• Title/Summary/Keyword: Solidification process

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Application of reflow soldering method for laminated high temperature superconductor tapes

  • Lee, Nam-Jin;Oh, Sang-Soo;Kim, Ho-Sup;Ha, Dong-Woo;Ha, Hong-Soo;Ko, Rock-Kil;Shin, Hyung-Seop;Youm, Do-Jun
    • Progress in Superconductivity and Cryogenics
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    • v.12 no.2
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    • pp.9-12
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    • 2010
  • A lamination system using reflow soldering was developed to enhance the mechanical properties of high temperature superconductor (HTS) tape. The laminated coated conductor tape was fabricated using the continuous lamination process. The mean, maximum, and minimum tensile loads in a T-peel test of the laminated coated conductor were 9.9 N, 12.5 N, and 7.6 N, respectively. The critical current ($I_c$) distributions of the non-laminated and laminated coated conductor were compared using anon-contact Hall probe method. The transport $I_c$ nearly matched the non-contact $I_c$; however, some degraded Ic regions were found on the length of 800 cm of laminated coated conductor. We confirmed that the cause of the partially degraded $I_c$ was due to an increase in line tension by (1) solidification induced by a change of composition that usually occurs in molten brass (Cu, Zn) in solder, or (2) non-homogeneity of the thickness of the coated conductor or metal tapes. We suggest that reflow soldering is a promising method for reinforced HTS tape if the controlling solder thickness and lamination guide are modified.

Evaluation of Hydration Reactivity of Recycled Cement for the Utilization of Radioactive Waste Solidifying Materials (방사성 폐기물 고화재 활용을 위한 재생시멘트의 수화반응성 평가)

  • Choi, Yu-Jin;Kim, Ji-Hyun;Chung, Chul-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.167-168
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    • 2022
  • Recently, starting with the permanent suspension of Gori 1 in Korea, the importance of the disposal of concrete structures in nuclear power plants has emerged, and environmental and safety are required to be proved accordingly. Safe radioactive waste disposal technology that immobilizes harmful radioactive elements, which are by-products of nuclear power, inside a solid matrix and recycling measures are needed to secure an efficient waste disposal space. This study was conducted to confirm whether recycled cement generated in the process of radioactive concrete treatment can be used as a solidifying material for radioactive waste treatment. In order to simulate the concrete exposed to radiation, aqueous solutions of Di-water, CsCl 1M, and CoCl2 1M were used as blending water at W/B 0.5. Tricalcium phosphate and Prussian blue were substituted with 5 wt.% based on the weight of recycled cement as a binder to improve solidification performance, and their hydration characteristic was analyzed.

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MICROSTRUCTURE AND MECHANICAL PROPERTIES OF EQUIATOMIC AND NON-EQUIATOMIC TiMoTaNbV HIGH ENTROPY ALLOYS PREPARED USING VACUUM ARC REMELTING

  • SEONGI LEE;KWANGMIN LEE
    • Archives of Metallurgy and Materials
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    • v.65 no.4
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    • pp.1311-1315
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    • 2020
  • This study investigates the microstructures and the mechanical properties of equiatomic Ti20Mo20Ta20Nb20V20 and non-equiatomic Ti40Mo15Ta15Nb15V15 and Ti60Mo10Ta10Nb10V10 HEAs using X-ray diffraction (XRD) analysis, field emission scanning electron microscope (FE-SEM), and micro-Vickers hardness test. The specimens were fabricated using the vacuum arc remelting (VAR) process and homogenized at a temperature of 1300℃ for 4 h in a vacuum atmosphere. The determined thermodynamic parameters, Ω ≥ 1.1, δ ≤ 6.6%, and VEC < 6.87, suggested that the HEAs consisted of BCC solid solutions. XRD patterns of all the HEAs displayed single BCC phases. The difference in the solidification rate led to the micro-segregation associated with the elements Ta and Mo enriched in the dendrite arms and the elements V and Ti in the inter-dendritic regions. The HEA specimens showed a decrease in hardness with higher concentration of Ti element because the intrinsic hardness of Ti is lower as compared to the intrinsic hardness of Nb and Mo.

Changes on the Microstructure of an Al-Cu-Si Ternary Eutectic Alloy with Different Mold Preheating Temperatures (금형 예열온도에 따른 Al-Cu-Si 3원계 공정합금의 미세조직 변화)

