• Title/Summary/Keyword: Solidification

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Microstructure and Magnetic Properties of Rapidly Solidified Nd-Fe(-Co) and Sm-Co(-Fe) Laves Compounds (급속냉각된 Nd-Fe(-Co)와 Sm-Co(-Fe)계 Laves 화합물의 미세조직과 자기특성)

  • 이우영;최승덕;양충진
    • Journal of the Korean Magnetics Society
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    • v.1 no.1
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    • pp.17-24
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    • 1991
  • Laves phases of $NdFe_2$, $Nd{(Fe_{0.5})}_2$, $SmCo_2$ and $Sm{(Fe_{0.5}Co_{0.5})}_2$ stoichiometry were prepared using a rapid solidification technology. Low temperature magnetic properties show ferromagnetic behaviors for the $Nd{(Fe_{0.5}Co_{0.5})}_2$, $SmCo_2$ and $Sm{(Fe_{0.5}Co_{0.5})}_2$Nd(Feo,Coo,) Laves compounds while a sort of spin reorientation has been suggested for the supposed composition of $NdFe_2$ alloy. This rapidly solidified $NdFe_2$ alloy is believed to consist of metastable rhombohedral $NdFe_7$ phase plus fine particles of Nd-rich phase. Some evidence of phase transition from the mixture of unstable $NdFe_7$ compound plus Nd-rich to $Nd_2Fe_{17}$ plus Fe-Nd-O phase was obtained after annealing the $NdFe_2$, alloy. The pseudo-binary Laves compound, $Sm{(Fe_{0.5}Co_{0.5})}_2$ exhibits a high coercivityof 4 kOe at room temperature with Curie temperature of $400^{\circ}C$ while the $Nd{(Fe_{0.5}Co_{0.5})}_2$ compound shows a magnetic moment of $2.8\;{\mu}_B/f.u.$.

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Magnetic Hardening of Rapidly Solidified $SmFe_{7+x}M_{x}(M=Mo,\;V,\;Ti)$ Compounds (급속냉각된 $SmFe_{7+x}M_{x}(M=Mo,\;V,\;Ti)$ 화합물에서 생성된 신 강자성상)

  • Choong-Jin Yang;E. B. Park;S. D. Choi
    • Journal of the Korean Magnetics Society
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    • v.4 no.3
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    • pp.226-232
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    • 1994
  • Rapidly solidified $SmFe_{7+x}M_{x}(M=Mo,\;V,\;Ti)$ compound were found to crystallize in the ${Sm(Fe,\;M)}_{7}$ based stable magnetic phase by introducing a second transition element into the Sm-Fe binary system. The ${Sm(Fe,\;M)}_{7}$ phase exhibits the highest Curie temperatuer ($T_{c}=355^{\circ}C$) ever Known in the Sm-Fe magnetic systems with a quite high intrinsic coercivity($_{i}H_{c}=3~6\;kOe $). The ${Sm(Fe,\;M)}_{7}$ phase remains stable even after annealing if once form during the rapid solidification. The primary reason for the high coercive force is due to the fine grain size($2000~8000\;{\AA}$)of the magnetic ${Sm(Fe,\;M)}_{7}$ matrix phase, and the enhanced Curie temperature is attributed to the extended solid-solubility of the additive transition elements in Fe matrix, which leads to volume expansion of the ${Sm(Fe,\;M)}_{7}$ cell causing an enhanced coupling constant of Fe atoms.

