• 제목/요약/키워드: Soluble Polymer

검색결과 473건 처리시간 0.021초

Quenching of Water Soluble Conjugated Polymer by Electrostatic Interaction

  • Jin, Youngeup
    • Bulletin of the Korean Chemical Society
    • /
    • 제33권11호
    • /
    • pp.3593-3596
    • /
    • 2012
  • The water-soluble conjugated polymer with fluorescence quenching as a result of electrostatic interaction and aggregation was synthesized through Suzuki polymerization. The absorption and emission of anionic polymer (a-PFP) is blue shifted as compared with cationic polymer (c-PFP) although getting same backbone, and the absolute PL quantum efficiency of a-PFP in water is over 90% due to good solubility in aqueous solution. We anticipate that the fluorescence quenching of anionic and cationic polymers, with same conjugated backbone, could be shown in aqueous solution.

인테리어용 인조가죽을 위한 용출형 극세사와 저온 융착사의 제조 (Manufacture of Soluble Micro-fiber and Low Melting Polymer for Interior Synthetic Leather)

  • 안영무
    • 한국생활과학회지
    • /
    • 제12권4호
    • /
    • pp.529-537
    • /
    • 2003
  • This study was conducted to manufacture the soluble micro-fiber and to synthesize low melting polymer for the interior fabric not to use the polyurethane resin causing some problems. Low melting polyester for weft yarn was introduced by adding 30-40 mol% ratio of isophthalic acid to a main chain of polyethylene terephthalate to decrease the melting temperature up to heat setting temperature. Micro-fiber for warp yarn consisted of both soluble and insoluble components with multi-layered structure. When the soluble micro-fiber was treated by alkaline hydrolysis with 3-5% concentration of NaOH, it showed the turning point at 28% weight loss since soluble polyester was hydrolyzed approximate five times faster than regular polyester.

  • PDF

Enhancement of the Escherichia coli Floc Strength with Water Soluble Polymers

  • KIM, CHAN-WHA;CHOKYUN RHA
    • Journal of Microbiology and Biotechnology
    • /
    • 제7권4호
    • /
    • pp.282-286
    • /
    • 1997
  • The floc strength of Escherichia coli was enhanced by adding water soluble polymer flocculants (BPA-5020 and BPA-5000) to the particulate flocculant (BPA-1000) as indicated by the increase in the shear index. The shear index of the E. coli flocs increased from 0.39 with the particulate flocculant alone to 0.94 with the particulate flocculant in conjunction with the water soluble polymer flocculant. In addition, the sedimentation rate of flocs was higher and the sedimented volume of flocs was smaller when the particulate flocculant was used with the water soluble polymer flocculant. When E. coli was flocculated first with the water soluble flocculant and the particulate flocculant was added later into the E. coli flocs formed, the sedimentation rate of the flocs was greater than that of any other combination. The shear index of the flocs was, however, independent of the sequence of the flocculant addition.

  • PDF

지반함몰 긴급복구용 수용성 폴리머 파우치의 기계적 물성강화 (Mechanical Property Enhancement of Water Soluble Polymer Pouch for Ground Reinforcement)

  • 정동호;정다솜;유승경;김주헌;한중근
    • 한국지반신소재학회논문집
    • /
    • 제16권4호
    • /
    • pp.221-230
    • /
    • 2017
  • 선행 연구에서 PVP를 이용하여 수용성 폴리머 파우치를 개발하였다. 그러나 개발된 재료의 용융점이 매우 낮아 재료의 성형 시 문제점이 많아 대량생산 시 필요한 성형, 제작이 불가능하였기에 성형성이 우수한 새로운 재료 조합을 이용하여 폴리머 파우치를 개발하였다. 새롭게 선정된 PEG의 수용성 변화 및 지반공동 내 보강 시 파우치의 기계적 물성을 만족해야한다. 따라서 PEG와 LLDPE, TALC 블렌딩 비율에 따른 특성평가를 실시하였는데 각 원료의 비율에 따라 발생하는 성질이 다르기 때문에 실험을 통해 적정 비율을 찾는 것이 중요하기 때문이다. 이러한 블렌딩을 통해 수용성 특성은 유지하며 인장 및 충격강도가 증진된 폴리머 파우치를 개발하였다. 최종 개발된 제품을 이용하여 직접전단 실험을 실시한 결과, 폴리머 파우치의 지반강도 효과를 확인할 수 있었다.

