• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.23 no.10
• /
• pp.1213-1222
• /
• 1999

A finite element method is developed for calculating the temperature and enthalpy distribution and accordingly the solid, liquid and mushy zone in a three-dimensional body subjected to any heat boundary conditions. The method concurrently consider both temperature and enthalpy for consideration of the latent heat effect, differently from other methods of using a special energy balance equation for solving a mushy zone. The developed brick element has eight nodes with one degree of freedom at each node. The numerical method and procedure are verified using the results of one and two dimensional analytic solutions and by other researchers. It is shown that the present method presents a consistent and stable results in either abrupt or ranged phase change problems. Moreover, the numerical results by the present method are hardly effected by the calculation time steps which otherwise are difficult to determine in most phase change problems. Finally, as a three-dimensional application, a T-shaped body of a phase change is presented and the temperature and enthalpy variation along the time are solved.

• International Journal of Air-Conditioning and Refrigeration
• /
• v.17 no.1
• /
• pp.32-36
• /
• 2009

The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N$) of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25 wt% has the average phase change tempera ture of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

• Journal of the Korean Society of Safety
• /
• v.8 no.4
• /
• pp.207-212
• /
• 1993

Numerical inverstigation of heat transfer in phase-change energy storage devices was performed in order to aid In the design process for a finned Phase-Change Material( PCM). A simplified model based on a quasi-linear, transient, thin fin equation, which predicts the fraction of melted phase-change material, and the shape of liquid-solid interface as a function of time, is used. The model is solved by using Finite Volume Method(FVM), and the numerical results have showed good agreement with experimental data.

• Solar Energy
• /
• v.4 no.2
• /
• pp.43-49
• /
• 1984

Experiments were performed to study freezing on a finned vertical tube when either conduction in the solid or natural convection in a liquid controls the heat transfer. Conduction is the controlling mode when the liquid is at its fusion temperature, whereas natural convection controls when the liquid temperature is above the fusion value. The liquid was housed in a cylinderical containment vessel whose surface was maintained at a uniform, time-invariment temperature during a data run, and the freezing occurred on a finned vertical tube positioned along the axis of the vessel. The phase change medium was n-octacosan, a paraffin which freezes at about $61^{\circ}C$. For conduction-controlled freezing, the enhancement of the frozen mass due to finning is greatest when the frozen layer is thin and decrease as the layer grows thicker. The degree of enhancement is generally less than the surface area ratio of the finned and unfinned tube.

• Journal of Mechanical Science and Technology
• /
• v.15 no.6
• /
• pp.796-803
• /
• 2001

Numerical solutions for the convection-dominated melting in a rectangular cavity are presented. The enthalpy-porosity model is employed as the mathematical model. This model is applied in conjunction with the EIT method to detect boundary movement in a phase changing environment. The absorption and evolution of latent heat during the phase change is dealt with by the enthalpy-based energy equation. This seems to be more efficient than resolving the temperature-based energy equation. The velocity switch-off, which is required when solid changes into liquid, is modeled by the porous medium assumption. For efficiency and simplicity of the solutions procedure, this paper proposes a simple algorithm, which iterates the temperature and the liquid fraction of the cells comprising the front layer. The numerical results agree reasonably well with the experimental data and other previous works using the transformed-grid system.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.2 no.3
• /
• pp.208-217
• /
• 1990

A rectangular test section is devised by assuming two dimensional melting of a solid phase change material heated from two sides which are maintained at constant temperature and allowing a free expansion due to density difference between solid and liquid. The timewise melting shape is recorded photographically by the shadow graph method for several experimental conditions. The analysis shows that the melting process consists of four regimes. At first, the pure conduction heat transfer is dominant, and as time goes by natural convection grows and plays a role greatly. Experiments are carried out varying not only the wall temperature but height of the wall. Each effect of them on the melting process is obtained in the form of combination of dimensionless parameters, $Ste^{0.8}\;FoRa^{0.2}$. An algebraic correlation is suggested, which predicts the melted fraction well.

• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 2006.09a
• /
• pp.66-67
• /
• 2006

The master sintering curve (MSC) is derived from densification data over a range of heating rates and temperatures. To improve the accuracy, several modifications were proposed: multi-phase MSC for solid state sintering with phase changes, MSC for liquid phase sintering, and MSC with consideration of grain growth. The developed MSC models were applied to several material systems such as molybdenum, stainless steels, and tungsten heavy alloys (WHA), in order to evaluate the effect of compaction pressure, phase change, grain growth, and composition on densification, to classify regions having different sintering mechanism, and to help engineer design, optimize, and monitor sintering cycles.

• Journal of Energy Engineering
• /
• v.11 no.3
• /
• pp.262-268
• /
• 2002

The present paper investigated the effect of ultrasonic vibrations on the melting process of phase-change materials (PCM). Furthermore, the present study considered constant heat-flux boundary condition, whereas many of the previous researches had adopted constant wall-temperature condition. The results of the present study revealed that ultrasonic vibrations accompanied the effects like acoustic streaming, cavitation, and thermally-oscillating flow. Such effects are a prime mechanism in the overall melting process when ultrasonic vibrations are applied. They speed up the melting process as much as 2.5 times, compared with the result of natural melting. Also, energy can be saved by applying ultrasonic vibrations to the natural melting. In addition, temperature and Nusselt numbers over time provided a conclusive evidence of the important role of ultrasonic vibrations on the melting phenomena.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.10 no.6
• /
• pp.923-928
• /
• 1986

A set of measurements has been made for the thermal conductivity of the pure paraffin in liquid and solid phases and for the effective thermal conductivity of the paraffin with metal scrap with the aid of the heat flux meter. Ther thermopile-type heat flux meter has been designed by steady state method and the functional relation between the temperature difference of both sides and heat flux has been obtained. The measured values of thermal conductivity are compared with the existing data for the pure paraffin and with the predicated values from the suggested model in which only one empirical constant is contained. The comparison within ten percent of the volume fraction of the metal scrap in the paraffin is satisfactory.

• Korean Chemical Engineering Research
• /
• v.53 no.6
• /
• pp.672-676
• /
• 2015

Spherical phospholipid bilayers, vesicles, were formed with respect to phase of each layer via a double emulsion technique. The conversion of phosphatidylcholine (PC) to phosphatidic acid (PA) at the outer layer, caused by phospholipase D (PLD), induced a curvature change in the vesicles, which eventually led them to fuse each other. The effect of the lipid layer physical-properties on the PLD-induced vesicle fusion was investigated using the fluorescence intensity change. 8-Aminonaphthalene-1,3,6-trisulfonic acid disodium salt(ANTS) and p-Xylene-bis(N-pyridinium bromide)(DPX) were encapsulated in the vesicles, respectively, for the quantification of the fusion. The fluorescence scale was calibrated with the fluorescence of a 1/1 mixture of ANTS and DPX vesicles in NaCl buffer taken as 100% fluorescence (0% fusion) and the vesicles containing both ANTS and DPX as 0% fluorescence (100% fusion), considering the leakage into the medium studied directly in a separate experiment using vesicles containing both ANTS and DPX. It was observed that the fusion occurred to the liquid-phase of the inner layer only. The fusion behaviors were very similar for both solid and liquid of the outer layer. However, the leakage was faster for the solid-phase outer-layer than the liquid-phase outer-layer. The difference in the leakage seems to be caused by the lipid concentration and the lateral diffusivity in the layer.