• Title/Summary/Keyword: Solute Flux

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Characteristics of Absorption and Heat Transfer for Film Falling along a Vertical Inner Tube (2nd. Report, Characteristics of Heat Transfer) (수직관내(垂直管內)를 흘러내리는 액막식(液膜式) 흡수기(吸收器)의 흡수(吸收) 및 열전달특성(熱傳達特性)(제(第)2보(報) 열전달특성(熱傳達特性)))

  • Ohm, K.C.;Rie, D.H.;Choi, G.G.;Kasiwagi, Takao;Seo, J.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.4
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    • pp.257-264
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    • 1993
  • This is the second report of a three part study on the absorption and heat transfer characteristics of absorber, the correlation of refrigerating capacity and heating capacity. The 2nd report deals with the heat transfer characteristics of a vertical falling film type absorber of inner copper tube. The solute is LiBr-Water solution(60wt%) and the solvent is water vapor. The film Reynoles numbers are varied in the range of 35~130. The states of LiBr solution at the top of absorber are supercooled liquid and superheated liquid. The results are summarized as follows ; Heat transfer results reveal that for the absorption of falling film, the state of LiBr solution appears to be influential in determining the heat transfer. Thus, for the state of supercooled liquid, heat transfer coefficient decreases with increasing the film Reynolds number, but in the condition of superheated liquid, it increases conversely. The mass transfer coefficients that were presented in the 1st.report and heat transfer coefficients of this paper are presented as the dimensionless correlation. The optimum water flowrate which brings about maximum value of heat flux in the film exists, and that increases with increasing the cooling water temperature.

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Effect of Toluene Added to Casting Solution on Characteristic of Phase Inversion Polysulfone Membrane (상전환 공정에 의한 폴리설폰막의 제조에 있어 제막용액에 첨가된 톨루엔의 영향)

  • Choi, Seung-Rag;Park, So-Jin;Seo, Bum-Kyoung;Lee, Kune Woo;Han, Myeong-Jin
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.633-639
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    • 2008
  • Polysulfone membranes were prepared via the phase inversion process. Toluene was added as a nonsolvent additive in the casting solution containing a mixture of polysulfone and n-methylpyrrolidone. When prepared via the diffusion-induced process using isopropanol as a precipitation nonsolvent, the solidified membranes revealed a similar asymmetric structure irrespective of the addition of toluene, presenting both a dense skin layer and a sponge-like support layer. The added toluene played a role of enhancing liquid-liquid phase separation of the casting solution, and skin layer thickness of a prepared membrane increased with toluene content in the casting solution. On membrane performance, the solute rejection showed a uniform behavior irrespective of the addition of toluene. However, in spite of the significant increase in dense skin layer thickness, the water permeation through the membrane prepared with 60 wt% toluene revealed five times as much flux, compared with that of the membrane prepared without toluene additive.

Microstructural Characteristics of 800 MPa Grade High Strength Steel Weld Metals (800 MPa급 고강도강 용접금속의 미세조직 특성 비교 연구)

  • Lee, Jae-Hee;Kim, Sang-Hoon;Yoon, Byung-Hyun;Kim, Hwan-Tae;Kil, Sang-Cheol;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.29 no.1
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    • pp.65-73
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    • 2011
  • Microstructural characteristics of two high strength (600 MPa & 800 MPa) weld metals produced by flux-cored arc welding process (FCAW) were evaluated. The 600 MPa grade weld metal was consisted of 75% acicular ferrite and 25% ferrite which was formed at relatively high temperature (grain boundary ferrite, widmanstatten ferrite, polygonal ferrite). However, the 800 MPa grade weld metal was composed of about 85% acicular ferrite and 15% low temperature forming phases (bainite, martensite). The prior austenite grain size of 800 MPa grade weld metal was decreased by solute drag force. The compositions and sizes of inclusions which are the dominant factors for the formation of acicular ferrite were analyzed by a transmission electron microscopy (TEM). In both 600 MPa and 800MPa grade weld metals, the inclusions were mainly consisted of Ti-oxide and Mn-oxide, and the average size of inclusions was $0.7{\mu}m$. The 800 MPa grade weld metal exhibited higher tensile strength and similar toughness compared with the 600 MPa grade weld metal. This result is mainly due to a higher fraction of low temperature products and a lower fraction of grain boundary ferrite in the 800 MPa grade weld metal.