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Behavior Characteristics of Underground Flexible Pipe Backfilled with Lightweight Foamed Soil (경량기포혼합토로 뒷채움된 연성매설관의 거동특성)

  • Lee, Yong-Jae;Yea, Geu-Guwen;Park, Sang-Won;Kim, Hong-Yeon
    • Journal of the Korean Geosynthetics Society
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    • v.14 no.1
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    • pp.43-50
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    • 2015
  • Lightweight Foamed Soil (LWFS) is a useful material for underground pipe backfill because of reusability of excavated soil and no compaction effect. In this research, a pilot test is carried out and monitoring results are analyzed to investigate behaviors of a flexible pipe, when LWFS is applied as a backfill material. Simultaneously, they are compared with another test case which is backfilled with Saemangeum dredged soil. As a result, the vertical earth pressure of the case backfilled with LWFS slurry presents that decreases as much as 25.6% in comparison with dredged soil and it is only within 10% after solidification. In case backfilled with dredged soil, the horizontal earth pressure is more than 3.6 times of the case used by LWFS and the vertical and horizontal deformation is more than 3.2 and 2.6 times of the case, respectively. It presents excellent effects on earth pressure and deformation reduction of LWFS. The stresses measured at the upper side of the pipe generally present compressive aspects in case backfilled with dredged soil. However, they present tensile aspects in case of LWFS. It is because of negative moment occurred at the center of the pipe due to the buoyancy from LWFS slurry. Conclusively, LWFS using Saemangeum dredged soil is very excellent material to use near the area in comparison with the dredged soil. However, the countermeasure to prevent the buoyancy is required.

Characterization of the PVDF Fibers Fabricated by Hybrid Wet Spinning (하이브리드 습식 공정을 통한 PVDF 섬유의 제조 및 특성에 관한 연구)

  • Jeong, Kun;Kim, Seong-Su
    • Composites Research
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    • v.29 no.4
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    • pp.145-150
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    • 2016
  • Polyvinylidene fluoride (PVDF) as a representative polymer with the piezoelectric property has been studied since the 1960s. Crystalline structure of poly(vinylidene fluoride) polymer is composed of five different crystal structure of the polymer as a semi-crystalline. Among the various crystal structures, ${\beta}-type$ crystal exhibits a piezoelectricity because the permanent dipoles are aligned in one direction. Generally ${\beta}-form$ crystal structure can be obtained through the transformation of the ${\alpha}-form$ crystal structure by the stretching and it can increase the amount through the after treatment as poling process after stretching. ${\beta}-form$ crystal structure the PVDF fibers produced by wet spinning is formed through a diffusion mechanism of a polar solvent in the coagulation bath. However, it has a disadvantage that the diffusion path of the solvent remains as pores in the fiber because the fiber solidification occurs simultaneously with the diffusion of the polar solvent. These pores play a role in reducing effect of poling process owing to effect of disturbances acting on the polarization by the electric field. In this work, the drying method using the microwave was introduced to remove more effectively the residual solvent and the pore within PVDF fibers produced through wet-spinning process and piezoelectric PVDF fibers was produced by transformation of the remaining ${\alpha}$ form crystal structure into ${\beta}-crystal$ structure through the stretching process.

Combination of Different Numerical Methods for Efficient Thermal Stress Analysis of Casting Process (주조공정에서의 효율적인 열응력 해석을 위한 이종해석기법의 연계)

  • Kwak, Si-Young;Lim, Chae-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.8
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    • pp.1051-1057
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    • 2010
  • This paper proposes a method that involves a combination of FDM and FEM for analyzing casting process. At present, many numerical analysis methods such as FDM, FEM, and BEM are used for solving engineering problems. For a given problem, a specific method that is suited to the problem is adopted; in general, FDM or FVM is favored for problems related to fluid flow or heat transfer, and FEM is adopted in stress analysis. However, there is an increasing need for using a combined method for complex and coupled phenomena analysis. Hence, we proposed a method in which FDM and FEM are coupled in three-dimensional space, and we applied this method to analyze casting process. In the proposed method, solidification and heat transfer was analyzed by using FDM. The field data such as temperature distribution were converted into a format suitable for FEM analysis that was used for calculating thermal stress distribution. Using the proposed method, we efficiently analyzed the analysis process from the viewpoints of work and time.