  • Oh, Seung-Hwan;Lee, Young-Cheol
    • Journal of Korea Foundry Society
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    • v.42 no.5
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    • pp.273-281
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    • 2022
  • In order to understand the solidification behavior and microstructural evolution of the Al-Cu-Si ternary eutectic alloy system, changes of the microstructure of the Al-Cu-Si ternary eutectic alloy with different cooling rates were investigated. When the mold preheating temperature is 500℃, primary Si and Al2Cu dendrites are observed, with (α-Al+Al2Cu) binary eutectic and needle-shaped Si subsequently observed. In addition, even when the mold preheating temperature is 300℃, primary Si and Al2Cu dendrites can be observed, and both (α-Al+Al2Cu+Si) areas observed and areas not observed earlier appear. When the mold preheating temperature is 150℃, bimodal structures of the binary eutectic (α-Al+Al2Cu) and ternary eutectic (α-Al+Al2Cu+Si) are observed. When the preheating temperature of the mold is changed to 500℃, 300℃, and 150℃, the greatest change is in the Si phase, and upon reaching the critical cooling rate, the ternary eutectic of (α-Al+Al2Cu+Si) forms. If the growth of the Si phase is suppressed upon the formation of (α-Al+Al2Cu+Si), the growth of both Al and Cu is also suppressed by a cooperative growth mechanism. As a result of analyzing the Al-27wt%Cu-5wt%Si ternary eutectic alloy with a different alloy design simulation programs, it was confirmed that different results arose depending on the program. A computer simulation of the alloy design is a useful tool to reduce the trial and error process in alloy design, but this effort must be accompanied by a task that increases reliability and allows a comparison to microstructural results derived through actual casting.

Development of a New Simulation Method of Casting Process Based on a Cylindrical Coordinate System (원통좌표를 이용한 주조공정의 수치해석모델 개발)

  • Mok, Jin-Ho;Park, Seong-Joon;Lee, Jin-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.4
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    • pp.433-440
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    • 2004
  • Since the numerical analysis was adopted in the mold design, lots of computational methods have been proposed for the simulations of casting processes for the various shaped molds. Today, it is possible to simulate the filling and solidification processes of most casts using the VOF technique. Though the three-dimensional numerical model based on the Cartesian coordinate system can be applied to any shape of cast, it becomes very inefficient when the three-dimensional model is applied to the cast of axi-symmetrical shape since the control volume includes at least 11 of the physical model. In addition, the more meshes should be distributed along the circumferential boundaries of curved shape in the Cartesian coordinate system fur the better results, while such curved circumferential boundary does not need to be considered in the two-dimensional cylindrical coordinate system. This motivates the present study i.e. developing a two-dimensional numerical model for the axi-symmetrically shaped casts. The SIMPLER algorithm, the VOF method, and the equivalent specific heat method have been adopted in the combined algorithm for the flow calculation, the free surface tracking, and the phase change heat transfer, respectively. The numerical model has been applied to the casting process of a pulley, and it was proven that the mesh and time effective calculation was accomplished comparing to the calculation using three-dimensional model.

Design of Turbulent In-situ Mixing Mixer and Fabrication of Cu-TiB2 Nanocomposities (난류 용탕 In-situ 합성 믹서의 설계 및 Cu-TiB2 나노 복합재료의 제조)

  • Choi, Baek-Boo;Park, Jung-Su;Yun, Ji-Hun;Ha, Man-Young;Park, Yong-Ho;Park, Ik-Min
    • Korean Journal of Materials Research
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    • v.17 no.1
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    • pp.11-17
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    • 2007
  • Turbulent in-situ mixing process is a new material process technology to get dispersed phase in nanometer size by controlling reaction of liquid/solid, liquid/gas, flow ana solidification speed simultaneously. In this study, mixing which is the key technology to this synthesis method was studied by computational fluid dynamics. For the simulation of mixing of liquid metal, static mixers investigated. Two inlets for different liquid metal meet ana merge like 'Y' shape tube having various shapes and radios of curve. The performance of mixer was evaluated with quantitative analysis with coefficient of variance of mass fraction. Also, detailed plots of intersection were presented to understand effect of mixer shape on mixing. The simulations show that the Reynolds number (Re) is the important factor to mixing and dispersion of $TiB_2$ particles. Mixer was designed according to the simulation, and $Cu-TiB_2$ nano composites were evaluated. $TiB_2$ nano particles were uniformly dispersed when Re was 1000, and cluster formation and reduction in volume fraction of $TiB_2$ were found at higher Re.

Behavior of Graphite and Formation of Intermetallic Compound Layer in Hot Dip Aluminizing of Cast Iron (주철 - 알루미늄 합금의 Hot Dip Aluminizing시 흑연 및 금속간화합물 층의 형성 거동)

