• Title/Summary/Keyword: Solution film thickness

검색결과 376건 처리시간 0.028초

졸-겔 세라믹 코팅에 의한 스테인레스강의 내산화 및 내식성 향상에 관한 연구 (II);$CeO_2$ 안정화 지르코니아 박막의 내산화 및 내식성 효과 (A Study on the Improvement of Oxidation and Corrosion Resistance of Stainless Steel by Sol-Gel Ceramic Coating (II); Effect on Oxidation and Corrosion REsistance of $CeO_2$ Stabilized Zirconia Thin Film)

  • 이재호;우일기;김병호
    • 한국세라믹학회지
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    • 제32권1호
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    • pp.95-105
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    • 1995
  • Ceria(CeO2) stabilized zirconia(CeSZ) sol was synthesized with zirconium n-butoxide Zr(OC4H9)4 and cerium nitrate hexahydrate Ce(NO3)3.6H2O as precursors and ethylacetoacetate(EAcAc) as a chelating agent under atmosphere. CeSZ films were deposited on AISI 304 stainless steel using the prepared polymeric sol by dipcoating and the coating characteristics were investigated by XRD, ellipsometry, scratch test and SEM. The CeSZ film began to crystallize from amorphous to tetragonal phase at 40$0^{\circ}C$ and it was not converted into monoclinic phase up to 100$0^{\circ}C$ by the addition of 16mol% CeO2 as a stabilizer which could suppress phase transformation of zirconia. The CeSZ films were prepared by varying the EAcAc contents and the cncentration of CeSZ sol and measured the thickness and refractive index. From these results, it was found that the EAcAc contents and concentration of CeSZ coating sol evidently affect the densification of CeSZ film. The CeSZ film coated with 0.4M CeSZ sol and heat-treated at $600^{\circ}C$ for 10min had thickness of 50nm and 17% porosity. The CeSZ film on 304 stainless steel effectively acted as a protective layer against oxidation up to 80$0^{\circ}C$ and had superior corrosion resistance in 25% H2SO4 solution for 4.5 hrs.

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금속 부식과 부동화에 관한 전기화학적 및 광학적 연구. 순철의 부동화 피막에 관한 전기화학적 및 광학적 연구 (An Electrochemical and Optical Study on the Corrosion and Passivation of Metals. An Electrochemical and Optical Study on the Passivation Film of Electrolytic Iron)

  • 박병소;백운기;여인형
    • 대한화학회지
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    • 제22권6호
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    • pp.365-369
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    • 1978
  • 음극 환원상태에 있는 철과 양극산화로 부동상태에 있는 철의 표면에 대하여 반사율과 광학적(ellipsometry) 측정을 하였다. 환원상태와 부동상태에 있는 표면들 사이의 광학적 파라미터들 (${\Delta},\;{\psi}$ 및 반사율)의 차이를 측정하여 그로부터 부동상태에서 금속 표면을 덮고 있는 표면막의 두께와 광학적 상수들을 정할 수가 있었다. 포화 칼로멜전극에 대하여 -400mV에서 부동화된 표면의 산화막은 약 11${\AA}$의 두께와 ${\tilde{n}}$ = 2.8 - 0.8 i 의 광학상수를 갖고 있는 것으로 나타났다. 이로부터 부동상태의 표면막은 적지 않은 전자 전기전도성을 가지고 있음을 알 수 있다.

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집적광학용 격자구조의 제작과 응용 (Fabrication of Grating Structures and Their Applications in Integrated Optics)

  • 이성재;송재원;신상영
    • 대한전자공학회논문지
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    • 제21권3호
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    • pp.39-45
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    • 1984
  • Submicron gratings are fabricated holographically on thin film single mode and multimode waveguides. Thin film waveguides are made by spin-coating polyurethane solution on the substrates of microscope slide glass and Corning 7059 glass. In order to characterize thin film waveguides, the refract사e index and the thickness of thin films are measured by using the m-line spectroscopy. The fabricated gratings are tested as a grating coupler, a mode converter, and a beam splitter. Also chirped gratings are fabricated to observe beam expansion phenomena and thus the possibility of the wavelength demultiplexing.

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고밀도 폴리에틸렌의 결정과 절연파괴 특성 연구 (Crystal and Electric Breakdowm Characteristic of High-Density Polyethylene)

  • 김석기;한상옥;박강식;신동국;김병준;김종석
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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    • pp.129-131
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    • 1995
  • In order to investigated the effects of crystal stucture in electrical breakdown of plyethylene film, Low molecular materials in polyethylene are removed by the method as follow Polyethylene was dissolved in xylene and filtered through a glass fiber filter, And then, a polyethyene thin films of thickness 0.4~1.4$\mu\textrm{m}$ are prepared with heat treatment from solution casting. To evaluate the performance of PE film. Electrical breakdown of PE film as measured on M(Al)-I(PE)-M(Al) systemes.

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Properties and Structure of Poly(vinyl Alcohol) Film Containing Electrolytes

  • Iwaseya, Masato;Yamaura, Kazuo;Dai, Lixing
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.99-99
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    • 2003
  • We have investigated the properties of poly (vinyl alcohol)-film obtained by casting from the solution PVA/electrolytes (NaCl, KCl, MgCl$_2$, CaCl$_2$)/water systems at room temperature. The removed electrolytes films have got high crystallinity as well as high draw ratio. The removed electrolytes films had layer-structure while a film without electrolytes didn't have it. A relation between draw ratio and thickness or number of layers, were recognized.

