• Corrosion Science and Technology
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• 제17권5호
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• pp.203-210
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• 2018

This paper compares the inhibition properties of aspartic and lactic acid salts with nitrite ions and their effect on critical chloride concentration. The tests were carried employing carbon steel specimens in saturated lime solution with varying pH in the range between13 to 13.6. The critical chloride concentration was estimated through multiple specimen potentiostatic tests at potentials in the usual range for passive rebar in the alkaline concrete of atmospheric structures. During tests, chloride salt was added every 48 h until all the specimens showed localized attacks. The cumulative distribution curves, i.e. the number of corroded specimens as a function of the chlorides concentration was obtained. Furthermore, IR spectra were recorded for the evaluation of the presence of the organic inhibitors on the passivity film. The results confirmed the inhibitory effect of 0.1M aspartate comparable with nitrite ions, at a similar concentration. Addition of calcium lactate did not result in an increase in the critical chloride concentration. However, the formation of a massive scale containing the substance that could reduce the corrosion propagation was observed.

• 공업화학
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• 제20권6호
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• pp.700-704
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• 2009

본 연구에서는 다공성 탄소전극의 내부 전해질 농도에 따른 전극의 전기화학적 특성 변화를 연구하였다. 다공성 탄소전극의 내부를 0.01, 0.05, 0.1, 0.5 M KCl 용액으로 채우고 양이온교환막을 결합한 후 cyclic voltammetry, chronoamperometry, impedance spectroscopy 분석을 실시하였다. 실험결과 전극의 특성은 전극 내부의 전해질 농도에 따라 큰 차이를 보였으며 농도가 높을수록 전극 내부의 charging 저항이 감소하여 전기용량이 크게 증가하는 것을 알 수 있었다. 실험결과로부터 이온교환막을 결합한 축전식 탈염공정에서 전극 내부의 전해질 농도를 높임으로써 저 농도의 염수를 효과적으로 탈염할 수 있을 것으로 기대된다.

• International Journal of Industrial Entomology and Biomaterials
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• 제27권2호
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• pp.326-328
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• 2013

Sericin undergoes gelation by the structural transition from random coil to b-sheet transition. In the present study, the gelation time of sericin solution was investigated in the presence of NaCl, KCl and $CaCl_2$. The addition of salts delayed the gelation time, and $CaCl_2$ had the most pronounced effect, which delayed about 8 h at maximum. The gelation time increased with the concentration of salt. The transition of secondary structure of sericin was retarded in the presence of salt. The effect of salts on the gelation time of sericin might be due to the solvation effect of relevant cation.

• Bulletin of the Korean Chemical Society
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• 제15권5호
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• pp.399-404
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• 1994

The non-Newtonian viscosities (the specific or intrinsic viscosities) of poly(L-proline) (PLP, $M_v$=19,000 and 32,000) in various mixed-solvent systems like water-propanol and acetic acid-propanol of varying compositions were measured during the reverse mutarotation (Form II ${\rightarrow}$Form I) by the application of external pressure (up to 4.5 psi). The non-Newtonian viscosity effect was found to be larger in acetic acid-propanol system than in water-propanol system and to somewhat decrease during the reverse mutarotation at a given solvent system. The non-Newtonian viscosity behavior of PLP in aqueous salt ($CaCl_2$) solution was also studied, from which it was found that the degree of the non-Newtonian effect decreased with increasing salt concentration, and increased with increasing PLP molecular weight. These findings could be explained in terms of conformational changes of PLP in solution (like the helix-helix or helix-coil transition) involved.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2001년도 추계학술발표대회
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• pp.808-811
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• 2001

The rheological properties of exopolysaccharide(EPS-R) produced by marine bacteria Hahella chjuensis KCTC 2395 was investigated. EPS-R solution showed a characteristic non-Newtonian behavior fluid properties. In aqueose dispersions of EPS-R 1%, consistency index(K) and flow behavior index(n) were 1,410 cp and 0.73. EPS-R solution was pseudoplastic fluid by power-low model. Rheological propertie of EPS-R was found to be influenced by the concentration of salt, pH, temperature and ionic compounds.

• 한국잠사곤충학회지
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• 제45권2호
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• pp.121-125
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• 2003

Dissolution of Antheraea pernyi silk fiber was carried out in a zinc nitrate 6 hydrate (Zn(NO$_3$)$_2$ㆍ6$H_2O$) solution with various dissolving conditions. The solubility was significantly dependent on the concentration of zinc nitrate, dissolving temperature and time. Regenerated A. pernyi silk fibroin powder was obtained through dialysis process to remove chaotropic salt. FTIR and X-ray diffractometer showed that the conformation of regenerated A. pernyi silk powder was sheet structure.

