• Corrosion Science and Technology
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• v.21 no.2
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• pp.158-169
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• 2022

The objective of this study was to investigate the electrochemical behavior and damage degree of metal surface under different conditions by performing a potentiodynamic polarization experiment using an electropolishing solution for UNS S31603 based on initial delay time and surface roughness (parameters). A second anodic peak occurred at initial delay time of 0s and 100s. However, it was not discovered at 1000s and 3600s. This research referred to an increase in current density due to hydrogen oxidation reaction among various hypotheses for the second anodic peak. After the experiment, both critical current density and corrosion current density decreased when the initial delay time (immersion time) was longer. As a result of surface analysis, characteristics of the potentiodynamic polarization behavior were similar with roughness, although the degree of damage was clearly different. With an increase in surface roughness value, the degree of surface damage was precisely observed. As such, electrochemical properties were different according to the immersion time in the electropolishing solution. To select electropolishing conditions such as applied current density, voltage, and immersion time, 1000s for initial delay time on the potentiodynamic polarization behavior was the most appropriate in this experiment.

• Corrosion Science and Technology
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• v.22 no.3
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• pp.137-152
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• 2023

Polarization behavior and corrosion inhibition of copper in acidic chloride solutions containing benzotriazole were studied. Pourbaix diagrams constructed for copper in NaCl solutions with different BTAH concentrations were used to understand the polarization behavior. Open circuit potential (OCP) depended not only on chloride concentration, but also on whether a CuBTA layer was formed on the copper surface. Only when the (pH, OCP) was located well in the CuBTA region of the Pourbaix diagram, a stable corrosion inhibiting CuBTA layer was formed, which was confirmed by X-ray Photoelectron Spectroscopy (XPS) and a long-term corrosion test. The OCP for the CuBTA layer decreased logarithmically with increasing [Cl^-] activity in the solution. A minimum BTAH concentration required to form a CuBTA layer for a given NaCl concentration and pH were determined from the Pourbaix diagram. It was found that 320 ppm BTAH solution could be used to form a corrosion-inhibiting CuBTA layer inside the corrosion pit in the sprinkler copper tube, successfully reducing water leakage rate of copper tubes. These experimental results could be used to estimate water chemistry inside a corrosion pit.

• Resources Recycling
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• v.10 no.1
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• pp.49-55
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• 2001

The strategy of recovering metals from scrap is in general much different from primary sources. One of the main differences between the treatment of scrap and that of primary sources lies with the fact that metals are frequently associated with other met-als to form alloys in scrap, while metals occur in primary sources as oxides or sulfides. In this paper, factors affecting the dis-solution behavior of metals from various alloy systems have been reviewed and discussed. Specific examples have been drawn from Au/Ag, Au/cu and Ag/cu systems. Results of the dissolution behavior of various metals from these alloys have been reviewed and compared to the dissolution behavior of single metal systems in various lixiviants such as acids, cyanide and ammonia. It has been observed that the presence of other metals in alloys would significantly affect the dissolution rate of the metal in question. The leaching behavior of metals from homogeneous alloys relies on the chemical interaction between atoms in the lattice of the alloys, while that from heterogeneous alloys is affected by galvanic interaction established in the solution The manner in which the dissolution of a certain metal is influenced by surrounding metals has been discussed in terms of pas-sive and noble nature of the metal in relation to the neighboring metals. The role of the standard electrochemical Potential of these metals on the selective dissolution for a given lixiviant has also been discussed.

• Coupled systems mechanics
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• v.6 no.1
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• pp.97-111
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• 2017

The present paper reports an analytical study of delamination fracture in the Mixed Mode Flexure (MMF) functionally graded beam with considering the material non-linearity. The mechanical behavior of MMF beam is modeled by using a non-linear stress-strain relation. It is assumed that the material is functionally graded along the beam height. Fracture behavior is analyzed by the J-integral approach. Non-linear analytical solution is derived of the J-integral for a delamination located arbitrary along the beam height. The J-integral solution derived is verified by analyzing the strain energy release rate with considering the non-linear material behavior. The effects of material gradient, crack location along the beam height and material non-linearity on the fracture are evaluated. It is found that the J-integral value decreases with increasing the upper crack arm thickness. Concerning the influence of material gradient on the non-linear fracture, the analysis reveals that the J-integral value decreases with increasing the ratio of modulus of elasticity in the lower and upper edge of the beam. It is found also that non-linear material behavior leads to increase of the J-integral value. The present study contributes for the understanding of fracture in functionally graded beams that exhibit material non-linearity.

