• Title/Summary/Keyword: Solution growth

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The Observation of Nucleation & Growth during Water Vapor Induced Phase Inversion of Chlorinated Poly(vinyl chloride) Solution using SALS

  • Jang, Jae Young;Lee, Young Moo;Kang, Jong Seok
    • Korean Membrane Journal
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    • v.6 no.1
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    • pp.61-69
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    • 2004
  • Small angle light scattering (SALS) and field emission scanning electron microscope (FE-SEM) have been used to investigate the effects of alcohol on phase separation of chlorinated poly(vinyl chloride) (CPVC)/tetrahydrofuran (THF)/alcohol (9/61/30 wt%) solution during water vapor induced phase separation. A typical scattering pattern of nucleation & growth (NG) was observed for all casting solutions of CPVC/THF/alcohol. In the case of the phase separation of CPVC dope solution containing 30 wt% ethanol or n-propanol, the demixing with NG was observed to be heterogeneous. Meanwhile, the phase separation of CPVC dope solution with 30 wt% n-butanol was found to be predominantly homogeneous NG. Although the different phase separation behavior of NG was observed with types of alcohol additives, the resultant surface morphology had no remarkable differences. That is, even though the NG process by water vapor is either homogeneous or heterogeneous, this difference does not play a main role on the final surface morphology. However, it was estimated from the result of hydraulic flux that the phase separation by homogeneous NG provided the membrane geometry with lower resistance in comparison with that by heterogeneous one.

Electrodeposition of Copper on AZ91 Mg Alloy in Cyanide Solution

  • Nguyen, Van Phuong;Park, Min-Sik;Yim, Chang Dong;You, Bong Sun;Moon, Sungmo
    • Journal of the Korean institute of surface engineering
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    • v.49 no.3
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    • pp.238-244
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    • 2016
  • Copper electrodeposition on AZ91 Mg alloy was studied in views of preferential deposition on ${\alpha}$- or ${\beta}$- phases and how to achieve uniform deposition over the entire surface on ${\alpha}$- and ${\beta}$-phases in a cyanide solution. The inhomogeneous microstructure of AZ91 Mg alloy, particularly ${\alpha}$- and ${\beta}$-phases, was found to result in non-uniform deposition of zincate layer, preferential deposition of zincate on ${\beta}$-phases, which leads to non-uniform growth of copper layer during the following electrodeposition process. The preferential depositions of zincate can be attributed to higher cathodic polarizations on the ${\beta}$-phases. Pin-hole defects in the copper electrodeposit were observed at the center of large size ${\beta}$-phase particles which is ascribed to gas bubbles formed at the ${\beta}$-phases. The activation of AZ91 Mg alloy in hydrofluoric acid solution was used to obtain uniform growth of zincate layer on both the ${\alpha}$- and ${\beta}$-phases. By choosing an optimum activation time, a uniform zincate layer was obtained on the AZ91 Mg alloy surface and thereby uniform growth of copper was obtained in a cyanide copper electroplating solution.

Growth, Deficiency Symptom and Tissue Nutrient Contents of Leaf Perilla (Perilla frutesens Britt) as Influenced by Potassium Concentrations in the Fertigation Solution (칼륨 시비농도가 잎들깨의 생육, 결핍증상 및 무기원소 함량에 미치는 영향)

