• Journal of the Semiconductor & Display Technology
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• v.21 no.3
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• pp.114-118
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• 2022

The stabilized all-solid-state battery structure indicate a fundamental alternative to the development of next-generation energy storage devices. Existing liquid electrolyte structures severely limit battery stability, creating safety concerns due to the growth of Li dendrites during rapid charge/discharge cycles. In this study, a low-dimensional graphene quantum dot layer structure was applied to demonstrate stable operating characteristics based on Li+ ion conductivity and excellent electrochemical performance. Transmission electron microscopy analysis was performed to elucidate the microstructure at the interface. The low-dimensional structure of GQD-based solid electrolytes has provided an important strategy for stable scalable solid-state lithium battery applications at room temperature. This study indicates that the low-dimensional carbon structure of Li-GQDs can be an effective approach for the stabilization of solid-state Li matrix architectures.

• Journal of the Korean Wood Science and Technology
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• v.51 no.6
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• pp.481-492
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• 2023

The ecofriendly lifestyle has attracted considerable support for sustainable development. Natural dyes, as sustainable products, have become a research focus and development area for many scientists. Ecofriendly processing also supports circular sustainable development. This study effectively obtained tannins as a natural dye from merbau (Intsia bijuga) sawdust using water as an ecofriendly solvent. Merbau sawdust is an underutilized industrial waste. Temperature and solid-solvent ratio variations were performed to extract tannins from merbau sawdust. Temperature and solid-solvent ratio positively affected solution yield and tannin concentration. The optimal condition was identified using response surface methodology and experimental observations. A yield of 0.2217 g tannins/g merbau was obtained under the conditions of 333.15 K and 0.125 solid-solvent ratio. Extraction was controlled by convective mass transfer at the interface of solid particles.

• Korean Journal of Materials Research
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• v.33 no.9
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• pp.353-359
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• 2023

This study investigated the growth behavior and characteristics of compounds formed at the interface between a liquid Al-Si-Cu alloy and solid cast iron. Through microstructural analyses, it was observed that various AlFe and AlFeSi phases are formed at the interface, and the relative proportion of each phase changes when small amounts of strontium are added to the Al alloy. The results of the microstructural analysis indicate that the primary phases of the interfacial compounds in the Al-Si-Cu base alloy are Al₈Fe₂Si and Al_4.5FeSi. However, in the Sr-added alloys, significant amounts of binary AlFe intermetallic compounds such as Al₅Fe₂ and Al₁₃Fe₄ formed, in addition to the AlFeSi phases. The inclusion of Sr has a slight diminishing effect on the rate at which the interfacial compounds layer thickens during the time the liquid Al alloy is in contact with the cast iron. The study also discusses the nano-indentation hardness and micro-hardness of the interfacial phases.

• Journal of Korea Foundry Society
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• v.10 no.1
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• pp.50-56
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• 1990

Continuous casting of the $Al-Al_3Ni$: eutectic composite was carried out by the upward continuous casting process. The morphology of the eutectic growth and the stability of solid-liquid interface were investigated under various growth conditions in an upward continuous casting. The effect of growth conditions on the mechanical properties of the $Al-Al_3$ Ni eutectic composit was also investigated, and the results were compared with those by the Bridgman method. As for the results, it was possible to get the planar solid-liquid interface at the condition of $G_L/R$＝$1.04{\times}10^3^{\circ}Csec/mm^2$. And the inter-rod spacing of $Al-Al_3Ni$ eutectic composite was decreased with the increase of pulling speed. The reduction of inter-rod spacing & value of $G_L/R$ caused the increase of ultimate tensile strength in $Al-Al_3Ni$: eutectic composite. The ultimate tensile strengths of $Al-Al_3Ni$ by the upward continuous casting were higher then those by the Bridgman method.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.10
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• pp.3322-3333
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• 1996

A numerical analysis has been conducted to investigate a modified floating-zone crystal growth process in which most of the melt surface is covered with a heated ring. The crystal rod is not only pulled downward but rotated around its axisymmetric line during crystal growth process in order to produce the flat interface of crystal growth and the single crystal growth of NaNO3 is considered in 6mm diameter. The present study is made from a full-equation-based analysis considering a pulling velocity in all of solid and liquid domains and both of solid-liquid interfaces are tracked simultaneously with a governing equation in each domain. Numerical results are mainly presented for the comparison of the surface shape of rotational crystal rod with that of no-rotational crystal rod and the effects of revolution speeds of the crystal rod. Results show that the rotation of crystal rod produces more its flat surface. In addition, the shape of crystal growth near the centerline is more concaved with the increase in the revolution speed of crystal rod. The flow pattern and temperature distribution is analyzed and presented in each case. As the pulling velocity of crystal rod is increasing, the free surface of the melt below the heated ring is enlarged due to the crystal interface migrating downward.

