• 제목/요약/키워드: Solid base

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Selective Concentration and Determination of Phenol and Chlorophenols by Solid Phase Extraction

  • Jung, Min-Woo;Lee, Dai Woon;Paeng, Ki-Jung
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.535-538
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    • 1995
  • This study employs the variety of mixtures of XAD resin and active carbons as concentration base for solid phase extraction (SPE) which has been widely used to preconcentrate and purify phenol and chlorophenols in determination of environmental water samples. In this study, we employed variety of mixtures of copolymer based XAD-4 resin with active carbons. This cartridges shows advantages of both materials, such as better affinity to phenol by active carbon and better mechanical stabilities from XAD resin. The better enrichment factor, pretreatment time, recoveries and limit of detection (LOD) were achieved by the attempts to pack precolumns with both meterials for preconcentration.

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A Study on the 3D Injection Mold Design Using Unigraphics API (Unigraphics API를 이용한 사출금형의 3차원 설계에 관한 연구)

  • Kim J.H.;Moon C.S.;Hwang Y.K.;Park J.W.
    • Korean Journal of Computational Design and Engineering
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    • v.10 no.6
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    • pp.381-391
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    • 2005
  • The design methodology of injection molding die has been changed from two-dimensional drafting to three-dimensional solid modeling, which is due to many advantages over the conventional methodology in terms of design modification and data associativity. In addition to the solid modeling capability, it is required for a mold designer to utilize a database management system that facilitates efficient mold design. In the paper presented is the implementation of a software program which automatically generates three-dimensional mold-bases including standard parts and slider parts, conforming to given geometric constraints. It is based on a commercial CAD system (Unigraphics NX) along with related API (application program interface) libraries. The research is expected to reduce design efforts and simplify construction of a complex three-dimensional mold-base model that is comprised of standard parts and slider parts, by use of the three-dimensional database and automatized geometric dimensioning.

Applying a GIS to Solid and Hazardous Waste Disposal Site Selection (쓰레기매립장 부지선정을 위한 GIS 활용연구)

  • 김윤종;김원영;유일현;백종학;이현우;류중희
    • Korean Journal of Remote Sensing
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    • v.6 no.2
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    • pp.135-151
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    • 1990
  • Solid and hazardous waste disposal site selection by using GIS(Geographic Information System) is the purpose of this study. The criteria of site selection are usually defined in accordance with geological, cultural and social characteristics. Unadequate adaptation of these criteria in a site selection may cause serious problem of water and soil pollution. The environmental information for extraction of these criteria consist of a lot of data : geology, geomorphology, hydrogeology, engineering geology, cultural and social information.... GIS could be easily applied to construct of this environmental information data base, and carry out cartography simulation using overlay mapping technique(polygon overlay). ARC/INFO(GIS system) was used for these studies, and AML(ARC/INFO Macro Language) in this system provided more variable and effective methods for cartography simulation. TM(Thematic Mapper) images were used for the evaluation of land cover/use in the studied area, by using ERDAS image processing system.

Natural time period equations for moment resisting reinforced concrete structures comprising hollow sections

  • Prajapati, Satya Sundar;Far, Harry;Aghayarzadeh, Mehdi
    • Computers and Concrete
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    • v.26 no.4
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    • pp.317-325
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    • 2020
  • A precise estimation of the natural time period of buildings improves design quality, causes a significant reduction of the buildings' weight, and eventually leads to a cost-effective design. In this study, in order to optimise the reinforced concrete frames design, some symmetrical and unsymmetrical buildings composed of solid and hollow members have been simulated using finite element software SAP 2000. In numerical models, different parameters such as overturning moment, story drift, deflection, base reactions, and stiffness of the buildings were investigated and the results have been compared with strength and serviceability limit criteria proposed by Australian Standard (AS 3600 2018). Comparing the results of the numerical modelling with existing standards and performing a cost analysis proved the merits of hollow box sections compared to solid sections. Finally, based on numerical simulation results, two equations for natural time period of moment resisting reinforced concrete buildings have been presented. Both derived equations reflected higher degree of correlation and reliability with different complexities of building when compared with existing standards and relationships provided by other scholars. Therefore, these equations will assist practicing engineers to predict elastic behaivour of structures more precisely.