Application of RO Membrane Process for Reuse of MBR Effluent (MBR 유출수 재활용을 위한 RO 막분리 공정에 대한 연구)

  • Yoon, Hyun-Soo;Kim, Jong-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.4
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    • pp.1391-1398
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    • 2010
  • Reuse feasibility of MBR effluent of S Electronic Company's organic wastewater as a LCD process water was investigated by a $32m^3/d$ pilot-scale RO membrane process. The effects of operating pressure and permeate flux at constant 85% recovery of RO membrane process using MBR effluent were analyzed for transmembrane pressure and period for CIP by membrane fouling as well as rejection of TOC and conductivity. MBR effluent requires additional treatment to meet the LCD process water quality criteria of TOC<1 mg/L and conductivity<$100{\mu}S/cm$ which is stringent as compared with those of conventional reuse water quality criteria. The RO process operated at 85% recovery with stepwise increasing of permeate fluxes from 12.5 LMH to 22.0 LMH was able to meet LCD process water quality criteria. However, the transmembrane pressure increased and the period of CIP decreased as increasing permeability fluxes due to fouling of RO membrane. The optimum operational conditions of RO membrane process were permeate fluxes of 16.5~18.5 LMH with operating pressure of $6.7{\sim}12.4kgf/cm^2$ and CIP period of 20~25 days at constant 85% recovery.

Treatment of AP Solutions Extracted from Solid Propellant by NF/RO Membrane Process (NF/RO 멤브레인 공정을 적용한 고체추진제에서 추출된 암모늄 퍼클로레이트 (AP) 처리 연구)

  • Kong, Choongsik;Heo, Jiyong;Yoon, Yeomin;Han, Jonghun;Her, Namguk
    • Membrane Journal
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    • v.22 no.4
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    • pp.235-242
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    • 2012
  • Ammonium perchlorate (AP) is primarily derived from the process of liquid incineration treatment when dismantling a solid rocket propellant. A series of batch dead-end nanofiltration (NF) and reverse osmosis (RO) membrane experiments were conducted to explore the retention mechanisms of AP under various hydrodynamic and solution conditions. Low levels of silicate type of siloxane had been detected through the GC/MS and FTIR analysis of liquid solutions extracted from solid ammonium perchlorate composite propellant (APCP). It is indicated that NF/RO membranes fouling in the presence of APCP was mainly attributed to the AP interactions because the concentration of silicate type of siloxane was negligible compared to that of AP. The osmotic pressure of AP was presumably resulted in the flux declines ranging from 13 to 17% in the case of the application of low-pressure (551 and 896 kPa for NF and RO) compared to those in application of high-pressure. The retention of AP by NF/RO membranes significantly varied from approximately 10 to 70% for NF and 26 to 87% for RO, depending on the operating and solution water chemistry conditions. The results suggested that retention efficiency of AP was fairly increased by reducing concentration polarization (i.e. application of low-pressure and stirring speed of 600 rpm) and increasing the pH of a solution. The result of this study was also consistent with the previous modeling of 'solute mass transfer of NF/RO membranes' and demonstrated that hydrodynamic and solution water chemistry conditions are to be a key factor in the retention of AP by NF/RO membranes.

New Method of Computing the Stokes Drift Including Shear Effect in the Cross-Sectional Flow Field (유수단면 흐름장에서 Shear 효과를 갖는 Stokes Drift의 계산법)

  • Kim, Jong-Hwa;Park, Byong-Su
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.33 no.1
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    • pp.9-26
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    • 1997
  • Stokes drift(SD) and Lagrangian discharge(LD) are important factors for analysis of flushing time, tidal exchange, solute transport and pollutant dispersion. The factors should be calculated using the approached method to flow phenomena. The aim of this paper re-examines the previous procedures for computing the SD and LD, and is to propose the new method approached to stratified flow field in the cross-section of coastal region, e.g. Masan Bay. The intensity of velocity near the bottom boundary layer(BBL) depends on the sea-bed irregularity in the coastal estuaries. So we calculated the depth mean velocity(DMV) considering that of BBL omitted in Kjerfve's calculation method. It revealed that BBL effect resulting in application of the bay acts largely on DMV in half more among 1l stations. The new expression of SD and LD per unit width in the cross-section using the developed DMV and proposed decomposition procedure of current were derived as follow : $$Q=u_0+\frac{1}{2}H_1{U_1cos(\varphi_h-\varphi_u)+U_3cos(\varphi_h-\varphi{ud})} LD ED SD$(Q_{skim}+Q_{sk2}) The third term, $Q_{sk2}$, on the right-hand of the equation is showed newly and arise from vertical oscillatory shear. According to the results applied in 3 cross-sections including 11 stations of the bay, the volume difference between proposed and previous SD was founded to be almost 2 times more at some stations. But their mean transport volumes over all stations are 18% less than the previous SD. Among two terms of SD, the flux of second term, $Q_{skim}$, is larger than third term, $Q_{sk2}$, in the main channel of cross-section, so that $Q_{skim}$ has a strong dependence on the tidal pumping, whereas third term is larger than second in the marginal channel. It means that $Q_{sk2}$ has trapping or shear effect more than tidal pumping phenomena. Maximum range of the fluctuation in LD is 40% as compared with the previous equations, but mean range of it is showed 11% at all stations, namely, small change. It mean that two components of SD interact as compensating flow. Therefore, the computation of SD and LD depend on decomposition procedure of velocity component in obtaining the volume transport of temporal and spacial flow through channels. The calculation of SD and LD proposed here can separate the shear effect from the previous SD component, so can be applied to non-uniform flow condition of cross-section, namely, baroclinic flow field.

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