• Bulletin of the Korean Chemical Society
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• 제21권9호
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• pp.913-918
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• 2000

Vanadium oxide catalyst supported on TiO2-ZrO2 has been prepared by adding Ti(OH)4-Zr(OH)4 powder to an aqueous solution of ammonium metavanadate followed by drying and calcining at high temperatures. The char-acterization ofthe prepared catalysts was performed using solid-state 51V NMR and FTIR.In thecase ofcalci-nation temperature at 773 K, vanadium oxide was in a highly dispersed state for the samples containing low loading V2O5 below 25 wt %, but for samplescontaining high loading V2O5 equal to or above 25 wt %, vana-dium oxidewas well crystallized due to the V2O5 loading exceeding the formation of monolayer on the surface of TiO2-ZrO2.The ZrV2O7 compound was formed through the reactionof V2O5 and ZrO2 at 773-973 K, where-as the V3Ti6O17 compound was formedthrough the reaction of V2O5 and TiO2 at 973-1073 K. The V3Ti6O17 compound decomposed to V2O5 and TiO2 at 1173 K, which were confirmed by FTIR and 51V NMR.

• 한국지진공학회논문집
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• 제5권4호
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• pp.83-95
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• 2001

내진상세가 적용되지 않은 철근콘크리트 교각의 거동특성 및 내진성능을 살펴보기 위해서 축소교각모형실험을 수행하였다. 횡방향 철근이 심부를 구속할 만큼 충분히 배근되어 있지 않은 중심 원형 단면의 실교각을 대상으로 기초 상단의 소성 힌지 부위에서 겹침이음이 된 주철근을 사용했을 때와 연속철근을 사용했을 경우로 구분되도록 철근상세를 결정하였다. 이에 따라 3기의 축소교각시험체를 제작하여 수직방향 축하중을 가한 상태에서 준정적 반복하중을 재하하는 실험을 수행하였다. 실험결과를 통해서 겹침이음이 있는 교각시험체는 연성거동을 하지 않지만, 겹침이음이 없이 연속철근을 사용한 교각시험체는 어느 정도의 한정연성거동을 하는 것으로 분석되었다.

• Environmental Engineering Research
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• 제19권4호
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• pp.395-399
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• 2014

Operation characteristics of the sequencing batch reactor (SBR) process with electro-flotation (EF) as a solid liquid separation method (EF-SBR) were investigated. EF-SBR process showed excellent solid-liquid separation performance which enabled to separate biosolids from liquid phase within 30 min and to extend cyclic reaction time. Although influent organic loading rate was increased stepwise from 5 to 15 g COD/day, food to microorganisms (F/M) ratio could be maintained about 0.3 g COD/g VSS/day in EF-SBR because biomass concentration could be easily controlled at desired level by EF. However, it was impossible to increase biomass concentration at the same level in control SBR (C-SBR) process because solid-liquid separation by gravity settling showed a limitation at higher mixed liquor suspended solids (MLSS) concentration with 60 min of settling time. Total chemical oxygen demand (TCOD) removal efficiency of EF-SBR process was not decreased although influent organic loading rate became 3 times higher than initial value. However, it was seriously deteriorated in C-SBR process after increasing the rate over 10 g COD/day, which was accounted for insufficient organic removal by relatively higher food to microorganisms (F/M) ratio as well as biosolids wash-out by a limitation of gravity sedimentation.

• 한국세라믹학회지
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• 제51권1호
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• pp.19-24
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• 2014

Three-layer porous alumina-mullite composites with a symmetric gradient porosity are prepared using a controlled freeze/gel-casting method. In this work, tertiary-butyl alcohol (TBA) and coal fly ash with an appropriate addition of $Al_2O_3$ were used as the freezing vehicle and the starting material, respectively. When sintered at $1300-1500^{\circ}C$, unidirectional macro-pore channels aligned regularly along the growth direction of solid TBA were developed. Simultaneously, the pore channels were surrounded by less porous structured walls. A high degree of solid loading resulted in low porosity and a small pore size, leading to higher compressive strength. The sintered porous layered composite exhibited improved compressive strength with a slight decrease in its porosity. After sintering at $1500^{\circ}C$, the layered composite consisting of outer layers with a 50 wt% solid loading showed the highest compressive strength ($90.8{\pm}3.7MPa$) with porosity of approximately 26.4%.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2010년도 제35회 추계학술대회논문집
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• pp.664-667
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• 2010

고체 추진기관은 다른 추진기관에 비해 구조가 간단하고 운용성이 좋아 전략무기의 추진기관으로 주로 사용되고 있다. 그러나 고체 추진기관의 추력형상은 추진제의 연소속도와 추진제 그레인의 연소면적에 의해 결정되며, 추진제의 외경, 길이, 무게, 충전율 등과 같은 다른 설계요소들에 의해 요구되는 추력형상의 획득에 제약을 받는다. 고체 추진기관의 이중추력 성능은 일반적으로 사거리 연장과 종말 속도 향상에 장점이 있으나 추진제 그레인의 형상만으로 성능을 획득하고자하는 경우 연소관 내 추진제의 충전율이 저하된다. 따라서 연소속도가 다른 이종추진제를 적용하여 이중추력을 획득하는 것이 유리하다. 본 연구에서는 연소속도가 다른 이종 추진제를 적용하여 소형 고체 추진기관의 내외탄도 해석 및 지상연소시험을 통해 이중추력 성능을 확인함으로써 이중추력 추진기관 개발 가능성을 확인하였다.

