• Title/Summary/Keyword: Solid-Liquid-Solid

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Microstructural Changes of $SiO_2-Si$ During Liquid-Phase Sintering (액상소결단계에서 $SiO_2-Si$의 미세조직 변화)

  • 강대갑;정충환
    • Journal of the Korean Ceramic Society
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    • v.31 no.4
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    • pp.443-447
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    • 1994
  • Compacts of mixed SiO2-Si powder were liquid phase sintered at 145$0^{\circ}C$ for up to 60 min in a hydrogen atmosphere. In contrast to the conventional microstructures of liquid phase sintered materials, the specimens showed that the solid phase of SiO2 formed a matrix while the liquid phase of Si was the dispersed in the solid matrix. The dispersion of liquid Si pockets was attributed to the high wetting angle of liquid Si on solid SiO2. Because of relatively high solubility of SiO2 in liquid Si at 145$0^{\circ}C$, SiO2 particles accommodated their shape via a solution-reprecipitation process. The liquid Si pockets grew by coalescing with their neighbour pockets. In the latter stage of the sintering, plate-shape grains appeared in the liquid Si pockets. The grains were SiO2 phase precipitated from the liquid Si which was oversaturated with oxygen during cooling to room temperature. By the formation and subsequent removal of the gaseous SiO phase due to the reaction between SiO2 and Si, the specimens became porous.

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Refining of Silicon by Fractional Melting Process (Fractional Melting에 의한 Si 정련에 관한 연구)

  • Kim, Kwi-Wook;Yoon, Woo-Young
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.598-607
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    • 1997
  • Fractional melting process involves heating an alloy within its liquid-solid region simultaneously ejecting liquid from the solid-liquid mixture. The extent of the purification obtained is comparable to that obtained in multi-pass zone refining. The new fractional melting process in which centrifugal force was used for separating the liquid from the mixture has been developed and applied to the purification of the metallic grade. Refining ratio depends on partition ratio, cake wetness and diffusion in the solid, and it was controlled by various processing parameters such as rotating speed and heating rate. The new parameter called "refining partition coefficient" has been suggested to estimate the effects of processing variables on the refining ratio. Because major impurities in MG-silicon such as Fe, Al, Ni have a low segregation coefficient, good purification effect is expected. The results of refining MG-silicon(98%) showed that 3N-Si was obtained in refined solid of 50% of the original sample.

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A Study on Friction and Wear Characteristics of Sintered W/C-35%Ni Tappets for Diesel Engine Application (디젤엔진용 소결(W/C35%Ni) 태핏의 마멸거동에 관한 연구)

  • 류병진;오세일;박맹로;양승호
    • Tribology and Lubricants
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    • v.16 no.1
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    • pp.33-38
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    • 2000
  • Abstract- In this paper tribological characteristics of solid and liquid phase sintered W/C-35%Ni tappets were investigated. Three test methods were performed to investigate the wear and surface damage mechanism of sintered tappets. First, block-on-ring wear test was performed to investigate the wear characteristics under pure sliding condition. Second, simplified cam and tappet tests (called component wear test hereafter) were carried out to simulate the real contact history of cam and tappet. Also, after the test, contact surfaces were analyzed with scanning electron microscope to study the wear mechanism. As a final screening, engine dynamo tests were performed. Results showed that in the block on ring sliding wear test, solid phase sintered specimens showed superior wear resistance to liquid phase sintered specimens. The component wear tests and engine dynamo tests also showed the same results. Therefore, in these tests, solid phase sintered tappet material revealed superior wear resistant properties to liquid phase sintered one.

Performance Study of Separator for Solid and Liquid using Rice Chaffs (왕겨를 필터로 하는 고액분리기의 성능에 관한 연구)

  • 김기선;이호근
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.2 no.2
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    • pp.19-23
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    • 2001
  • The paper presents the development of separating system from the slash with solid and liquid. The materials of filter are used rice chaffs, which are widely found in the agricultural village. The performance of separator is experimentally shown through new developed measurement apparatus. The flow rates of the system are evaluated by changing the inlet pressure of slash, thickness of filter and size of particle concentration of rice chaffs. In this work the optimal design parameters can be obtained for the separator for solid and liquid. And in the results rice chaffs filter improve the performance of separator solid and liquid.

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Behavior of Impinging Droplet on a Solid Surface for the Variation of Fuel Temperature (연료 온도 변화에 따른 평판 충돌 액적의 거동에 관한 연구)

  • Lee, Dong-Jo;Kim, Ho-Yong;Chung, Jin-Taek
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.167-173
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    • 2003
  • An experimental study on the behavior of droplets impinging on a solid flat surface was carried out in the present study. Breakup of a liquid droplet impinging on a solid surface has been investigated experimentally for various fuels with different properties. The fuel temperature and incident angle were chosen as major parameters. And fuel temperature and incident angle varied in the range from $-20^{\circ}C$ to $30^{\circ}C$ and from $30^{\circ}$ to $60^{\circ}$, respectively, were investigated. It was found that the variation of fuel temperature influences upon droplet mean diameter which were bounced out from the solid surface. As the increases of incident angle, the break-out mass flow rate increases. This causes the decrease of liquid film flow rate. The larger incident angle gives less liquid film flow rate.