  • Han, Kwang-Sic;Kang, Yong-Joo;Kang, Mun-Seok;Kang, Sung-Min;Kim, Jin-Su;Son, Kwang-Suk;Kim, Dong-Gyu
    • Journal of Korea Foundry Society
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    • v.31 no.2
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    • pp.66-70
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    • 2011
  • Hot dip aluminizing (HDA) is widely used in industry for improving corrosion resistance of material. The formation of intermetallic compound layers during the contact between dissimilar materials at high temperature is common phenomenon. Generally, intermetallic compound layers of $Fe_2Al_5$ and $FeAl_3$ are formed at the Al alloy and Fe substrate interface. In case of cast iron, high contact angle of graphite existed in the matrix inhibits the formation of intermetallic compound layer, which carry with it the disadvantage of a reduced reaction area and mechanical properties. In present work, the process for the removal of graphite existed on the surface of specimen has been investigated. And also HDA was proceeded at $800^{\circ}C$ for 3 minutes in aluminum alloy melt. The efficiency of graphite removal was increased with the reduction of particle size in sanding process. Graphite appears to be present both in the region of melting followed by re-solidification and in the intermetallic compound layer, which could be attributed to the fact that the surface of cast iron is melted down by the formation of low melting point phase with the diffusion of Al and Si to the cast iron. Intermetallic compound layer consisted of $Fe(Al,Si)_3$ and $Fe_2Al_5Si$, the layer formed at cast iron side contained lower amount of Si.

Microstructures and Mechanical Properties of Extruded Al 7050 Billet and Ring Forged One with Large Scale

  • Bae, Dong-Su;Joo, Kyung-Hwan;Lee, Jin-Kyung;Lee, Sang-Pill;Chang, Chang-Beom;Hong, Sung-Seop;Park, Tae-Won
    • Journal of Power System Engineering
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    • v.20 no.6
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    • pp.40-45
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    • 2016
  • The manufacturing process of large scaled Al 7050 alloy is difficult for the occurrence of solidification crack during casting. The aims of this study are the evaluations of microstructure and mechanical properties of extruded Al 7050 billet and ring forged one with large scale. Large scaled Al 7050 billet was casted by direct-chill casting process. The extruded and ring forged specimens were prepared from the casted ingot after residual stress relief and homogenization heat treatment, respectively. Microstructures, hardness and tensile test of the surface, middle and center part of each specimen were performed at room temperature. Sheared and elongated type grains were observed at the edge parts of surface and center area and its aspect ratios of grains were low and similar as 0.21 while that of middle area was closed to 0.92 value in ring forged Al 7050 alloy. The mechanical properties of extruded Al 7050 alloy were superior than those of ring forged one. The hardness values of surface and center part were slightly higher than that of middle part in ring forged Al 7050 alloy.

Development of Variable Deposition manufacturing for Ethylene Vinyl Acettecopolymer (EVA를 이용한 가변 용착 쾌속 조형 공정의 개발)

  • Lee, Sang-Ho;Sin, Bo-Seong;Jeong, Jun-Ho;An, Dong-Gyu;Yang, Dong-Yeol
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.9
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    • pp.189-195
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    • 2000
  • RP techniques have their unique characteristics according to the working principles : star-stepped surface of parts due to layer-by-layer stacking low build speed caused by line-by-line solidification to fish one layer and post processing to improve surface finish etc The objective of this study is to propose a new RP technique Variable Deposition Mnanufacturing (VDM) which can make up for the disadvantages of the existing RP techniques and to develop an apparatus to implement the technique. The proposed process can greatly reduce the build time and improve the surface finish of parts generated. Experiments are carried out to obtain the range of temperature of molten material to maintain its fluidity and to investigate the effect of gas cooling on the preservation of the slopes. Some simple shapes such as a line-shape an S-shape and a circle-shape are fabricated from Ethylene Vinyl Acetatecopolymer(EVA) In order to examine the applicability of VDM to more general shapes a tensile specimen and a yo-yo shape were manufactured by the proposed RP method using EVA material as a trial approach. The current basic study shows a high potential of practical use of the proposed VDM process to prototyping of a general three-dimensional shape.

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Influence of Electrolytic KF on the Uniform Thickness of Oxide Layers Formed on AZ91 Mg Alloy by Plasma Electrolytic Oxidation

  • Song, Duck-Hyun;Lim, Dae-Young;Fedorov, Vladimir;Song, Jeong-Hwan
    • Korean Journal of Materials Research
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    • v.27 no.9
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    • pp.495-500
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    • 2017
  • Oxide layers were formed by an environmentally friendly plasma electrolytic oxidation (PEO) process on AZ91 Mg alloy. PEO treatment also resulted in strong adhesion between the oxide layer and the substrate. The influence of the KF electrolytic solution and the structure, composition, microstructure, and micro-hardness properties of the oxide layer were investigated. It was found that the addition of KF instead of KOH to the $Na_2SiO_3$ electrolytic solution increased the electrical conductivity. The oxide layers were mainly composed of MgO and $Mg_2SiO_4$ phases. The oxide layers exhibited solidification particles and pancake-shaped oxide melting. The pore size and surface roughness of the oxide layer decreased considerably with an increase in the concentration of KF, while densification of the oxide layers increased. It is shown that the addition of KF to the basis electrolyte resulted in fabricating of an oxide layer with higher surface hardness and smoother surface roughness on Mg alloys by the PEO process. The uniform thickness of the oxide layer formed on the Mg alloy substrates was largely determined by the electrolytic solution with KF, which suggests that the composition of the electrolytic solution is one of the key factors controlling the uniform thickness of the oxide layer.