  • Choi, Jong-Myung;Park, Jong-Yoon
    • Journal of Bio-Environment Control
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    • v.16 no.4
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    • pp.372-378
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    • 2007
  • This study was carried out to investigate the effect of potassium concentrations in fertigation solution on growth and development of nutrient deficiency symptoms of leaf perilla (Perilla frutesens). The nutrient concentrations in above ground plant tissue, petiole sap and soil solution of root media were also determined. Potassium deficiency symptoms developed in older leaves with marginal necrosis. The brown areas on the lower leaves enlarged rapidly and the margins became scorched. Elevation of K concentrations in the fertigation solution up to 8 mM increased the crop growth in leaf length, stem thickness, and fresh and dry matter production of above ground plant tissue. However, that decreased the chlorophyll contents. The 8.0 mM K treatment which showed the greatest growth had 5.01 g in dry weight and 2.76% in K content of above ground plant tissue, suggesting that maintaining K content higher than 1.7% is necessary for good growth of Perilla frutesens. The K concentrations in petiole sap and soil solution of 8.0 mM treatment were $12,289mg{\cdot}kg^{-1}\;and\;11.65mg{\cdot}L^{-1}$, respectively. These indicated that K fertilization to maintain higher than $8,700mg{\cdot}kg^{-1}$ in petiole sap and $4.5mg{\cdot}L^{-1}$ in soil solution are necessary to ensure good crop growth.

Modeling Nutrient Uptake of Cucumber Plant Based on Electric Conductivity and Nutrient Solution Uptake in Closed Perlite Culture (순환식 펄라이트재배에서 전기전도도와 양액흡수량을 이용한 오이 양분 흡수 모델링)

  • Hyung Jin Kim;Young Hoi Woo;Wan Soon Kim;Sam Jeung Cho;Yooun Il Nam
    • Journal of Bio-Environment Control
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    • v.10 no.3
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    • pp.133-140
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    • 2001
  • This study was conducted to develop a nutrient uptake model in cucumnber (Cucumis sativus L. cv. Eunsung Backdadagi) plants for prediction of the amount of nutrients in drainage solution in a closed perlite culture system. Electrical conductivity (EC) of the nutrient solution was adjusted to 1.5, 1.8, 2.1, 2.4, and 2.7 dS. $m^{-1}$ . The amount of nutrient solution absorbed in different EC treatments was not different until the mid stage of growth. However, after the mid growth stage, a high EC treatment resulted in less solution absorption. The absorption rates of K, N $O_3$$^{[-10]}$ -N, Mg, and P increased continuously for a whole growing period in all treatments, while those of Ca decreased slightly. For S, the decrease was significant after th mid stage of growth. although the amounts of absorbed inorganic ions in different EC treatments were not significantly different at the first stage of growth, they were significantly different after the mid stage of growth and decreased slightly at the end of growth stage. Models for predicting the amounts of each inorganic ion absorbed were developed by using EC and the amount of nutrient solution absorbed per unit radiation(mg.M $J^{-1}$), which proved to be practical with a positive correlation at 1 percent probability between the developed model and practical values..

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Effects of Al and Mn on the Growth, Nutrient Status and Gas Exchange Rates of Pinus densiflora Seedlings (소나무 묘목(苗木)의 생장(生長), 영양상태(營養狀態) 및 가스교환속도(交換速度)에 미치는 Al과 Mn의 영향(影響))

  • Lee, Choong Hwa;Jin, Hyun-O;Kim, Young-Kul
    • Journal of Korean Society of Forest Science
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    • v.90 no.1
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    • pp.74-82
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    • 2001
  • The effects of Al and Mn concentration on dry weight growth, nutrient status and gas exchange rates of 2-Year-old Japanese red pine(Pinus densiflora) seedlings grown in a nutrient culture solution were investigated. Al was added as aluminum chloride at 0, 10, 30 or 60ppm, and Mn was added as manganese chloride at 0, 30 or 60ppm to the nutrient culture solution. The pH of the solution was maintained at 4.0 by adding HCl or NaOH solution. The seedlings were transplanted into the nutrient culture solution, then they were grown in a greenhouse for 90 days. The interactive effects of Al and Mn on the dry weight growth of the seedlings were not significant. There were a main effect of Al or Mn on the dry weight growth and element concentrations of the seedlings. The treatment with Al of ${\geq}10ppm$ or that with Mn of 60ppm induced a significant reduction in the dry weight growth, which indicates that the effect of Al is stronger than that of Mn. The chlorophyll content of needles was not affected by Al treatment, but was significantly reduced by treatment with Mn of 60ppm. Furthermore, the treatment with Al of 60ppm or that with Mn of ${\geq}30ppm$ caused a significant reduction in the dark respiration rate of the roots. The net photosynthetic rate of the seedlings reduced with increasing the concentration of Al or Mn in the nutrient culture solution, which suggests that Al or Mn induced reductions in the relative growth rate(RGR) and net assimilation rate(NAR) of the seedlings were mainly due to the decrease of net photosynthesis.