The Effect of Ca Addition on Creep Behavior of As-cast Mg-8.0Zn-1.6Y Alloys with Icosahedral Phase (Icosahedral 상을 갖는 Mg-8Zn-1.6Y 합금의 크리프 거동에 미치는 Ca 첨가 영향)

  • Jung, Young-Gil;Yang, Wonseok;Kim, Shae K.;Lim, Hyunkyu;Oh, Gun-Young;Kim, Youngkyun;Kim, Do Hyang
    • Journal of Korea Foundry Society
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    • v.40 no.2
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    • pp.7-15
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    • 2020
  • The high-temperature stability of Mg-8.0Zn-1.6Y (wt.%) alloys upon the addition of Ca has been investigated by characterizing the ignition temperature, microstructure, tensile and creep properties. The ignition temperature increases with an increase in the Ca content, indicating that an addition of Ca enhances the ignition resistance of the Mg-Zn-Y alloy. The as-cast microstructures of all tested alloys mainly consisted of the dendritic α-Mg matrix and I-phase (Mg3Zn6Y) at the grain boundaries. In the Ca-added Mg-8.0Zn-1.6Y alloys, the Ca2Mg6Zn3 phase forms, with this phase fraction increasing with an increase in the Ca contents. However, a high volume fraction of the Ca2Mg6Zn3 phase rather deteriorates the mechanical properties. Therefore, a moderate amount of Ca element in Mg-8.0Zn-1.6Y alloys is effective for improving the tensile and creep properties of the Mg-Zn-Y alloy. The Mg-8.0Zn-1.6Y-0.3Ca alloy exhibits the highest tensile strength and the lowest creep strain among the alloys investigated in the present study. The creep resistance of Mg-Zn-Y-Ca alloys depends on the selection of the secondary solidification phase; i.e., when Ca2Mg6Zn3 forms in an alloy containing a high level of Ca, the creep resistance deteriorates because Ca2Mg6Zn3 is less stable than the I-phase at a high temperature.

Quality Stability of a Softened, Sea Tangle Paste by Various Hydrocolloids during Storage (Hydrocolloid를 첨가한 연화 다시마 Paste의 품질 안정성)

  • Song Jae-Chul;Park Hyun-Jeong
    • The Korean Journal of Food And Nutrition
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    • v.17 no.3
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    • pp.246-253
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    • 2004
  • This study was carried out to examine softening stability, exponent of Avrami equation, color change, sensory characteristcs during storage when hydrocolloid was added to the sea tangle paste treated with acetic acid and heat treatment. Rate constant of solidification showed the least value of 0.05 in Avrami equation. In addition hardness of the softened sea tangle paste was not changed after two days of storage in case of carrageenan. Rate of hardness in the softened sea tangle paste formulated with carrageenan exhibited the lowest value of 0.28 kg/mm/day. Heat melting spreadability of the softened sea tangle paste showed the highest value in case of carrageenan and its fluid behavior was rheopectic. Viscosity change in the sea tangle paste formulated with carrageenan was the least during storage and its significant difference at the level of p < 0.05 was exhibited. Change of L, a and b value of softened sea tangle formulated with carrageenan during storage was significantly different at level of p<0.05. Color preference, odor, cohesiveness, softerness, process compatibility and overall acceptance of softened sea tangle were revealed to be in best when carrageenan was added. When hydrocolloid was added to the softened sea tangle paste, it showed the positive result in quality and storage stability of softened sea tangle paste. It was extremely effective on softening stability when carrageenan was added to the softened sea tangle paste.

