• Title/Summary/Keyword: Solid surface

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Effects of Amorphous Phase Fraction on the Scratch Response of NiTiZrSiSn Bulk Meatllic Glass in the Kinetic Spraying Process (저온분사공정을 통한 NiTiZrSiSn 벌크 비정질 코팅의 비정질 분율에 따른 스크래치 반응)

  • Yoon, Sang-Hoon;Kim, Soo-Ki;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.25 no.3
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    • pp.28-36
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    • 2007
  • A bulk amorphous NiTiZrSiSn powder produced using an inert gas atomization was sprayed by kinetic spraying process that is basically a solid-state deposition process onto a mild steel substrate. They were successfully overlaid onto the mild steel substrate. In order to evaluate the tribological behavior of the kinetic sprayed NiTiZrSiSn BMG (Bulk Metallic Glass) coatings, a partially crystallized coating and a fully crystallized coating were prepared by the isothermal heat treatments. Tribological behaviors were investigated in view of friction coefficient, hardness and amorphous phase fraction of coating layer. Surface morphologies and depth in the wear tracks were observed and measured by scanning electron microscope and alpha-step. From the examination of the scratch wear track microstructure, transition from the ductile like deformation (micro cutting) to the brittle deformation (micro fracturing) in the scratch groove was observed with the increase of the crystallinity.

Numerical Simulation of Bubble and Pore Generations by Molten Metal Flow in Laser-GMA Hybrid Welding (레이저-GMA 하이브리드 용접에서 유동에 의한 기포 및 기공 형성 해석)

  • Cho, Won-Ik;Cho, Jung-Ho;Cho, Min-Hyun;Lee, Jong-Bong;Na, Suck-Joo
    • Journal of Welding and Joining
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    • v.26 no.6
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    • pp.67-73
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    • 2008
  • Three-dimensional transient simulation of laser-GMA hybrid welding involving multiple physical phenomena is conducted neglecting the interaction effect of laser and arc heat sources. To reproduce the bubble and pore formations in welding process, a new bubble model is suggested and added to the established laser and arc welding models comprehending VOF, Gaussian laser and arc heat source, recoil pressure, arc pressure, electromagnetic force, surface tension, multiple reflection and Fresnel reflection models. Based on the models mentioned above, simulations of laser-GMA hybrid butt welding are carried out and besides the molten pool flow, top and back bead formations could be observed. In addition, the laser induced keyhole formation and bubble generation duo to keyhole collapse are investigated. The bubbles are ejected from the molten pool through its top and bottom regions. However, some of those are entrapped by solid-liquid interface and remained as pores. Those bubbles and pores are intensively generated when the absorption of laser power is largely reduced and consequently the full penetration changes to the partial penetration.

A Novel Method for Calcium Hardness Control of Closed OCC Recycling System

  • Ow, Say-Kyoun;Shin, Jong-Ho;Song, Bong-Keun;Ryu, Jeong-Yong
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.164-171
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    • 1999
  • A new technique for recycling process water was developed in order to reduce the calcium hardness of the closed OCC recycling system. Calcium ions present in the white water were precipitated as calcium carbonate by a reaction with sodium carbonate and the CaCO$_3$precipitates were easily removed from the system by a dissolved air flotation(DAF) method. After the DAF stage, CO$_2$-gas was purged into the water because the pH of Na$_2$CO$_3$-treated white water was reduced to neutral by CO$_2$gas. Since CaCO$_3$precipitate tends to stick onto the fine fiber surface and then is selectively removed from the water, a proper amount of suspended solid in the process water acts as an important factor in deciding the removal efficiency. By the application of Na$_2$CO$_3$addition - DAF - CO$_2$purging to the short circulated white water the calcium hardness was significantly reduced by 92% and more. The removal of calcium ions with fine fibers led to drainage improvement, reduction of fresh water consumption, and enhanced efficiency of wet-end chemicals.