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The Effect of Ginseng Saponin Fraction on the Germination and Early Growth of Rice Seed (Oryza sativa L.) (인삼사포닌이 벼의 발아 및 초기 생장에 미치는 영향)

  • 이용우;주충노
    • Journal of Ginseng Research
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    • v.11 no.1
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    • pp.77-83
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    • 1987
  • The effects of ginseng saponin on the germination and early growth of rice seeds (Oryza sativa L.) were investigated. The early growth (length) of test rice seeds which were rinsed for 60 hrs in $10^{-4}$% saponin solution prior to transplantation to water agar bed was about 20% faster than that of control seeds, It was also found that the amylase activity of the seeds was most active when the seeds were rinsed in 10-4% saponin solution for 48 hrs. In vitro investigation showed that the amylase activities were stimulated about 30% by the treatment of $10^{-5}$% saponin solution compared with control group. From the above results, it seems that the ginseng saponin might activate amylase of rice seed during germination, resulting in rapid growth of rice.

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Corrosive Characterisics of 12Cr Alloy Steel and Fatigue Characteristics of the Artificially Degraded 12Cr Alloy Steel (고온의 인공해수 중 12Cr강의 부식피로특성에 관한 연구)

  • Jo, Seon-Yeong;Kim, Cheol-Han;Bae, Dong-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.5
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    • pp.772-778
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    • 2001
  • In this study, corrosion fatigue characteristics of 12Cr alloy steel were investigated in 3.5wt.% NaCl solution of 150$^{\circ}C$ and 4.5bar. Behavior of corrosion fatigue cracks was measured by the indirect compliance method and compared with the results in distilled water and in air. 1) 12Cr alloy steel was susceptible to temperature. Its susceptibility was increased as the temperature was increased. 2) The crack growth characteristics of 12Cr alloy steel in distilled water were similar to 3.5wt.% NaCl solution. 3) The temperature of solution affects to the crack growth characteristics of 12Cr alloy steel. In corrosion solutions of 4.5bar, 150$^{\circ}C$, fracture surfaces of corrosion fatigue crack growth at a/W=0.3 was showed the trans-granular fracture suface. As the crack grew up, it was changed to inter-granular type. In condition of high temperature, The crack growth behaviors of 12Cr alloy steel were remarkable.

Study on effect of solution temperature on corrosion fatigue of high strength steel (고장력강의 부식피로에 미치는 용액온도의 영향에 관한 연구)

  • 유헌일
    • Journal of the korean Society of Automotive Engineers
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    • v.8 no.1
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    • pp.40-51
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    • 1986
  • A study has been made of the corrosion fatigue of high strength low alloy steel in 3.5% NaCl solution under tension stress for solution temperature being 25.deg. C, 55.deg. C and 85 .deg. C. The main results obtained are as follows; 1) The corrosion fatigue crack growth rate curve could be divided into the First Region, the Second Region and the Third Region. 2) The corrosion fatigue crack growth rates in the First Region and the Second Region were Arrhenius temperature-dependent in this test range. The apparent activation energies for the corrosion fatigue cack growth rate were found to be 2000cal/mol in the First Region and 3700 cal/mol in the Second Region. 3) Hematite (Fe$_{2}$O$_{3}$) as the hexahedral crystal and magnetite (Fe$_{3}$O$_{4}$) as the octahedral crystal were observed in the corrosion products on the corrosion fatigue fracture surface at 85.deg. C and the anode fusion seem to be generated in the crack tip region at high temperature. 4) The complex environment effect ratio which was defined by the ratio of fatigue crack growth rate in corrosion environment to that in air might be considered not only a criterion estimating the effect of environment quantitatively but also an important parameter in the selection of the design stress for the fail safe design. The complex environment effect was not greater than ten in this test.