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금속유기물증착법에 의한 $La_2Ti_2O_{7}$ 박막의 제조 (Fabrication of $La_2Ti_2O_{7}$ Film by Metalorganic Deposition)

  • 조경호;우동찬;박철우;이희영;남효덕
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
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    • pp.122-125
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    • 1995
  • Using metalorganic deposition technique, $La_2Ti_2O_{7}$ precursor solution was deposited on platinium coated SiO$_2$/SI(100) substrates by spin-coating process. Crystalline and crack-free films of ∼0.2$\mu\textrm{m}$ thickness were successfully fabricated on the above substrate from four different types of $La_2Ti_2O_{7}$ precursor solutions by proper heat treatment in the temperature range of $700^{\circ}C$$1200^{\circ}C$. Microstructure and X-ray diffraction analysis of $La_2Ti_2O_{7}$ thin film showed that the crystallization temperature and the preferred orientation of $La_2Ti_2O_{7}$ thin film were strongly dependent on the precursor used.

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자성 박막에서 여기되는 스핀파 거동 (Behavior of Spin Waves Excited in Magnetic Thin Film)

  • 한기평;손영준;백문철;조경익
    • 한국자기학회지
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    • 제10권2호
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    • pp.86-92
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    • 2000
  • 자성 박막 표면에서의 일축 자기이방성을 고려한 자화의 경계조건을 Maxwell 방정식과 자화에 대한 Gilbert 방정식을 동시에 만족하는 해에 적용하여 자성박막에서 여기되는 스핀파 공명신호에 대한 모의실험을 수행하였다. 공명신호에 영향을 주는 물리량은 박막두께, 교환강성 상수, 표면 자기이방성 상수, 포화자화, 감쇠 상수, 전기비저항 등이며, 이러한 물리량들이 자성 박막에서 여기되는 스핀파 거동에 미치는 영향을 공명흡수선의 공명자기장, 선폭, 세기로 구분하여 조사하였다.

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표면 거칠기를 고려한 볼베어링의 탄성유체윤활 (EHL Analysis of Ball Bearing Considering Surface Roughness)

  • 이향;조용주
    • Tribology and Lubricants
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    • 제29권4호
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    • pp.228-234
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    • 2013
  • This paper presents analysis of elastohydrodynamic lubrication (EHL) of ball bearings, in which surface roughness is considered. A lot of time is required to obtain a solution in the case of EHL analysis where surface roughness is considered, because the analysis requires a variety of analytic nodes. To save time, we use the full approximation scheme (FAS) among multilevel methods. We analyze the results of EHL and contact analyses in terms of pressure. We also compare the results for smooth and rough surfaces with respect to film thickness. We confirm that the film pressure decreases as compared to contact pressure because of the presence of lubricants between the ball and the raceway. Furthermore, in the case when surface roughness is considered, the film pressure increases because of contact asperities. Therefore, surface roughness should be considered when designing ball bearings.

부 채널 신호에 대한 박막의 영향 (Thin Film Effects on Side Channel Signals)

  • 선용빈
    • 반도체디스플레이기술학회지
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    • 제12권2호
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    • pp.51-56
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    • 2013
  • Even if transmissions through normal channel between ubiquitous devices and terminal readers are encrypted, any extra sources of information retrieved from encrypting module can be exploited to figure out the key parameters, so called side channel attack. Since side channel attacks are based on statistical methods, making side channel signal weak or complex is the proper solution to prevent the attack. Among many countermeasures, shielding the electromagnetic signal and adding noise to the EM signal were examined by applying different thicknesses of thin films of ferroelectric (BTO) and conductors (copper and gold). As a test vehicle, chip antenna was utilized to see the change in radiation characteristics: return loss and gain. As a result, the ferroelectric BTO showed no recognizable effect on both shielding and adding noise. Cu thin film showed increasing shielding effect with thickness. Nanometer Au exhibited possibility in adding noise by widening of bandwidth and red shifting of resonating frequencies.

고특성 REBCO 초전도 박막 제조를 위한 새로운 MOD 전구 용액 제조 (New MOD solution for the preparation of high $J_c$ REBCO superconducting films)

  • 김병주;홍계원;이희균
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.2001-2003
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    • 2005
  • Various organic acid were used in order to prepare new metalorganic deposition solution for high quality $REBa_2Cu_3O_{7-{\delta}}$ (RE=Y, Eu, Gd) films. Prepared fluorine free MO precursor solution was coated on single crystal (001) $LaAlO_3$ (LAO) by dip coating method. Processing parameters such as oxygen partial pressure, water vapor, ramping rate and pyrolysis temperature etc havebeen controlled in order to make high $J_c$ films with a good epitaxial relationship with substrate. 0.5 micron-thick film was obtained by single coating and no crack appeared after calcination. Oxygen partial pressure was varied in the range of $100{\sim}1,000 ppm$ and conversion heat treatment was carried out at the temperature of $725{\sim}765^{\circ}C$. A critical transition temperature $(T_{c0})$ of 90K and a critical transport current density $(J_c)$ of $>0.5MA/cm^2$ (77K and self-field) were demonstrated for the YBCO film on (001) oriented LAO substrates with a thickness of 0.5 micron. $I_c$ was determined by utilizing a transport measurement. SEM and XRD investigations confirmed that films were grown epitaxially onto the LAO single crystal substrate. It is thought that fluorine free new MOD solutionis promising for high quality REBCO films.

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