• Title/Summary/Keyword: Solidification.

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Metallurgical Refinement of Multicrystalline Silicon by Directional Solidification (일방향 응고법에 의한 다결정 실리콘의 야금학적 정련)

  • Jang, Eunsu;Park, Dongho;Yu, Tae U;Moon, Byung Moon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.111.1-111.1
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    • 2011
  • The solar energy is dramatically increasing as the alternative energy source and the silicon(Si) solar cell are used the most. In this study, the improved process and equipment for the metallurgical refinement of multicrystalline Si were evaluated for the inexpensive solar cell. The planar plane and columnar dendrite aheadof the liquid-solid interface position caused the superior segregation of impurities from the Si. The solidification rate and thermal gradient determined the shape of dendrite in solidified Si matrix solidified by the directional solidification(DS) method. To simulate this equipment, the commercial software, PROCAST, was used to solve the solidification rate and thermal gradient. Si was vertically solidified by the DS system with Stober process and up-graded metallurgical grade or metallurgical grade Si was used as the feedstock. The inductively coupled plasma mass spectrometry (ICP) was used to measure the concentration of impurities in the refined Si ingot. According to the result of ICP and simulation, the high thermal gradient between the two phases wasable to increase the solidification rate under the identical level of refinement. Also, the separating heating zone equipped with the melting and solidification zone was effective to maintain the high thermal gradient during the solidification.

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A study on the S/W application for a riser design process for fabricating axisymmetric large offshore structures by using a sand casting process

  • Seo, Hyung-Yoon;Seo, Pan-Ki;Kang, Chung-Gil
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.11 no.1
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    • pp.462-473
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    • 2019
  • The effects of the location and dimension of the gate, location, and volume of the feeder, application of a chill, chill volume, and heating method of the feeder with respect to the effect of the mold-designing technologies on the defect status of the products are described. It is possible to increase the solidification time of the feeder by heating feeder. Furthermore, the pressure generated from the feeder is imposed on a product, and this decreases the generation of shrinkage porosities. In this study, two types of gating and feeding systems had been proposed: the bottom L-type junctions and the top L-type junctions. Additionally, solidification behaviors, such as solidification time, shrinkage porosities, weight percentage of chill system to product, hot spot, and solidification time ratio (=Solidification time of feeder/solidification time of product), are extensively analyzed by using commercial casting simulation software. Based on the solidification behaviors, reasonable mold design, feeding system, critical feeder heating temperature, and solidification time ratios are proposed in the sand casting process for the fabrication of carrier housing in order to reduce the casting defects and to increase the recovery rate.

Solidification Cracking Behavior in Austenitic Stainless Steel Laser Welds (Part 2) -Effects of δ-ferrite Crystallization and Solidification Segregation Behavior on Solidification Cracking Susceptibility- (오스테나이트계 스테인리스강 레이저 용접부의 응고균열 거동 (Part 2) - δ 페라이트 정출 및 응고편석 거동에 따른 응고균열 민감도 변화 -)

  • Chun, Eun-Joon;Lee, Su-Jin;Suh, Jeong;Kang, Namhyun;Saida, Kazuyoshi
    • Journal of Welding and Joining
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    • v.34 no.5
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    • pp.61-69
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    • 2016
  • A numerical simulation of the solid/liquid coexistence temperature range, using solidification segregation model linked with the Kurz-Giovanola-Trivedi model, explained the mechanism of the BTR shrinkage (with an increase in welding speed) in type 310 stainless steel welds by reduction of the solid/liquid coexistence temperature range of the weld metal due to the inhibited solidification segregation of solute elements and promoted dendrite tip supercooling attributed to rapid solidification of laser beam welding. The reason why the BTR enlarged in type 316 series stainless welds could be clarified by the enhanced solidification segregation of impurity elements (S and P), corresponding to the decrement in ${\delta}-ferrite$ crystallization amount at the solidification completion stage in the laser welds. Furthermore, the greater increase in BTR with type 316-B steel was determined to be due to a larger decrease in ${\delta}-ferrite$ amount during welding solidification than with type 316-A steel. This, in turn, greatly increases the segregation of impurities, which is responsible for the greater temperature range of solid/liquid coexistence when using type 316-B steel.