• Journal of the Korean Society of Safety
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• v.18 no.1
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• pp.101-107
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• 2003

Dynamic behavior of flexible rectangular liquid storage structures is analysed by the developed method. The rectangular liquid storage structures are assumed to be fixed to the ground and a moving coordinate system is used. The irrotational motion of invicid and incompressible ideal fluid is represented by two analytic solutions. One is the solution of the fluid motion in the rigid rectangular liquid storage structure due to ground motions and the other is the solution of the fluid motion by the motion of the wall in the flexible rectangular liquid storage structure. The motion of structure is modeled by finite elements. The fluid-structure interaction effect is reflected into the coupled equation of motion as added fluid mass matrix. The free surface sloshing motion and hydrodynamic pressure acting on the wall in the flexible rectangular liquid storage structure due to the horizontal ground motion are obtained by the developed method and verified.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10c
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• pp.185-190
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• 1998

Corrosion of steel reinforcement is the most significant factor of deterioration in reinforced concrete structures. Chloride ion is considered one of the most common culprits on the corrosion of steels in concrete. The main objective of this study is understanding behavior of chloride ion in hardened cement pastes at different stages of curing. Cement pastes with water-cement ratio of 0.5 are allowed to hydrate in sealed containers for 28, 70, 180 days. And than pore solution is expressed. It was found that the $Cl^-$ concentrations in pore solution is decreased with increasing curing time in all Nacl addition level, the $OH^-$ concentrations is increased to 70 days but decrease at 180 days in all Nacl addition level. The $Cl^-$/$OH^-$ in pore solution is increased with increasing curing time in all Nacl addition level, however $Cl^-$/$OH^-$ of maximum Nacl addition level(Nacl 0.54% by weight of cement) is under the onset of depassivation level 0.3.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.549-554
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• 2001

It is possible for concrete using sea sand to contain chloride ion as well as cation such as Na$^{+}$and $K^{+}$ during mixing process. It is known that some cations such as Na$^{+}$and $K^{+}$ remain in pore solution without binding In this study, therefore, we intend to inspect the behavior of cations in cement paste as well as NaCl, CaCl$_2$ and KCI through analysis of pore solution extracted from cement paste with high pressure vessel. As a result, increase of alkali ions by adding sea sand and admixtures to the fresh concrete means use of the cement contained high alkali contents. In this case, alkali ions in pore solution can decrease durability of cement products causing alkali-aggregate reaction or accelerated carbonation. So it needs to be studied.studied.

• Journal of the Korean Society of Safety
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• v.12 no.3
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• pp.38-44
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• 1997

6063-T5 alloys are tested in laboratory air, water and 3% NaCl solution to investigate the effects of corrosive environment on the retardation behavior through single overload fatigue test. Also, the fatigue crack propagation and the crack closure behavior are studied. The results obtained in this experimental study are summarized as follows. 1) Behaviors of fatigue crack growth retardation are observed in water and 3% NaCl solution as they do in air. The number of delay cycles and the size of affected region by single overload decrease greatly in water and 3% NaCl compared with those in air. 2) In fractographic results, the overload marking by single overload appear remarkably in air, but indistinctly in water and 3% NaCl solution. 3) The effect of crack closure on crack propagation is most remarkable in the beginning of crack propagation. With crack propagation, the crack closure level and its effect decrease greatly.

• Steel and Composite Structures
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• v.23 no.3
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• pp.263-271
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• 2017

A theoretical study was carried-out of mode II delamination fracture behavior of the End Loaded Split (ELS) functionally graded beam configuration with considering the material non-linearity. The mechanical response of ELS was modeled analytically by using a power-law stress-strain relation. It was assumed that the material is functionally graded transversally to the beam. The non-linear fracture was investigated by using the J-integral approach. Equations were derived for the crack arm curvature and zero axes coordinate that are needed for the J-integral solution. The analysis developed is valid for a delamination crack located arbitrary along the beam height. The J-integral solution was verified by analyzing the strain energy release rate with considering material non-linearity. The effects of material gradient, non-linear material behavior and crack location on the fracture were evaluated. The solution derived is suitable for parametric analyses of non-linear fracture. The results obtained can be used for optimization of functionally graded beams with respect to their mode II fracture performance. Also, such simplified analytical models contribute for the understanding of delamination fracture in functionally graded beams exhibiting material non-linearity.

• Journal of Powder Materials
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• v.9 no.5
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• pp.346-351
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• 2002

Pure and fine, two-component titanate powders (barium titanate, calcium titanate etc.) were synthesized by an ethylene glycol method. Titanium isopropoxide and other metal ionic salts were dissolved in liquid-type ethylene glycol without any precipitation. In non-aqueous system, the amount of ethylene glycol affected the solubility and homogeneity of metal cation sources in the solution. At the optimum amount of the polymer, the metal ions were dispersed effectively in solution and a homogeneous polymeric network was formed. Most of the synthesized powders had sub-micron or nano-size primary particles after calcination and the agglomerated calcined powders were easily ground by ball milling process. All synthesized titanate powders had stable crystallization behavior at low temperature and high specific surface area after ball milling. The crystallization behavior and the microstructures of the calcined powders were affected on the ethylene glycol content.