• Computers and Concrete
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• 제13권4호
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• pp.569-585
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• 2014

In this paper, a four-layer road structure consisting of an edge transverse crack is simulated using three-dimensional finite element method in order to capture the influence of a single-axle wheel load on the crack propagation through the asphalt concrete layer. Different positions of the vehicular load relative to the cracked area are considered in the analyses. Linear elastic fracture mechanics (LEFM) is used for investigating the effect of the traffic load on the behavior of a crack propagating within the asphalt concrete. The results obtained show that the crack front experiences all three modes of deformation i.e., mode I, mode II and mode III, and the corresponding stress intensity factors are highly affected by the crack geometry and the vehicle position. The results also show that for many loading situations, the contribution of shear deformation (due to mode II and mode III loading) is considerable.

• Steel and Composite Structures
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• 제33권3호
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• pp.463-472
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• 2019

Initial thermo-elastic and steady state creep deformation of a rotating functionally graded simple blade is studied using first-order shear deformation theory. A variable thickness model for cantilever beam has been considered. The blade geometry and loading are defined as functions of length so that one can define his own blade profile and loading using any arbitrary function. The blade is subjected to a transverse distributed load, an inertia body force due to rotation and a distributed temperature field due to a thermal gradient between the tip and the root. All mechanical and thermal properties except Poisson's ratio are assumed to be longitudinally variable based on the volume fraction of reinforcement. The creep behaviour is modelled by Norton's law. Considering creep strains in stress strain relation, Prandtl-Reuss relations, Norton' law and effective stress relation differential equation in term of effective creep strain is established. This differential equation is solved numerically. By effective creep strain, steady state stresses and deflections are obtained. It is concluded that reinforcement particle size and form of distribution of reinforcement has significant effect on the steady state creep behavior of the blade.

• 한국재료학회지
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• 제11권10호
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• pp.869-878
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• 2001

Alumina $(Al_2O_3)$ green bodies were fabricated by gel-casting using three kinds of alumina with different particle size (mean particle size: 4.6 $\mu\textrm{m}$, 0.32 $\mu\textrm{m}$, 10nm). The effects of particle size on gel-casting process and green microstructure were investigated. The optimum dispersion conditions using ammonium salt (D-3019) as dispersant were 0.2 wt% (4.63 $\mu\textrm{m}$), 0.5 wt% (0.32 $\mu\textrm{m}$), and 5.0 wt% (10 nm), in high solid loading. The optimum solid loading of each starting material for gel-casting was obtained as 59 vol% (4.63 $\mu\textrm{m}$), 57 vol% (0.32 $\mu\textrm{m}$), 15 vol% (10 nm), depending on particle size, indicating that nano-size particle (10 nm) represent lower solid loading as high specific surface area than those of other two starting materials. The drying at ambient conditions (humidity; $\thickapprox$90%) was performed more than 48hrs to enable ejection of the part from the mold and then at $120^{\circ}C$ for 2hrs in an air oven, showing no crack and flaw in the dried green bodies. The pore size and distribution of the gelcast green bodies showed the significant decrease with decreasing particle size. Green microstructure was dependent on the pore size and distribution due to the particle size, and on the deairing step. The green density maximum obtained was 58.9% (4.63 $\mu\textrm{m}$), 60% (0.32 $\mu\textrm{m}$), 47% (10 nm) theoretical density (TD), and the deairing step applied before gel-casting did not affect green density.

• 대한환경공학회지
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• 제34권9호
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• pp.583-589
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• 2012

하수슬러지의 처분 방안으로서 하수슬러지를 생활폐기물과 혼합소각시의 가능성을 타진하기 위해 전체폐기물 중 하수슬러지를 20%까지 혼합하여 실험한 결과, 열부하 및 대기오염물질(질소산화물, 황산화물)부하에 영향을 크게 주지 않는 것으로 나타났다. 생하수슬러지(함수율 78.8%) 및 건조하수슬러지(함수율 60%)를 혼합소각한 결과, 건조하수슬러지를 혼합한 경우에는 열부하변동이 거의 없었으나 생하수슬러지를 혼합소각한 경우는 열부하가 다소 낮아지는 것으로 나타나 전처리를 한슬러지 혼합소각이 평상시와 같은 운전조건으로 소각로 연소를 이룰 수 있을 것으로 판단되나 고발열 생활폐기물 발열에 의한 소각로 파손을 방지하기 위해서는 에너지 비용 및 슬러지 경화현상에 의한 국부소각 방지 등을 고려하여 생하수슬러지에 수분을 공급하여 소각하는 방안도 고려해 볼만 하다고 판단된다.

• Coupled systems mechanics
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• 제7권2호
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• pp.141-162
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• 2018

This work presents a novel model for analysis of the loading rate influence onto structure response. The model is based on the principles of nonlinear system dynamics, i.e., consists of a system of nonlinear differential equations. In contrast to classical linearized models, this one comprises mass and loading as integral parts of the model. Application of the Kelvin and the Maxwell material models relates the novel formulation to the existing material formulations. All the analysis is performed on a proprietary computer program based on Wolfram Mathematica. This work can be considered as an extended proof of concept for the application of the nonlinear solid model in material response to dynamic loading.