• Journal of the Korean Ceramic Society
• /
• v.33 no.8
• /
• pp.889-894
• /
• 1996

This study was subjected to the stabilization of heavy metals using DSp cement. Heavy metal Cr and Pb ions were mixed with cement paste and hydration behavior and leaching property by heavy metal were exami-ned. It was found that, Cr ion accelerated the early hydration of the cement and has no accelerating effect in later hydration period. However Pb ion retarded the hydration of the cement for a early hydration periods. As a result of leaching test the quantity of leachant has a very low value and the influence of leached heavy metal effected on the environments is very weak.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2008.10a
• /
• pp.35-37
• /
• 2008

The light Mg alloys bearing the remarkably high strength, corrosion resistance and elevated temperature stability stand on the center of interest. The accomplishment so far is, however, only by alloy modification without any consideration on the rapid solidification effect. This work is to report not only the effect of rapid solidification of $MgZn_{4.3}Y_{0.7}$ alloy powders, but the extrusion behavior on the materials properties. The average grain size of the atomized powders was about $3-4{\mu}m$. The extrusion was carried out with the area reduction ratio of 10:1 to 15:1. As the ratio increased, homogeneous microstructure was obtained, and the mechanical properties such as tensile strength and elongation were simultaneously increased.

• Journal of Korea Foundry Society
• /
• v.18 no.6
• /
• pp.555-562
• /
• 1998

Modified fluid critical solid fraction method was utilized as a prediction parameter to describe the shrinkage formation including the position, shape and amount of shrinkage cavities. A numerical scheme was implemented adapting this method for the evaluation of solidification defects in various casting processes. In the present numerical code, the form of shrinkage cavity can be simultaneously determined when an isolated loop is predicted to occur by the fluid critical solid fraction method. An auxiliary parameter, shrinkage potential, was also used in order to calculate the amount of residual liquid during solidification. Solidification analysis was carried out for the validation of the present scheme. It was shown that the calculated results were in good agreement with those of practical casting runs in all of the casting processes envolved in the present research. It may be concluded that the present program successfully predicts the detailed shrinkage formation behavior without the consideration of interdendritic fluid flow analysis.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2000.10a
• /
• pp.174-177
• /
• 2000

In this paper, The bulging behavior of the solidified shell in continuously cast slabs have been numerically analyzed using three-dimensional elasto-plastic and creep finite element method Three-dimensional model has been applied in order to investigate the effect of the narrow face shell on restraining the bulging deflection. Solidification analysis are carried out by two-dimensional finite difference method. In this way, strains occurring at the solidification front near the narrow face of the slab, as well as those occurring in the board face have been computed. The adequacy of the model has been checked against the experimental results. In addition, the effect of the slab width and casting speed on the bulging are discussed.

• Proceedings of the KWS Conference
• /
• 2004.05a
• /
• pp.176-178
• /
• 2004

Gas tungsten arc welds on Al-4 wt% Cu alloys were investigated to determine effects of gravitational orientation on the weld solidification behavior. Outward convection flows in the parallel-down weld might be inhibited because of its reverse direction with respect to the gravity vector. This resulted in abnormal 'S' shape of the trailing s-1 interface and the solidification rate (Vs), which was receded toward the weld pool center. Significant influence of gravitational orientation resulted in the variation on the weld pool shape associated with convection flows, which in turn affected solidification orientation/morphology and the primary dendrite spacing(λ$_1$).

• Journal of Welding and Joining
• /
• v.10 no.3
• /
• pp.1-12
• /
• 1992

A literature review was conducted to survey informations available on the welding metallurgy of aluminum alloys and its effect on fusion weldability, especially on solidification cracking and pore formation. Solidification cracking behavior of Al weld is a complicate matter as compared to other high alloys, where a relatively simple Fe-X(most detrimental elements S, P, B, Si, etc) binary diagram can be successfully applicable. Both additive and synergistic effects of elements should be considered together. A same element play a different role from system to system. Porosity, caused by hydrogen contamination of the weld is one of the most troublesome welding problems. The primary sources of hydrogen are believed to be an absorbed moisture on the filler metal or base metal and in the shielding gas. It is extremely important that reliable quality-control procedures be employed to eliminate all possible sources of hydrogen contamination. Selection of proper process and parameters is sometimes more important than controlling of alloying elements in order to make a defect-free weld.

