulsion systems were made from 2 or 4% (w/w) oil (soybean oil, olive oil or isopropyl myristate) and 10, 15 or 20% (w/w) Brij 96. They were compared with micellar solution of equivalent surfactant concentration m therms of physicochemical properties, and the solubilization of sudan IV. They were characterized by dynamic light scattering, stability, surface tension, viscosity and rheogram. The mean diameters of O/W microemulsion systems were 10-15nm, and those of Brij 96 micellar solutions were 18-19 nm. Both of them were monodisperse systems. The O/W microemulsion systems showed Newtonian flow and their apparent viscosities were lower than those of micellar solutions. The surface tensions of O/W microemulsion systems were increased or decreased depending on the types of oil used, when compared with those of micellar solutions. The O/W microemulsion systems were very stable, and did not show any flocculation or aggregation. Their mean diameters were not changed after three months. But oxidation was observed in microemulsions without nitrogen gas at high temperature. There was a significant improvement in the sudan IV solubffimtion in micromulsion compared with that m the micellar solution containing equivalent concentration of surfactant. The size distribution and mean diameters of O/W micromulsions were not changed when sudan IV was solubilized.

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Effect of Concentration of Carboxymethycellulose on Degradation by Radiation (Carboxymethycellulose의 농도에 따른 방사선 분해 연구)

  • Kim, Jeongsoo;Sung, Nak-Yun;Kim, Jae-Hun;Kim, Tae-woon;Lee, Ju-Woon;Choi, Jong-il
    • Journal of Radiation Industry
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    • v.4 no.4
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    • pp.385-389
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    • 2010
  • In this study, the effect of the concentration of carboxymethylcellulose (CMC) solution on the degradation by irradiation was investigated. The CMC solutions with different concentrations of 3%, 4%, 5%, 6% and 7% were irradiated at the doses of 5, 10, 15, 20, 25 and 30 kGy with gamma ray or electron beam, and the viscosity of CMC solution was measured. The viscosity of the CMC solutions was decreased with an increase in the irradiation dose, but the extent of the degradation by an irradiation was found to be decreased with an increase of the CMC concentration in the solution. The dependency of the irradiation sources showed that an electron beam radiation had degraded the CMC less severely than gamma ray.

Dissolution, crystallilnity, and mechanical properties of silk sericin from Sericinjam silkworm cocoons

  • Yun Yeong Choi;Seong Wan Kim;Kee Young Kim;In Chul Um
    • International Journal of Industrial Entomology and Biomaterials
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    • v.46 no.1
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    • pp.9-15
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    • 2023
  • Recently, a silkworm strain (tentatively named Sericinjam) producing 100% sericin cocoons has been studied in South Korea. In this preliminary study, the crystallinity, mechanical properties, and dissolution conditions of sericin from Sericinjam cocoons were examined. The Sericinjam cocoon could be dissolved in water at high temperature (120℃) and high pressure (HTHP method) in an autoclave and in a CaCl2/H2O/EtOH mixture (ternary solvent method), resulting in 82% and 97% dissolution after 30 min, respectively. The solution viscosity of the silk sericin formic acid (SSFA) solution obtained from sericin extracted using the ternary solvent method was higher than that obtained using the HTHP method; however, SSFA solutions obtained from sericin extracted from conventional Baekokjam cocoons yielded a higher solution viscosity. The crystallinity and breaking strength of the sericin film from Sericinjam cocoons were slightly lower, respectively, than those from Baekokjam cocoons. In contrast, the elongation at break of the Sericinjam sericin film obtained using the HTHP method was higher than that of the Baekokjam sericin film.