Formation of Solidification and Eutectic Microstructures with Solidification Rates in the Single Crystal Superalloy CMSX 10 (단결정 초내열합금에서 응고속도에 따른 응고 및 공정조직의 형성 거동)

  • Lee, Je-Hyun
    • Korean Journal of Materials Research
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    • v.18 no.11
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    • pp.577-582
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    • 2008
  • Directional solidification experiments were carried out at $1-300\;{\mu}m/sec$ solidification rates in the single crystal superalloy, CMSX 10. The solid/liquid interface morphology changed from planar to dendritic, and the dendrite spacing became finer as the solidification rate increased. The pool size of the ${\gamma}/{\gamma}'$ eutectic, formed between dendrites, reduced as the solidification rate increased. The phase formation temperatures, such as the solidus, liquidus and eutectic, were estimated by differential scanning calorimetry (DSC) analysis. The morphology of the ${\gamma}/{\gamma}'$ phase, known to be eutectic, showed ${\gamma}'$ cells with a $\gamma$ intercellular network, and this ${\gamma}/{\gamma}'$ was composed of coarse and fine ${\gamma}/{\gamma}'$ regions. In this study, it is suggested that the ${\gamma}/{\gamma}'$ phase was a coupled peritectic.The solidification procedure of the ${\gamma}/{\gamma}'$ between dendrites is also discussed.

A Numerical Study of Turbulent Flow, Heat Transfer, and Solidification in Twin-Roil Continuous Casting (쌍롤 연속 주조에서의 난류 유동, 온도 및 응고 예측을 위한 연구)

  • Ha, Man Yeong;Choi, Bong Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.1
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    • pp.12-24
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    • 1999
  • A computer program has been developed for analyzing the two-dimensional, unsteady conservation equations for transport phenomena in the molten region of twin-roll continuous casting in order to predict the turbulent velocity, temperature fields, and solidification process of the molten steel. The energy equation of the cooling roll is solved simultaneously with the conservation equations of molten steel in order to consider heat transfer through the cooling roll. The results show the velocity, temperature and solidification pattern in the molten region with roll temperature as a function of time. The results for velocity and temperature fields with solidification are compared with those without solidification, giving different thermofluid characteristics in the molten region. We also investigated the effects of revolutional speed of roll, superheat and nozzle geometry on the turbulent flow, temperature and solidification in the molten steel and temperature fields in the cooling roll.

Unidirectional Solidification of $Al-CuAl_2$ Eutectic Composites under Forced Convection by Vibration (진동하에서 일방향응고 시킨 $Al-CuAl_2$ 공정복합재료의 응고에 관한 연구)

  • Lee, Hyun-Kyu;Lee, Kil-Hong
    • Journal of Korea Foundry Society
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    • v.18 no.3
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    • pp.234-239
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    • 1998
  • Unidirectional solidification of $Al-CuAl_2$ eutectic composites was studied under the condition of forced convection by vibration. It has been shown that thermal gradient for solid is different from that for liquid during solidification under force convection by vibration. With increase of vibration, mobility of liquid increases, but decreases with decreasing vibration. The rate of solidification is very high initially, and decreases suddenly. For further solidification, the rate of solidification decrceases slowly, and shows a L-type behavior. The mechanical vibration during solidification effects efficiently on nucleation, and induces a forced convection in liquid. By the forced convection, great thermal gradient of liquid interface between solid and liquid can be obtained. The amount of solute near the interface also decreases as solute distribution is improved by the forced convection.