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Effect of Tributylphosphine for the Solution-Liquid-Solid Synthesis of CdSe Nanowires

  • Jang, Hee Su;Lee, Jin Seok
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.590-594
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    • 2013
  • Semiconductor CdSe nanowires (NWs) can serve as model systems for investigating the physical properties of one-dimensional (1D) nanostructures and have great potential for applications in electronics and photonic nanodevices. With numerous attractions arisen from their physical properties, CdSe NWs have been synthesized by vapor-liquid-solid (VLS) methods, but they have some limitations of high reaction temperature and low production. Here, we synthesized CdSe NWs via the solution-liquid-solid (SLS) mechanisms using bismuth (Bi) covered substrates as a low-melting point catalyst and compared the products after injecting identical amount of Se and different amount of tributylphosphine (TBP). CdSe NWs have similar diameters but longer lengths with decreasing TBP, so we proposed the role of TBP as a solvent and capping agent of Se.

Characteristics of Surface Flashover on Partially Immersed of Spacer in Liquid Nitrogen (액체질소 중에서 spacer의 부분적 침적에 대한 연면 방전특성)

  • 김영석;이병성;백승명;정종만;정순용;김상현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.2
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    • pp.177-182
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    • 2000
  • Composite insulation system of liquid nitrogen and solid spacer is widely applied in high temperature superconduction power machine. This study has three step procedure. As follow, first step is composition of parallel deposited electrode and vertically deposited electrode along the direction of immersion in liquid nitrogen(LN2). Second step is investigation into surface flashover voltage of solid spacer under partially immersed in LN2, and last step is comparison the result of this research with that of fully immersed in LN2 and at cryogenic temperature gaseous nitrogen(GN2). This result presented that surface flashover voltage along solid spacer half immersed in LN2 was almost the same as that of fully immersed spacer when the thickness of spacer(t) was t<10mm. In the case of t> 10mm, however, spacer flashover voltage was equal to that obtained in GN2 at cryogenic temperature. And the immersed direction functions as role of deciding the difference of surface flashover voltage.

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Influences of Gas and Solid Particle on the Cavitation Erosion-Corrosion (케비테이션 침식-부식에 미치는 기체와 고체입자의 영향)

  • Lim, Uh-Joh;Beak, Suk-Jong;Hwang, Jae-Ho
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.29 no.2
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    • pp.124-131
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    • 1993
  • Recently. with the rapid development in large sea water systems. there occurs much interest in the study of erosion-corrosion. In this study. the mild steel(SB41) was tested by using of a erosion-corrosion test apparatus with fountain-jet and was investigated under the environments of liquid, air-liquid 2 phase flow and solid particle-liquid 2 phase flow. Main results obtained are as follows : 1. The weight loss by corrosion-erosion in air-liquid 2 phase flow are more increased than that in only liquid solution. 2. Effect of air-liquid 2 phase flow on corrosion-erosion sensitivity becomes more sensitive in natural seawater than that in distilled water. 3. The corrosion potential by corrosion-erosion in air-liquid and solid particle-liquid 2 phase flow becomes noble than that of only liquid solution.

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The Role of pd in the Unified Theory on Solid-Liquid Separation: Especially on the Cake Thickness at Hindered Sedimentation, Cake Filtration and Expression (고액분리 통합이론에서 pd의 역할: 간섭침전, 케이크 여과, 압착에서 케이크 두께를 중심으로)

  • Yim, Sung-Sam;Song, Yun-Min
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.334-342
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    • 2012
  • To know the role of 'the solid compressive pressure to the first solid layer of a cake, $p_d$' in the 'unified theory on solid-liquid separation', we analyzed extremely compressible cake formed with floc for the following three operations with our new concepts. First, the role of $p_d$ was studied in calculating the sediment thickness of floc, and in calculating the cake thickness in cake filtration performed with floc sediment. Second, we calculated the expression procedure using $p_d$. Finally, the influence of $p_d$ on cake thickness in hindered sedimentation, and on the calculation of the procedure of hindered sedimentation $p_d$ was verified. Thus the possibility of application of 'unified theory on solid-liquid separation' and the importance of $p_d$ was verified. Through these processes, new theoretical definitions of the cake filtration, expression and hindered sedimentation was established.

The Basic Insulation Characteristics of Solid-Nitrogen for Cryocooling of HTS Systems (고온초전도 시스템 냉각용 고화질소의 기초 절연 특성)

  • Choi, Jae-Hyeong;Choi, Jin-Wook;Lee, Hai-Gun;Song, Jung-Bin;Kim, Hae-Jong;Seong, Ki-Chul;Kim, Sang-Hyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.1
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    • pp.132-136
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    • 2009
  • Recently, for improvement of the magnetic field of high temperature superconductor (HTS) apparatus, many studies investigating on operating in the range of $20{\sim}65\;K$ with liquid helium or the conducting method using cryocooler are actively reviewed. Also, the cooling method using solid nitrogen as cryogen is being suggested. Since the nitrogen has very large specific heat in solid state, it is expected that it can be operated for a long time without a continuous supply of cooling energy. However, there are still insufficient data on the characteristics of solid nitrogen such as thermodynamic properties and liquid-solid phase change. Especially, there was almost no study done on the electrical insulation properties of solid nitrogen so far. In this study, solid nitrogen to find the electrical characteristics was made by using cryocooler and cryostat, and investigated the flashover discharge and breakdown. The results of this study will be useful as a basic data for electrical insulation design of the HTS system using solid nitrogen as cryogen.