Synthesis of Few-layer Graphene Film on a Ni Substrate by Using Filtered Vacuum Arc Source Method

  • Kim, Chang-Su;Seo, Ji-Hun;Gang, Jae-Uk;Kim, Do-Geun;Kim, Jong-Guk;Lee, Hyeong-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.157-157
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    • 2011
  • Graphene has generated significant interest in the recent years as a functional material for electronics, sensing, and energy applications due to its unique electrical, optical, and mechanical properties. Much of the considerable interest in graphene stems from results obtained for samples mechanically exfoliated from graphite. Practical applications, however, require reliable and well-controlled methods for fabrication of large area graphene films. Recently high quality graphene layers were fabricated using chemical vapor deposition (CVD) on nickel and copper with methane as the source of the carbon atoms. Here, we report a simple and efficient method to synthesize graphene layers using solid carbon source. Few-layer graphene films are grown using filtered vacuum arc source (FVAS) technique by evaporation of carbon atom on Ni catalytic metal and subsequent annealing of the samples at 800$^{\circ}$C. In our system, carbon atoms diffuse into the Ni metal layer at elevated temperatures followed by their segregation as graphene on the free surface during the cooling down step as the solubility of carbon in the metal decrease. For a given annealing condition and cooling rate, the number of graphene layers is easily controlled by changing the thickness of the initially evaporated amorphous carbon film. Based on the Raman analysis, the quality of graphene is comparable to other synthesis methods found in the literature, such as CVD and chemical methods.

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State-selective Dissociation of Water Molecules on MgO Films Using LT-STM

  • Shin, Hyung-Joon;Jung, J.;Motobayashi, K.;Kim, Y.;Kawai, M.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.112-112
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    • 2011
  • The interaction of water molecules with solid surfaces has been a subject of considerable interests, due to its importance in the fields from atmospheric and environmental phenomena to biology, catalysis and electrochemistry [1,2]. Among various kinds of surfaces, a lot of theoretical and experimental studies have been performed regarding water on MgO(100), however, to date, there has been no direct observation of water molecules on MgO by scanning tunneling microscope (STM) as compared with those on metal surface. Here, we will present the direct observation and manipulation of single water molecules on ultrathin MgO(100) films using low-temperature scanning tunneling microscope (LT-STM) [3]. Our results rationalize the previous theoretical predictions of isolated water molecules on MgO including the optimum adsorption sites and non-dissociative adsorption of water. Moreover, we were able to dissociate a water molecule by exciting the vibrational mode of water, which is unattainable on metal surfaces. The enhanced residual time of tunneling electrons in molecules on the insulating film is responsible for this unique pathway toward dissociation of water.

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A Study of A Nonlinear Viscoelastic Model for Elastomeric Bushing in Automotive Suspension System (I) -Axial Mode- (차량현가장치용 일래스토메릭 부시으이 비선형점탄성 모델연구 (I) -축 방향 모드-)

  • 이성범
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.5
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    • pp.154-161
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    • 1999
  • An elastomeric bushing is a device used in automotive suspension systems to cushion the force transmitted from the wheel to the frame of the vehicle. A bushing is an elastomeric hollow cylinder which is bonded to a solid metal shaft at its inner surface and a metal sleeve at its outer suface. The relation between the force applied to the shaft or sleeve and their relative deformation is nolinear and exhibits features of viscoelasticity. Numerical solutions of the boundary value problem represent the exact bushing response for use in the method for determining the force relaxation function of the bushing. The new nonlinear viscoelastic bushing model, which is called Pipkin-Rogers model, is proposed and it is shown that the predictions of the proposed force-displacement relation are in very good agreement with the exact results. This new bushing model is thus very suitable for use in multi-body dynamics codes. The success of the present study for axial mode response suggests that the same approach be applied to other modes, such as torsional or radial modes.

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Effect of Process Conditions on the Microstructure of Particle-Stabilized Al2O3 Foam

  • Ahmad, Rizwan;Ha, Jang-Hoon;Hahn, Yoo-Dong;Song, In-Hyuck
    • Journal of Powder Materials
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    • v.19 no.4
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    • pp.278-284
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    • 2012
  • $Al_2O_3$ foam is an important engineering material because of its exceptional high-temperature stability, low thermal conductivity, good wear resistance, and stability in hostile chemical environment. In this work, $Al_2O_3$ foams were designed to control the microstructure, porosity, and cell size by varying different parameters such as the amount of amphiphile, solid loading, and stirring speed. Particle stabilized direct foaming technique was used and the $Al_2O_3$ particles were partially hydrophobized upon the adsorption of valeric acid on particles surface. The foam stability was drastically improved when these particles were irreversibly adsorbed at the air/water interface. However, there is still considerable ambiguity with regard to the effect of process parameters on the microstructure of particle-stabilized foam. In this study, the $Al_2O_3$ foam with open and closed-cell structure, cell size ranging from $20{\mu}m$ to $300{\mu}m$ having single strut wall and porosity from 75% to 93% were successfully fabricated by sintering at $1600^{\circ}C$ for 2 h in air.