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Efficacy of Aqueous Chlorine Dioxide and Citric Acid in Reducing Escherichia coli on the Radish Seeds Used for Sprout Production

  • Lim, Jeong-Ho;Jeong, Jin-Woong;Kim, Jee-Hye;Park, Kee-Jai
    • Food Science and Biotechnology
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    • v.17 no.4
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    • pp.878-882
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    • 2008
  • The efficacy of citric acid-aqueous chlorine dioxide ($ClO_2$) treatment of radish seeds artificially contaminated with Escherichia coli was studied. Radish seeds were inoculated with E. coli. Following inoculation, samples were stored at $4^{\circ}C$ and soaked in citric acid or aqueous $ClO_2$ for 10 min. The treatment of radish seeds using 200 ppm aqueous $ClO_2$ solution caused a 1.5 log CFU/g reduction in the population of E. coli. Compared to the aqueous $ClO_2$ treatment, soaking radish seeds in 2.0% citric acid solution for 10 min was more effective in reducing E. coli populations on radish seeds. The efficacy of spray application of chlorine (100 ppm) or 0.5% citric acid to eliminate E. coli during the germination and growth of radish was investigated. Radish seed inoculated with E. coli was treated for the duration of the growth period. Although it resulted in a decrease in the E. coli population, the spray application of 100 ppm chlorine during the growth period was not significantly effective. In contrast, the combined treatment of seeds using 200 ppm aqueous $ClO_2$ and treatment of sprouts with 0.5% citric acid solution during sprout growth was hardly effective in eliminating E. coli.

Composition of Optimal Nutrient Solution for Single-stemmed Rose 'Red velvet' in a Closed Aeroponic System

  • Kang Mu Jang;Lee Joo Hyun;Lee Yong-Beom
    • Journal of Bio-Environment Control
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    • v.14 no.3
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    • pp.174-181
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    • 2005
  • Experiments were carried out to develop an optimal nutrient solution for the single-stemmed rose (Rosa hybrida L.) 'Red velvet' in a closed aeroponic system. Plants were grown in 1/3, 1/2, 1, or 3/2 strength of the nutrient solution of National Horticultural Research Station in Japan (NHRS). Significantly less changes of pH and EC ($dS{\cdot}m^{-1}$) in the drainage were observed in 1/2 strength treatment as compared to other treatments. The $NO_3-N$, K, Ca, and Mg concentrations in the drainage solution of 1/2 strength treatment were maintained at optimal levels. These results indicated that the rose uptakes of both nutrients and water was more stable than those in other concentration. The concentration of macronutrients in nutrient solution were adjusted based on the ratio of nutrient:water (n/w) taken up by plants grown in the 1/2 strength solution. The composition of the new solution (classified the University of Seoul (UOS) solution) was as follow; $NO_3-N$ 8.8, $NH_4-N$ 0.67, P 2.0, K 4.8, Ca 4.0, Mg 2.0 $me{\cdot}L^{-1}$. To further evaluate new solution on crop growth, the rose 'Red Velvet' was grown again in l/2, 1, and 2 strength UOS solution to compare with 1.0 strength PBG (proefstion voor bloemisterij en glasgroenpe) solution. Overall the plant growth, including the stem length and number of five-leaflet leaves was higher in 1.0 strength of UOS solution than other treatments. Results presented in this study indicate that the nutrients in the UOS solution are well balanced for the single-stemmed rose in the closed aeroponic system.