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A Study on the Solidification Characteristics of CV Graphite Cast Iron (CV흑연주철(黑鉛鑄鐵)의 응고특성(凝固特性)에 관한 연구(硏究))

  • Chun, C.C.;Kim, S.Y.;Lee, G.W.
    • Journal of Korea Foundry Society
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    • v.5 no.3
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    • pp.5-12
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    • 1985
  • Many researchers have studied the eutectic solidification of CV Graphite Cast Iron qualitatively. However quantative studies have not been done. The type of eutectic solidification of CV Graphite Cast Iron treated with CG Alloy (Fe-Si-Mg-5Ti-Ca-Ce) was studied quantitatively through M.D.E. value (Mushy Degree of Eutectic Solidification) = $t_2/t_1)$, where $t_1$ is the difference of the eutectic solidification starting time between surface and center part of the casting sample, and $t_2$ is the time of eutectic solidification of the center part. Following results were obtained. (1) The M.D.E. value of CV graphite cast iron lies between that of spheroidal graphite and that of flake graphite cast iron but is closer to that of Flake graphite cast iron. (2) The M.D.E. value of CV graphite cast iron depends upon CV ratio. (3) The time required for eutectic solidification increases as graphite form is changed from Flake, CV. to spheroidal graphite. (4) The M.D.E. value increases as cooling rate increases.

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Heat Conduction of the Solidification Process in a Cylinder with Finite Thichness (유한두께를 가지는 원형관내의 응고과정의 열전도)

  • ;;Ro, Sung Tack
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.1 no.4
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    • pp.196-202
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    • 1977
  • The solidification process in a cylinder with finite thickness in studied by explicit finite difference method. The temperature distribution, the solidification front profile and the dischrged latent heat for the process are obtained. It is found that the solidification front profile is almost linear except in the vicinity of the initation of phase change. This result motivates us to use linear relations between the position of solidification and time for approximate calculations.

A Study on the Cracking Behavior in the Welds of Ni-Cr-Fe and Ni-Fe-Cr-Mo Alloys Part I : Solidification Cracking in the Fusion Zone (Ni-Cr-Fe 및 Ni-Fe-Cr-Mo계 합금의 용접부 균열특성에 관한 연구 Part I : 용착금속의 응고균열)

  • 김희봉;이창희
    • Journal of Welding and Joining
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    • v.15 no.4
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    • pp.78-89
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    • 1997
  • This study has evaluated the weld metal solidification cracking behavior of several Ni base superalloys (Incoloy 825, Inconel 718 and Inconel 600). Austenitic stainless steels(304, 310S) were also included for comparison. In addition, a possible mechanism of solidification cracking in the fusion zone was suggested based on the extensive microstructural examinations with SEM, EDAX, TEM, SADP and AEM. The solidification cracking resistance of Ni base superalloys was found to be far inferior to that of austenitic stainless steels. The solidification cracking of Incoloy 825 and Inconel 718 was believel to be closely related with the Laves-austenite (Ti rich in 825 and Nb rich in 718) and MC-austenite eutectic phases formed along the grain boundaries during solidification. Cracking in Inconel 600 was always found along the grain boundaries which were enriched with Ti and P. Further, solidifidcation cracking resistance was dependent not only upon the type of love melting phases but also on the amount of the phases along the solidification grain boundaries.

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Austenite Precipitation Behaviors with Solidification Rate and N Solubility in Cast Duplex Stainless Alloys (주조용 이상스테인리스강에서 응고속도 및 질소고용도에 따른 오스테나이트 석출 거동)

  • Lee, Jong-Yeop;Lee, Je-Hyun;Kim, Sang-Sik;Choi, Byung-Hak;Kim, Sung-Jun;Son, Hee-Young
    • Korean Journal of Materials Research
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    • v.17 no.12
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    • pp.654-659
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    • 2007
  • Austenite precipitation behavior was studied with solidification rates and alloying contents, N and Cr, in duplex stainless steels by directional solidification. Directional solidification experiments were carried out with solidification rates, $1{\sim}100mm/s$, and N and Cr contents, $0{\sim}0.27wt.%,\;25{\sim}28wt.%$ respectively, in a duplex stainless steel, CD4MCU. As the solidification rate increases, the dendrite spacing reduced and the austenite phase in the ferrite matrix became finer. The volume fraction of austenite phase increased and its shape went to be round with increasing nitrogen contents in duplex stainless alloys. The Cr alloying element, even though it is a ferrite former, showed to enhance the nitrogen solubility in the alloy and caused the austenite round and finer. Also, Cr was supposed to decrease the austenite volume fraction, but it increased the austenite slightly due to increasing nitrogen solubility during solidification.