Microflora Occurring in the Fermentation by Tea Fungus (Tea fungus 발효음료 제조시 발효계의 미생물상)

  • 최미애;최경호;김정옥
    • Journal of Life Science
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    • v.6 no.1
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    • pp.56-65
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    • 1996
  • Black tea extractbsupplemented with 10% sucrose was fermented by fungus at 30$\circ$C. A pellicle thick as 7$\sim$8 mm covered entire surface of the medium and the wxtract converted to acidic beverage(abbreviated below as fermented black tea) by 14 days of fermentation. It was a kind of acetic acid fermentation depending on symbiotic microorganisms. During the fermentation strains of yeasts(Saccharomyces cerevisiae and Eeniella sp.)and bacteria(Bacillus subtilis, Kurthia zopfii, Gluconobacter oxydans and Deinicoccus sp.) were isolated from aqueous layer. Contrastly to it, a bacterial strain(Acetobacter aceti) was isolated from thick pellicle. The bacteria grew as a viscouse cluster on solid agar medium differently from usual strains of A. aceti. Fermented black tea had sweet-sour taste and sweet smell.

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A Study on the Microstructure of Melt-Quenched AISI 310 Stainless Steel (단롤법으로 제조한 AISI 310 스테인레스강의 급냉 조직에 관한 연구)

  • Choi, J.H.;Oh, M.S.;J., S.S.;Lee, Y.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.1
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    • pp.19-26
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    • 1996
  • Melt-quenching of steels leads to various metallographic effects such as refinement of grain size, extension of the solid solubility of carbon and alloying elements, and is expected to improve the mechanical properties of conventional steels. Furthermore, this technique is a useful method for producing sheet directly from liquid state. And it will lend itself to development as a continuous cast process which offers significant savings in energy and product costs. The purpose of this study is to present the microstructures of melt-quenched austenitic stainless steels. As the results of this study, the morphology of melt-quenched microstructure show that the roll contact area is columnar structure, and the free surface area is dendrite structure. As the line speed increases, the ratio of $d_{colunnar}/d_{total}$ increases from 0.12 to 0.60, but the ribbon thickness decreases from $150{\mu}m$ to $30{\mu}m$.

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Numerical Analysis on Rapid Solidification of Gas-atomized Al-8wt. pct Fe Droplets (가스분무한 Al-8wt.%Fe 합금분말의 급속응고과정에 대한 수치해석)

  • Kim, Seong-Gyoon;Choi, Hoi-Jin;Ra, Hyung-Yong
    • Journal of Korea Foundry Society
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    • v.13 no.5
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    • pp.462-475
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    • 1993
  • A numerical analysis on the microstructural evolutions of microcellular and cellular ${\alpha}-aluminum$ phase in the gas-atomized Al-8wt. pct droplets was represented. The 2-dimensional non-Newtonian heat transfer and the dendritic growth theory in the undercooled melt were combined under the assumptions of a point nucleation on droplet surface and the macroscopically smooth solid-liquid interface enveloping the cell tips. It reproduced the main characteristic features of the reported microstructures quite well. It predicted a considerable volume fraction of segregation-free region in a droplet smaller than $l0{\mu}m$ if an initial undercooling larger than 100K is given. The volume fractions of the microcellular region($g_A$) and the sum of the microcellular and cellular region($g_a$) were predicted as functions of the heat transfer coefficient, h and initial undercooling, ${\triangle}T$. It was shown that $g_A$ and $g_a$, in the typical gas-atomization processes with $h=0.1-1.0W/cm^2K$, are dominated by ${\triangle}T$ and h, respectively, but for h larger than $4.0W/cm^2K$, a fully microcellular structure can be obtained irrespective of the initial undercooling.

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