Effect of Agitation on Production of Methylan and Rheological Characteristics of Methylan Fermentation Broth (다당류, 메틸란, 발효밴잉액의 점성특성과 메틸란 생산에 미치는 교반속도의 영향)

  • Oh, Deok-Kun;Lim, Hyun-Soo;Kim, Jung-Hoe
    • Applied Biological Chemistry
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    • v.38 no.3
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    • pp.191-195
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    • 1995
  • Production of a high viscosity exoploysaccharide, methylan, by Methylobacterium organophilum from methanol was carried out in fed-batch cultures and the rheological properties of methylan fermentation broth were studied. Bacterial biomass showed little influence on viscosity, but the accumulation of methylan caused the increase of viscosity. With proceeding fermention, the viscosity at the same concentration of methylan was significantly increased and methylan solution showed slightly higher pseudoplasticity. The composition changes of methylan were investigated at various fermentation times. Contents of total sugar, reducing sugar and methylan were decreased but contents of acids(pyruvic acid, uronic acid and acetic acid) were increased with the culture time. It was considered that the increased content of acids resulted in the increase of the hyrodynamic domain in the solution due to charge repulsion. Consequently, the solution viscosity increased in propotion to the acids contents of methylan. Cell growth and methylan production were severely decreased by the limitation of dissolved oxygen. However, the cellular activity for methylan production was almost constant regardless of the level of dissolved oxygen. As a result, the high speed of agitation increased the methylan production, the specific production rate of methylan, and the methylan yield of the cell.

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Identification of Cross-WLF Viscosity Model Parameters Using Optimization Technique (최적화기법을 이용한 Cross-WLF점도 모델 계수 추정)

  • Kim, Sun-Yong;Park, Si-Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.4
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    • pp.623-632
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    • 2018
  • Predicting the behavior of rheological polymers is highly shear rate- and temperature-dependent. The Cross-WLF viscosity model has become a powerful solution that describes the shear rate- and temperature-dependent characteristics. To estimate the behavior of polymers in computational simulations, the coefficients of the Cross-WLF model should be well identified. An identification technique was proposed to determine the Cross-WLF viscosity model coefficient. The assumption is that the Cross-WLF viscosity model well describes the real characteristics of polymers when the calculated viscosity with the parameters is identical to the reference data. In this study, Auto-desk Moldflow data were used as a reference. The numerical examples showed that the proposed method accurately identifies the Cross-WLF viscosity model coefficients.

Effect of Fluid Viscosity on Centrifugal Pump Performance (유체의 점성이 원심펌프 성능에 미치는 영향)

  • Kim, Noh-Hyeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.6
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    • pp.599-605
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    • 2013
  • The characteristics of centrifugal pump performance according to fluid viscosity change were studied experimentally. A small volute pump with low specific speed was tested by changing the viscosity of an aqueous solution of sugar and glycerin, which is considered a Newtonian fluid. After finishing the test, the total head, shaft horsepower, and pump efficiency were compared with those of a water pump. The results are summarized as follows: (1) when the fluid viscosity is increased, the shut-off head shows very little change but the total head decreases gradually as the flow increases, and this makes the H-Q curve leaning rapidly, and (2) when the fluid viscosity is increased, the shaft horsepower shows very little change at the shutoff condition; however, the shaft horsepower increases more rapidly with an increase in the flow and viscosity.

Studies on the Rheology of the Biopolymer produced by Bacillus sp. K-1 Strain and its Mutants (Bacillus sp. K-1과 그의 변이주가 생산하는 Biopolymer의 물성에 관한 연구)

  • Kim, Sung-Ho;Yim, Moo-Hyun;Choung, Nack-Hyun
    • Applied Biological Chemistry
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    • v.39 no.3
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    • pp.165-171
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    • 1996
  • The rheological properties of biopolymers produced by Bacillus sp. K-1 and its mutant strains(KM-21, KM-83) were studied. Apparent viscosity of biopolymers decreased as rising the temperature. The biopolymer produced by KM-21 strain showed 1.7 times low viscosity, 2.7 times low viscosity by K-1 and 1.9 times low viscosity by KM-83 at $80^{\circ}C$ compared with at $20^{\circ}C$ respectively. The viscosity of biopolymer solution also increased with increasing the polymer concentration and showed pseudoplastic characteristics which is high temperature dependency in all concentration. The change of the biopolymer viscosity on the pH showed the highest value at the pH 7.0 and it showed lower at acidic condition than at alkaline condition comparatively.

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