A Study on the Mechanical Properties of the Friction Welding with Hollow and Solid Shaft of SM45C (SM45C의 중실축과 중공축의 마찰용접 특성에 관한 연구)

  • Koo, Keon-Seop;Choe, Won-Yong
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.19 no.6
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    • pp.841-846
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    • 2010
  • The present study examined the mechanical properties of the friction welding with hollow and solid shaft of SM45, of which the diameter is 25.2mm and 33mm. Friction welding was conducted at welding conditions of 2,000rpm, friction pressure of 50MPa, upset pressure of 70MPa, friction time of 0.4sec to 1.4sec by increasing 0.2sec, upset time of 2.0 sec including variable such as friction time are following. Under these conditions, a tensile test, a hardness test and a microstructure of weld interface were studied. The results were as follows : When the friction time was 1.0 seconds under the conditions, the maximum tensile strength of the friction weld happened to be 1,094MPa, which is 120% compared with the tensile strength of SM45C base metal. The upset length linearly increased as friction time increased. According to the hardness test, the hardness distribution of the weld interface was formed from 475Hv to 739Hv. HAZ(Heat Affected Zone) was formed from the weld interface to 2mm of SM45C.

Fabrication and Characterisation of a Novel Pellicular Adsorbent Customised for the Effectvie Fluidised Bed Adsorption of Protein Products

  • Sun, Yam;Pacek, Andrzej W.;Nienow, Alvin W.;Lyddiatt, Andrew
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.6
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    • pp.419-425
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    • 2001
  • A dense pellicular solid matrix has been fabricated by coating 4% agarose gel on to dense zironia-silica(ZS) spheres by watr-in-oil emulsification . The agarose evenly laminated the ZS bead to a depth of 30㎛, and the resultin gpellicular assembly was characterised by densities up to 2.39g/mL and a mean particle dimeter of 136 ㎛. In comparative fluidisation tests, the pellicular solid phase exhibited a two-fold greater flow velocity than commercial benchmark ad-sorbents necessary to achieve common values of bed expansion. Furthermore, the perlicular parti-cles were characterised by improved qualities of chromatographic behaviour, particularly with re-spect to a three-fold increase in the apparent effective diffusivity of lysozyme within a pellicular assembly modified with Cibacron Blue 3GA. The properties of rapid protein adsorption/desorp-tion were attributed to the physical design and pellicular deployment of the reactive surface in the solid phase. When combined with enhanced feedstock throughput, such practical advantages recommend the pellicular assembly as a base matrix for the selective recovery of protein products from complex, particulate feedstocks(whole fermentation broths, cell disruptates and biological extracts).

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An analytical study on free vibration of magneto electro micro sandwich beam with FG porous core on Vlasov foundation

  • Kazem Alambeigi;Mehdi Mohammadimehr;Mostafa Bamdad
    • Advances in nano research
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    • v.15 no.5
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    • pp.423-439
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    • 2023
  • The aim of this paper is to investigate the free vibration behavior of the micro sandwich beam composing of five layers such as functionally graded (FG) porous core, nanocomposite reinforced by carbon nanotubes (CNTs) and piezomagnetic/piezoelectric layers subjected to magneto electrical potential resting on silica aerogel foundation. The effect of foundation has been taken into account using Vlasov model in addition to rigid base assumption. For this purpose, an iterative technique is applied. The material properties of the FG porous core and FG nanocomposite layers are considered to vary throughout the thickness direction of the beams. Based on the Timoshenko beam theory and Hamilton's principle, the governing equations of motion for the micro sandwich beam are obtained. The Navier's type solution is utilized to obtain analytical solutions to simply supported micro sandwich beam. Results are verified with corresponding literatures. In the following, a study is carried out to find the effects of the porosity coefficient, porous distribution, volume fraction of CNT, the thickness of silica aerogel foundation, temperature and moisture, geometric parameters, electric and magnetic potentials on the vibration of the micro sandwich beam. The results are helpful for the design and applications of micro magneto electro mechanical systems.