• Fibers and Polymers
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• 제6권2호
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• pp.95-102
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• 2005

Sodium cellulose carbonate (CC-Na) dissolved in $8.5\;wt\%$ NaOH/ZnO (100/2-3, w/w) aqueous solution was spun into some acidic coagulant systems. Diameter of regenerated cellulose fibers obtained was in the range of $15-50\;{\mu}m$. Serrated or circular cross sectional views were obtained by controlling salt concentration or acidity in the acid/salt/water coagulant systems. Velocity ratio of take-up to spinning was controlled up to 4/1 with increasing spinning velocity from 5 to 40 m/min. Skin structure of was developed at lower acidity or higher concentration of coagulants. Fineness, tenacity and elongation of the regenerated cellulose fibers were in the range of 1.5-27 denier, 1.2-2.2 g/d, and $8-11.3\;\%$, respectively. All of CC-Na and cellulose fibers spun from CC-Na exhibited cellulose II crystalline structure. Crystallinity index was increased with increasing take-up speed.

• Journal of the Korean Wood Science and Technology
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• 제20권4호
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• pp.57-64
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• 1992

The unique cell wall micropores of pulp fiber can be utilized as loading site in variety of important practical application which could be the basis of new papermaking technologies. One of these includes the manufature of paper containing higher levels of in situ filler precipitated. Hardwood pulp fiber were first impregnated with the solution of sodium carbonate($Na_2CO_3$). The micropores in cell wall of pulp fibers were filled with the liquid salt solution. The second calcium nitrate($Ca(NO_3)_2$) solution formed an insoluble calcium carbonate($CaCO_3$) precipitate within the cell wall micropores by interacting with the first sodium carbonate solution. The effects of chemical concentration and dryness of pulp fibers on the retention of cell wall micropore loaded filler were investigated. The paper properties of cell wall micropore loaded pulp fibers were compared with those of conventionally loaded and lumen loaded pulp fibers. Also the presense of the fillers within the cell wall micropore was observed by SEM. Increasing the chemical concentration to generate the calcium carbonate increased the retention of filler in cell wall micropore loaded pulp fibers. The particle size distribution of precipitated calcium carbonate ranged from $0.1{\mu}m$ to $80{\mu}m$. But, the average particle size of cell wall micropore loaded calcium carbonate was $4{\mu}m$. The paper made from never dried pulp fibers, the cell wall micropores which were filled with calcium carbonate, had better mechanical and optical properties than those of conventionally loaded or lumen loaded pulp fibers.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 춘계 학술논문 발표대회
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• pp.27-28
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• 2018

Deterioration of reinforced concrete structures due to salt corrosion is a phenomenon that can be easily seen, and the main reason for deterioration is chloride ion. Therefore, researches are actively conducted to control chlorine ion penetration worldwide. The purpose of this study is to evaluate the chloride ion fixation capacity of Portland cement paste containing Hydrotalcite. For this purpose, cement paste containing 0%, 2.5%, and 5% of Hydrotalcite was sealed and cured for 28 days, and the cured cement paste was crushed. Chloride ion solution was prepared at a concentration of 0.5M using NaCl, and the powdered cement paste was reacted for a specific time in aqueous chloride ion solution. After the reaction, the concentration of the chloride ion aqueous solution was measured using a silver nitrate potentiometric titrator, and the reacted cement paste was analyzed using XRD and FT-IR.

• 농업생명과학연구
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• 제45권4호
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• pp.13-21
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• 2011

망개떡의 주원료인 청미래덩굴 잎은 소금물에 저장한 후, 이용 시 세척하여 사용한다. 이에 염장 시 저장 과정에서의 잎의 특성변화를 확인하였다. 천일염과 정제염으로 염장 후 저장한 잎의 수분함량 변화에서는 차이를 보이지 않았으며, 소금의 농도가 높을수록 수분함량은 크게 감소하였다. 실온에서는 정제염에 저장한 잎의 전단력이 높았으나, 저온($4^{\circ}C$)에서는 천일염에서 저장한 잎의 전단력이 높았고, 소금의 농도는 높을수록 저장기간은 짧을수록 전단력이 높아지는 경향을 보였다. 실온보다 저온에서 저장과 소금의 농도가 10% 이하에서 저장한 잎의 색도 변화가 적은 것으로 나타났다.