• 제목/요약/키워드: Solute Transport

검색결과 164건 처리시간 0.023초

Study on Simultaneous Material Transport through Charged Mosaic Membrane

  • Myeongkwan Song;Lee, Jang-Oo;Akira Yamauchi;Wongkang Yang
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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    • pp.109-112
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    • 2004
  • The charged mosaic membranes having cation and anion exchange mixed groups within membrane were researched. The composite charged mosaic membrane was investigated from simultaneous transport such as solute and solvent flux. On the other hand, the reflection coefficient and salt flux coefficient were estimated by taking account of the cross constants of the phenomenological equation.(omitted)

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하천 내 유사와 인 이동에 관한 모델링 (Modeling of Sediment and Phosphorous Transport in a River Channel)

  • 김경현
    • 한국물환경학회지
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    • 제26권2호
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    • pp.332-342
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    • 2010
  • A model has been developed to investigate in-river sediment and phosphorus dynamics. This advective-dispersive model is coupled with hydrodynamics and sediment transport submodels to simulate suspended sediment, total dissolved phosphorus, total phosphorus, and particulate phosphorus concentrations under unsteady flow conditions. It emphasizes sediment and phosphorus dynamics in unsteady flow conditions, in which the study differs from many previous solute transport studies, conducted in relatively steady flow conditions. The diffusion wave approaximation was employed for unsteady flow simulations. The first-order adsorption and linear adsorption isotherm model was used on the basis of the three-layered riverbed submodel with riverbed sediment exchange and erosion/deposition processes. Various numerical methods were tested to select a method that had minimal numerical dispersion under unsteady flow conditions. The responses of the model to the change of model parameter values were tested as well.

Toxicological Relevance of Transporters

  • Maeng, Han-Joo;Chung, Suk-Jae
    • Toxicological Research
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    • 제23권1호
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    • pp.1-9
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    • 2007
  • Transporters are membrane proteins that mediate the transfer of substrate across the cellular membrane. In this overview, the characteristics and the toxicological relevance were discussed for various types of transporters. For drug transporters, the overview focused on ATP-binding cassette transporters and solute carrier family 21A/22A member transporters. Except for OCTN transporters and OATP transporters, drug transporters tend to have broad substrate specificity, suggesting drug-drug interaction at the level of transport processes (e.g., interaction between methotrexate and non-steroidal anti-inflammatory agents) is likely. For metal transporters, transporters for zinc, copper and multiple metals were discussed in this overview. These metal transporters have comparatively narrow substrate specificity, except for multiple metal transporters, suggesting that inter-substrate interaction at the level of transport is less likely. In contrast, the expressions of the transporters are often regulated by their substrates, suggesting cellular adaptation mechanism exists for these transporters. The drug-drug interactions in drug transporters and the cellular adaptation mechanisms for metal transporters are likely to lead to alterations in pharmacokinetics and cellular metal homeostasis, which may be linked to the development of toxicity. Therefore, the transporter-mediated alterations may have toxicological relevance.

하수처리장 방류수에 용존된 무기화학종의 연속계측자료를 이용한 하천유량, 유속 및 방류량 추적

  • 김강주;한찬
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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    • pp.3-6
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    • 2001
  • Various Parameters such as stream velocities, discharges, and dispersion coefficients of dissolved solutes were estimated by fitting 1-D nonreactive solute transport model to the time-series chemistry data. This study was done for the reaches of Mankyung River lower than the Jeonju Wastewater Treatment Plant (Jeonju WTP). Korea. Concentrations of inorganic chemicals in the stream waters are strongly influenced by mixing with the chemically distinct effluent from Jeonju WTP. Sulfate, EC. and the total major cation were proved to be nearly conservative in the study area front their relationships with chloride, the conservative chemical species. The solute transport model was constrained to the time-series concentrations for these 4 conservative species. The variations of concentration and discharge of Jeonju WTP were used as input parameters, and the stream velocities, dispersion coefficients, and concentrations and discharges of some inflows were optimized. The differences between the observed arid simulated values for alkalinities and nitrates are inversely correlated and show diurnal fluctuations, indicating the photosynthesis. The parameters obtained front this mode] range from 550 to 774 kcmd (stream discharge at the outlet of the study area), from 0.06 to 0.10 m/sec (flow velocity), and from 0.7 to 6.4 m$^2$/sec (dispersion coefficient). The history of Jeonju WTP discharge was well predicted when optimized, indicating the validity of the model results.

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주형의 회전이 Al-Cu 합금의 응고과정에 미치는 영향 (The effect of mold rotation on solidification process of an Al-Cu alloy)

  • 유호선
    • 대한기계학회논문집B
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    • 제21권4호
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    • pp.525-540
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    • 1997
  • The effect of mold rotation on the transport process and resultant macrosegregation pattern during solidification of an Al-Cu alloy contained in a vertical axisymmetric annular mold cooled from the inner wall is numerically investigated. The mold initially at rest starts to rotate at a prescribed angular velocity simultaneously with the beginning of cooling. Computed results for a representative case show that the mold rotation essentially suppresses the development of both thermal and solutal convections in the melt, creating distinct characteristics such as the liquidus front, flow pattern and temperature distribution from those for the stationary mold. Thermal convection which develops at the early stages of cooling is soon extinguished by the rotating flow induced during spin-up, and thus does not effectively remove the initial superheat from the melt. On the other hand, solutal convection, though it weakens considerably and is confined within the mushy zone, still predominates over the solute redistribution process. With increasing the angular velocity, the solute transport in the axial direction is enhanced, whereas that in the radial direction is reduced. The final macrosegregation formed in the mold rotating at moderate angular velocities appears to be favorable in comparison with the stationary casting, in that not only relatively homogenized composition is achieved, but also a severely positive-segregated channel is restrained.