Effects of sodium lauryl sulfate on the encapsulation of ethanol by spray-drying technique

  • Lee, Sa-Won;Kim, Chong-Kook
    • 한국응용약물학회:학술대회논문집
    • /
    • 한국응용약물학회 1996년도 춘계학술대회
    • /
    • pp.288-288
    • /
    • 1996
  • The microcapsules containing ethanol in a water-soluble polymer shell could be formed by the spray-drying technique. A mixed solution of ethanol, water and a water-soluble polymer is spray-dried at the lowest possible temperature to obtain a powder product in which the water is substantially removed and the ethanol is encapsulated in water-soluble polymer shell because of the hydrophillic property of polymer and permeability difference between ethanol and water. In this study, the effect of sodium lauryl sulfate (SLS) on the ethanol content, ethanol encapsulation efficiency and yield were investigated to maximize the microencapsulation of ethanol.

  • PDF

수용성 고분자를 이용한 열화한지의 보강처리 (Strengthening Treatment of Aged Hanji with Water Soluble Polymers)

  • 김강재;이민형;엄태진
    • 펄프종이기술
    • /
    • 제43권5호
    • /
    • pp.1-10
    • /
    • 2011
  • In this study, 13 water soluble polymers(6 natural polymer, 7 synthetic polymer) were treated on Hanji. Mechanical properties, morphology and oxidation index with thermal aging were measured on the aged Hanji, dewaxed Hanji and polymer treated Hanji. 3 natural polymer(such as CMC, EC, MC) and 3 synthetic polymers(such as PVA 1500, 2000, PEG 1500) treated Hanji had higher strength than other polymer treated Hanji. The oxidation index of 3% methyl cellulose solution treated Hanji did a little increase with thermal aging. Finally, methyl cellulose was found to be the most efficient method for strengthening the dewaxed Hanji. The best aging safety and thermal stability were obtained at the methyl cellulose 3% water solution.

LCD 컬러 필터용 알칼리 가용성, 감광성 폴리에스터의 합성과 물성 (Synthesis and Properties of Alkali-Soluble and Photosensitive Polyester Derivatives for LCD Color-Filter)

  • 이상훈;조영곤;김주성;배진영
    • 폴리머
    • /
    • 제31권5호
    • /
    • pp.442-446
    • /
    • 2007
  • 알칼리 가용성, 광경화형 폴리에스터를 합성하기 위해 플루오렌형 에폭시 아크릴레이트에 다양한 산 2 무 수물을 반응시켰다. LCD (liquid crystal display) 컬러 필터용 블랙매트릭스를 제조하기 위해서 합성된 폴리에스터와 카본블랙 등을 혼합하여 포토레지스트 용액을 조제한 후 리소그래피 공정을 통해 유리 기판 위에 블랙매트릭스패턴을 형성하였다. 합성된 다양한 폴리에스터의 특성과 리소그래피 패턴을 비교 조사하였다.

Novel Water-Soluble Polyfluorenes as an Interfacial layer leading to Cathodes-Independent High Performance of Organic Solar Cells

  • 오승환;심희상;박동원;정연길;이재광;문승현;김동유
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
    • /
    • pp.394-394
    • /
    • 2009
  • Water solubility of conjugated polymers may offer many applications. Potential applications of water-soluble conjugated polymers include the polymer light-emitting diode and new materials for nano and micro hollow-capsules, and bio- or chemo-sensors. We synthesized neutral polyfluorenes containing bromo-alkyl groups by the palladium catalyzed Suzuki coupling reaction. Bromo-alkyl side groups in neutral polyfluorenes were quaternized by tri-methyl amine solution. The electrochemical and optical properties of water-soluble conjugated polymers are discussed. This novel synthesized water-soluble conjugated polymers were used as a interfacial dipole layer between active layer and metal cathode in polymer solar cell for enhancement of open-circuit voltage (Voc), which is one of the most critical factors in determining device characteristics. We also investigated the device performance of polymer solar cell with different metal cathode such as Al, Ag, Au and Cu. In polymer solar cell, novel cationic water-soluble conjugated polymers were inserted between active layer and high-work function cathode (Al, Ag, Au and Cu).

  • PDF