Efficient Macrocyclization for Cyclicpeptide Using Solid-Phase Reaction

  • Kim, Joong-Hup;Hong, Il-Khee;Kim, Hyo-Jeong;Jeong, Hyeh-Jean;Choi, Moon-Jeong;Yoon, Chang-No;Jeong, Jin-Hyun
    • Archives of Pharmacal Research
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    • v.25 no.6
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    • pp.801-806
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    • 2002
  • Cyclicpeptides are important targets in peptide synthesis because of their interesting biological properties. Constraining highly flexible linear peptides by cyclization is one of the mostly widely used approaches to define the bioactive conformation of peptides. Cyclic peptides often have increased receptor affinity and metabolic stability over their linear counterparts. We carried out virtual screening experiment via docking in order to understand the interaction between HLE-Human Leukocyte Elastase and ligand peptide and to identify the sequence that can be a target in various ligand peptides. We made cyclic peptides as a target base on Metlle-Phe sequence having affinity for ligand and receptor active site docking. There are three ways to cyclize certain sequences of amino acids such as Met-lie-Phe-Gly-Ile. First is head-to-tail cyclization method, linking between N-terminal and C-terminal. Second method utilizes amino acid side chain such as thiol functional group in Cys, making a thioether bond. The last one includes an application of resin-substituted amino acids in solid phase reaction. Among the three methods, solid phase reaction showed the greatest yield. Macrocyclization of Fmoc-Met-Ile-Phe-Gly-Ile-OBn after cleavage of Fmoc protection in solution phase was carried out to give macrocyclic compound 5 in about 7% yield. In the contrast with solution phase reaction, solid phase reaction for macrocyclization of Met-Ile-Phe-Gly-Ile-Asp-Tentagel in normal concentrated condition gave macrocyclic compound 7 in more than 35% yield.

Study on Possibility of PrBaMn2O5+δ as Fuel Electrode Material of Solid Oxide Electrolysis Cell (이중 페로브스카이트 촉매 PrBaMn2O5+δ의 고온전기분해조(Solid Oxide Electrolysis Cell) 연료극 촉매로 적용 가능성에 대한 연구)

  • Kwon, Youngjin;Kim, Dongyeon;Bae, Joongmyeon
    • Journal of the Korea Institute of Military Science and Technology
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    • v.20 no.4
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    • pp.491-496
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    • 2017
  • The hydrogen($H_2$) is promising energy carrier of renewable energy in the microgrid system such as small village and military base due to its high energy density, pure emission and convenient transportation. $H_2$ can be generated by photocatalytic water splitting, gasification of biomass and water electrolysis driven by solar cell or wind turbine. Solid oxide electrolysis cells(SOECs) are the most efficient way to mass production due to high operating temperature improving the electrode kinetics and reducing the electrolyte resistance. The SOECs are consist of nickel-yttria stabilized zirconia(NiO-YSZ) fuel electrode / YSZ electrolyte / lanthanum strontium manganite-YSZ(LSM-YSZ) air electrode due to similarity to Solid Oxide Fuel Cells(SOFCs). The Ni-YSZ most widely used fuel electrode shows several problems at SOEC mode such as degradation of the fuel electrode because of Ni particle's redox reaction and agglomeration. Therefore Ni-YSZ need to be replaced to an alternative fuel electrode material. In this study, We studied on the Double perovskite $PrBrMnO_{5+{\delta}}$(PBMO) due to its high electric conductivity, catalytic activity and electrochemical stability. PBMO was impregnated into the scaffold electrolyte $La_{0.8}Sr_{0.2}Ga_{0.85}Mg_{0.15}O_{3-{\delta}}$(LSGM) to be synthesized at low temperature for avoiding secondary phase generated when it exposed to high temperature. The Half cell test was conducted at SOECs and SOFCs modes.