하천 오염물질의 모의를 위한 프랙탈 이송확산방정식의 해석적 유도 (The Analytical Derivation of the Fractal Advection-Diffusion Equation for Modeling Solute Transport in Rivers)

  • 김상단;송미영
    • 한국수자원학회논문집
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    • 제37권11호
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    • pp.889-896
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    • 2004
  • 프랙탈 이송확산방정식은 정수 차수의 미분연산자로 구성된 고전적인 이송확산방정식과 비교하여 프랙탈 차수의 미분연산자로 구성된 보다 상위개념의 방정식으로써 정의된다. 지금까지의 프랙탈 이송확산방정식은 추계학적인 기법을 동원하여 푸리에-라플라스 공간에서 주로 해석되었으나, 본 연구에서는 실제 공간에서 유한차분개념을 도입하여 보다 직접적으로 하천에서의 오염물 이송확산에 관한 지배방정식을 유도하였다. 이러한 개념의 유도방법은 프랙탈 차수 및 관련 확산계수의 물리적인 추정에 관한 실마리를 제공할 수 있다. 고전적인 이송확산방정식과는 달리 프랙탈 이송확산방정식은 실제 하천에서 관측되는 오염물의 시간-농도 분포곡선의 왜곡현상과 분포곡선의 전후방부 농도를 보다 실제에 가깝게 모의할 수 있을 것으로 기대되어진다.

농경지의 비료, 농약의 지하유실량 추정 -Preferential 흐름모형- (Estimating Leaching of Nutrients and Pesticides in Agricultural Lands -A Perferential Flow Model-)

  • 이남호;타모스틴후이스
    • 한국농공학회지
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    • 제39권2호
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    • pp.62-73
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    • 1997
  • The application of nutrients and pesticides to agricultural lands has been reported to contribute to groundwater contamination, which can be explained by preferential flow in lieu of convective-dispersive flow. An one-dimensional numerical model depicting preferential water and solute movement was modified to describe multi-layer flows. The model is based on a piecewise linear conductivity function. By combining conservation of mass and Darcy's law and using the method of characteristics a solution is obtained for water flow in which water moves at distinct velocities in different flow regions instead of an average velocity for the whole profile. The model allows transfer ofqr solutes between pore groups. The transfer is characterized by assuming mixing coefficients. The model was applied to undisturbed soil columns and an experiment site with structured sandy clay loam soil. Chloride, bromide, and 2, 4-D were used as tracers. Simulated solutes concentrations were in good agreement with the soil column data and field data in which preferential flow of solute is significant. The proposed model is capable of describing preferential solute transport under laboratory and field conditions.

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Olefin/Paraffin Separation though Facilitated Transport Membranes in Solid State

  • Hong, Seong-Uk;Won, Jong-Ok;Hong, Jae-Min;Park, Hyun-Chae;Kang, Yong-Soo
    • 한국막학회:학술대회논문집
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    • 한국막학회 1999년도 The 7th Summer Workshop of the Membrane Society of Korea
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    • pp.15-18
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    • 1999
  • A simple mathematical model for facilitated mass transport through a fixed site carrier membrane was derived by assuming an instantaneous, microscopic concentration (activity) fluctuation. The current model demonstrates that the facilitation factor depends on the extent of concentration fluctuation, the time scale ratios of diffusion to chemical reaction and the ratio of the carrier concentration to the solute solubility in matrix. The model was examined against the experimental data on oxygen transport in membranes containing metallo-porphyrin carriers, and the agreement was exceptional (within 10% error). The basic concept of this approach was applied to separate olefin from olefin/paraffin mixtures. A proprietaty carrier, developed here, resulted that the selectivity of propylene over propane was more than 120 and the propylene permeance exceed 40 gpu.

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전기저항센서가 부착된 주상실험기에서 측정된 전기저항값을 이용한 용질의 이동해석 (Analysis of Solute Transport based on Electrical Resistance Measurements from Laboratory Column Tests)

  • 김용성;김재진;박준범
    • 대한토목학회논문집
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    • 제28권4C호
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    • pp.231-238
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    • 2008
  • 본 연구에서는 오염용질의 이동특성을 분석하기 위한 측정방법으로서 전기저항센서를 부착한 주상실험기를 개발하였으며 3가지의 포화사질토에 비반응성 추적자를 주입하여 그 적용성을 평가하였다. 측정된 전기저항 값을 바탕으로 전기전도도 파과곡선을 얻었으며, 추정된 농도자료를 이류-확산 방정식에 대입하여 수리분산계수를 산정하였다. 유출수 파과곡선에서 추정된 평균간극유속과 종분산계수를 바탕으로 전기전도도 파과곡선의 신뢰성을 평가해본 결과 전제된 ${\sigma}_{sat}-{\sigma}_w-C$(흙의 전기전도도-간극수의 전기전도도-간극수 내 용질의 농도) 사이의 선형 조건이 성립할 시 측정된 전기저항치는 흙 매질내 간극수 용질의 상대농도를 간접적으로 추정할 수 있는 인자임을 확인하였다. 전기전도도 파과곡선은 실제농도(resident concentration)의 시간적 변화를 나타낼 수 있는 만큼 시간연속적인 전기저항 측정은 많은 시간과 노력이 요구되는 용출수 샘플링과 분석을 효과적으로 대체할 수 있을 것으로 판단되었다. 불확실성을 줄이기 위해 저항측정위치와 주입되는 용액과 포화간극수와의 전기적 차이가 고려되어야함을 확인하였다.