• Journal of Welding and Joining
• /
• v.20 no.2
• /
• pp.82-89
• /
• 2002

In order to clarify hot cracking phenomena occurred in Inconel 690 welds and it's prevention, in this study, the cracking behavior and the influence of welding variables on cracking in Inconel 690 overlay welds on Mn-Ni-Cr-Mo steel(SA 508 cl.3) for pressure vessel were investigated by using mock-up test. The main results are as follows: The cracks in Inconel 690 overlay welds were mainly generated near the start and the end part of welding beads adjacent to STS 309L welded outside of Inconel 690 welds. Most of the cracks showed typical solidification crack, and also it was assumed that there was possibility of liquation cracking in HAZ. The existence of Nb constituents or concentration of Nb was recognized on the fracture facets of the solidification cracks in the welds by SMAW. Therefore Nb was considered to be the main factor of the solidification cracking. As the weld heat input was more increased and the weld bead length was longer, the extent of cracking was more increased. Moreover the extent of cracking was considerably decreased by changing of welding sequence to the start and the end part of welds. Hot cracking in welds by GTAW was considerably decreased as compared with that of SMAW. And cracks were well generated in the Inconel 690 overlay welds adjacent to 575 309L welds. This means that the hot cracking susceptibility of Inconel 690 welds was largely varied by chemical components and/or compositions of filter metals, base metals and neighboring welds.

• Journal of Korea Foundry Society
• /
• v.20 no.5
• /
• pp.344-353
• /
• 2000

In order to find out the casting conditions of the thin wall stainless steel exhaust manifold for automobile, the melt flow and solidification behavior simulated by the Z-CAST program were evaluated, and experimental casting result on the test casting and exhaust manifold of SSC13 alloy were investigated. From the results of this study, it was shown that the calculated results on fluid flow were in good agreement with practical thin wall test castings under the same casting conditions, as pouring metal is austenitic stainless steel(SSC13) and pouring temperature is 1575, 1630, and $1665^{\circ}C$ respectively. That calculated result with designed thin wall exhaust manifold was predicted filling up into the mold cavity, and practical casting was sound. The solidification simulation was predicted shrinkages at the bosses for original exhaust manifold, and designed it without bosses was predicted no defect. Therefore practical exhaust manifold casting was sound and in good agreement with calculated solidification results.

• Journal of Powder Materials
• /
• v.21 no.5
• /
• pp.366-370
• /
• 2014

The present study demonstrates the effect of solidification condition on the pore structure in freeze drying process using the slurries of CuO/sublimable vehicles. Camphene and Camphor-45 wt% naphthalene based slurries with 14 vol% CuO powder were frozen into a mold at $-25^{\circ}C$, followed by sublimation at room temperature. The green bodies were hydrogen-reduced and sintered at $500^{\circ}C$ for 1 h. The porous Cu specimen, frozen the CuO/camphene slurry into the heated mold of the upper part, showed large pores with unidirectional pore channels and small pores in their internal wall. Also, it was observed that the size of large pores was decreasing near the bottom part of specimen. The change of pore structure depending on the freezing condition was explained by the nucleation behavior of camphene crystals and rearrangement of solid powders during solidification. In case of porous Cu prepared from CuO/Camphor-naphthalene system, the pore structure exhibited plate shape as a replica of the original structure of crystallized vehicles with hypereutectic composition.

• Journal of Advanced Marine Engineering and Technology
• /
• v.28 no.8
• /
• pp.1270-1278
• /
• 2004

This paper describes the effectiveness of laser pulse shaping in eliminating weld defects such as porosity, cracks and undercuts in pulsed Nd:YAG laser welding. A large porosity was formed in a keyhole mode of deeply penetrated weld metal of any stainless steel. Solidification cracks were present in STS 310S with above 0.017%P and undercuts were formed in STS 303 with about 0.3%S. The conditions for the formation of porosity were determined in further detail in STS 316. With the objectives of obtaining a fundamental knowledge of formation and prevention of weld defects, the fusion and solidification behavior of a molten puddle was observed during laser spot welding of STS 310S through a high speed video photographing technique. It was deduced that cellular dendrite tips grew rapidly from the bottom to the surface, and consequently residual liquid remained at the grain boundaries in wide regions and enhanced the solidification cracking susceptibility. Several laser pulse shapes were investigated and optimum pulse shapes were proposed for the reduction and prevention of porosity and solidification cracking.