• Journal of Korea Foundry Society
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• v.25 no.1
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• pp.30-35
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• 2005

The structures and mechanical property of the unidirectionally solidified Al-Co eutectic alloy were investigated. Al-Co eutectic alloy was unidirectionally solidified with growth rates(R) between I cm/hr and 10 cm/hr in the induction furnace maintaining the thermal gradient (G) at solid-liquid interface, $32^{\circ}C$/cm. The eutectic microstructure was varied with the growth condition(G/R ratio). When the G/R ratio was larger than $8.5{\times}10^{3}^{\circ}C/cm^{2}/sec$, a lamellar structure was formed, But the G/R ratio was smaller than $8.5{\times}10^{3}^{\circ}C/cm^{2}/sec$, a colony structure was formed. It was found that the interlamellar spacing(${\lambda}$) was dependent on the growth rate(R) with the relationship, ${\lambda}^{2}{\cdot}R=constant$. The microhardness of this eutectic alloy increased with increase in the growth rate.

• Korean Journal of Materials Research
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• v.13 no.6
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• pp.381-388
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• 2003

Directional solidification experiments were carried out at 0.5-150 $\mu\textrm{m}$/s in the Co-base superalloy ECY 768. As increasing solidification rate, the dendrite length increased and it reached the maximum at 150 $\mu\textrm{m}$/s, where the tip temperature is close to the liquidus. The liquidus and eutectic temperatures could be estimated by comparing the dendrite lengths and the temperature gradients at the solid/liquid interface and those were estimated as $1424.6^{\circ}C$ and $1343^{\circ}C$ respectively. Between the dendrites just below final freezing temperature, MC carbide and $M_{23}$$C_{6}$ carbide were found. It was confirmed that the script or blocky shape was Ta or W-rich MC carbide, and the lamellar shape was Cr-rich eutectic carbide. The solid/liquid interface morphology clearly showed that the Cr-rich eutectic carbide formed just after the script type MC carbide.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.4
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• pp.556-565
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• 1995

The physical model of interest is based upon the concentric cylinder, where the outside cylinder is filled with optically thick and high temperature phase change material(PCM). The fluid is flowing through the inside cylinder to transfer the appropriate energy. The fluid is flowing through the inside cylinder to transfer the appropriate energy. The governing equations for the phase change material including internal thermal radiation and for the turbulent transfer fluid have been employed and numerically solved. The optically thick phase change justifies the P-l spherical harmonics approximation, which is believed to be appropriate choice particularly for the much coupled problem like in this study. The solid/liquid interface, temperature distribution within the PCM and the heat flux from the PCM to the transfer fluid have been obtained and compared with those of laminar transfer fluid. The numerical results show that the turbulent transfer fluid accelerates the solid/liquid interface and results in the increase of heat transfer rate from the PCM. The internal thermal radiation within the PCM, however, does not always playa role to increase the heat transfer rate throughout the inside cylinder. It is believed that the combined heat flux has been picked up more in the inflowing area than in the pure conductive phase change material.

• Bulletin of the Korean Chemical Society
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• v.19 no.10
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• pp.1047-1054
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• 1998

We present the results of molecular dynamics simulations for three different systems of bilayers of long-chain alkyl thiol [S(CH2)15CH3] molecules on an solid-solid interface using the extended collapsed atom model for the chain-molecule. It is found that there exist two possible transitions: a continuous transition characterized by a change in molecular interaction between sites of different chain molecules with increasing area per molecule and a sudden transition from an ordered lattice-like state to a liquid-like state due to the lack of interactions between sites of chain molecules on different surfaces with increasing distance between two solid surfaces. The third system displays a smooth change in probability distribution characterized by the increment of gauche structure in the near-tail part of the chain with increasing area per molecule. The analyses of energetic results and chain conformation results demonstrate the characteristic change of chain structure of each system.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.39 no.8
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• pp.793-799
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• 2015

In this research, we study the propagation of longitudinal and transverse waves through a metal rod including a liquid layer using computational and experimental analyses. The propagation characteristics of longitudinal and transverse waves obtained by the computational and experimental analyses were consistent with the wave propagation theory for both cases, that is, the homogeneous metal rod and the metal rod including a liquid layer. The fluid-structure interaction modeling technique developed for the computational wave propagation analysis in this research can be applied to the more complex structures including solid-liquid interfaces.