Quality characteristics of Tteokbokki (Rice Cake) depending on cultivars and particle sizes of dry-milling rice flour

  • Song, Eun-Ju;Choi, So-Ra;Song, Young-Eun;Lee, In-Sok;Lee, Ki-Kwon
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.276-276
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    • 2017
  • This study was examined to establish a conditions for producing Tteokbokki using dry-milling rice flour which can save manpower and labor time. Since the cost of producing rice flour milled in a wet condition is 500 to 700 won/kg, which is more than twice as much as that of 300 won wheat flour, it is necessary to directly make rice flour from raw rice. The dry-milling rice flour used in the experiment was produced by Air mill (Nara machinary co. ltd., Tokyo, Japan) from 5 rice cultivars (Samkwang, Dasan-1, Boramchan, Seolgaeng, Hanareum-2), which were cultivated in A-san in 2015 year. Their particle sizes were 50, 100 and $150{\mu}m$ for each cultivar, respectively. A control was a wet-milled rice flour milled with a roll mill after the rice was soaked in water for 4 hours. The moisture content of dry-milling rice flour based on cultivars was 11 ~ 12%, and added water up to 50~55% of dry-milling rice flour weight. The RVA characteristic of peak viscosity was the highest in Dasan-1 and Hanareum-2, the lowest in Seolgaeng. The setback value used as an indicator of aging was the highest in Dasan-1, therefore Dasan-1 was expected to be quick solidification, resulting in the low tendency of sensory evaluation. The damaged starch was high in Dasan-1 and Boramchan (p<0.05) compared to others. The Hunter color L were no significant among cultivars and b value increased in all cultivars of dry-milling rice flour compared with control. The hardness of dry-milling rice flour was higher than that of the control, especially Dasan-1 and Hanareum-2 were the highest. Based on the sensory evaluation, the best cultivars were Boramchan, Hanareum-2 and Samkwang. The overall preference of dry-milling rice flour was good in particle size of 50~100um.

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Effects of process parameters on encapsulations of BSA aqueous solutions into PLGA microcapsule particles using double emulsion technique (이중유화법을 통하여 BSA 수용액을 PLGA 마이크로캡슐 입자에 봉입하는 과정에서의 공정변수의 영향)

  • Kwon, Sejin;Koo, Ja-Kyung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.147-153
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    • 2018
  • PLGA microcapsule particles encapsulating BSA aqueous solutions were prepared using a water-in-oil-in-water emulsion method. The morphology, particle size, BSA encapsulating efficiency, and in-vitro release test were also studied using the microcapsule particles. In the outer aqueous phase, an emulsifier, e.g., PVA, was replaced with metal salts for surface solidification. Scanning electron microscopy (SEM) showed that the microcapsule particles had smooth surfaces and were between $1{\mu}m$ and $7{\mu}m$ in size. The microcapsule particle morphology was affected directly by the ratio between the polymer solution and inner aqueous solution, and composition of the outer aqueous solution. The factors also partially affected the BSA encapsulation efficiencies and in-vitro release rates. All the microcapsule particles showed an initial burst release through the in-vitro release test. On the other hand, the particles also showed a relatively long release period. Metal salts could be good choices to replace the emulsifier to solidify the microcapsule particle surfaces.

Study on the Thermal Buffer Mass and Phase Change Material for Thermal Control of the Periodically Working Satellite Component (주기적으로 작동하는 위성부품 열제어용 열적완충질량과 이를 대체할 상변화물질을 이용한 열제어부품의 비교연구)

  • Kim, Taig Young;Seo, Jung Gi;Hyun, Bum-Seok;Cheon, Hyeong Yul;Lee, Jang-Joon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.42 no.12
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    • pp.1013-1019
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    • 2014
  • Solid-liquid Phase Change Material(PCM) as a thermal control hardware for the electro-optical payload of low earth orbit satellite is numerically studied which can be substituted with Thermal Buffer Mass(TBM). The electro-optical module in LEO satellite is periodically work and high heat is dissipated during the imaging period, however, the design temperature range is very tight and sensitive. In order to handle this problem TBM is added and as a result the time constant of the module temperature increases. TBM is made of Al6010 and its mass directly affects the system design. To save the mass PCM is suggested in this study. The latent heat of melting or solidification is very high and small amount of PCM can play a role instead of TBM. The result shows that only 12% of TBM mass is enough to control the module temperature using PCM.