• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
• /
• pp.831-832
• /
• 2006

Solid-state processing via the bulk mechanical alloying enables us to directly fabricate $Mg_2X$ semi-conductive material performs. Precise control of chemical composition leads to investigation on the dilution and enrichment of X in $Mg_2X$. Two types of solid-state reactivity are introduced: e.g. synthesis of $Mg_2Si$ from elemental mixture Mg-Si is nucleation-controlled process while synthesis of $Mg_2Sn$ from Mg-Sn, diffusion-controlled process. Thermoelectricity of these $Mg_2X$ is evaluated for discussion on the validity and effectiveness of this new PM route as a reliable tool for fabrication of thermoelectric compounds.

• 한국세라믹학회지
• /
• 제34권7호
• /
• pp.731-737
• /
• 1997

TixZr1-xC(0$0^{\circ}C$, 5.1 mm/sec respectively. The relative density, three point flexural strength, and the hardness of composites, which was sintered at 190$0^{\circ}C$ for 60 min by using hot-pressing under a pressure of 30 MPa, were 99%, 525 MPa and 24 GPa respectively.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2008년도 추계학술대회B
• /
• pp.2574-2577
• /
• 2008

The screw-feeders are used at gathering the minerals at the seafloor, transportation of the sewage, and at the beverage industry. This study was carried out to study solid-liquid mixture hydraulic transport of solid particles in a horizontal and inclined screw-feeders with rotating. This study is about the amount of the alteration amount of the material transportation for regular transportation. In this study a clear acrylic pipe was used in order to observe the movement of solid particles. Relates to the angle, rpm and ratio of pitch ; finding the optimum condition and knowing about designing the screw feeders shape. As a result, we found the suitable rpm and a suitable angle. According to the experiment, the best rpm and angle are 100-200rpm and $10^{\circ}$, respectively.

• 한국분말재료학회지
• /
• 제10권4호
• /
• pp.288-293
• /
• 2003

Mechanical alloying (MA) by high energy ball mill of Pure chromium Powders was carried out under the nitrogen gas atmosphere. Cr-N amorphous alloy powders have been produced through the solid-gas reaction subjected to MA. The atomic structure during amorphization process was observed by X-ray and neutron diffractions. An advantage of the neutron diffraction technique allows us to observe the local atomic structure surrounding a nitrogen atom. The coordination number of metal atoms around a N atom turns out to be 5.5 atoms. This implies that a nitrogen atom is located at both of centers of the tetrahedron and octahedron formed by metal atoms to stabilize an amorphous Cr-N structure. Also, we have revealed that a Cr-N amorphous alloy may produced from a mixture of pure Cr and Cr nitrides powders by solid-solid reaction during mechanical alloying.

• Korean Chemical Engineering Research
• /
• 제47권3호
• /
• pp.355-361
• /
• 2009

선택적 고체순환을 위한 2탑 유동층 공정에서 고체분리기에 의한 고체분리속도에 미치는 조업변수들의 영향을 측정 및 고찰하였다. 본 연구에서 개발한 고체분리기를 이용하여 굵은입자(212~300 또는 $425{\sim}600{\mu}m$)와 고운입자($63{\sim}106{\mu}m$)의 분리가 가능하였으며 고체분리속도는 66~987 g/min의 범위를 나타내었다. 고체분리속도는 고체분사노즐의 유속, 고체층 높이, 고체분사노즐의 직경, 고운입자와 굵은입자의 입자크기 차이, 고체분리기 금속망 간극크기 및 혼합입자 중 고운입자의 무게분율이 증가함에 따라 증가하였으며 유동화 속도의 영향은 크지 않았다.

• 한국정밀공학회지
• /
• 제13권7호
• /
• pp.100-114
• /
• 1996

In order to create a solid model more efficiently for a plastic or sheet metal product with a thin and constant thickness, various methods have been proposed up to now. One of the most typical approaches is to create a sheet model initially and then transform it into a solid model automatically for a given thickness. The sheet model as well as the transitive model in sheet modeling procedure is a non-manifold model. However, the previous methods adopted the boundary representations for a solid model as their topological framework. Thus, it is difficult to represent the exact adjacency relationship between topological entities and to implement the topological operations for sheet modeling and the transformation procedure of a sheet into a solid. In this paper, we proposed a sheet modeling system based on a non-manifold topological representation which can represent solids, sheets, wireframes, and their mixture. A set of generalized Euler operators for non-manifold topology as well as the sheet modeling capabilities including adding, bending, and punching functions are provided for easy modeling of sheet objects, and they are perfomed interactively with a two dimensional curve editor. Once a sheet model is completed, it can be transformed into a solid automatically. The transformation procedure is composed of the offset functions and the Boolean operations of sheet models, and it is even more comprehensive and easier to be implemented than the precious methods.

• 보존과학회지
• /
• 제35권4호
• /
• pp.269-277
• /
• 2019

Seaweed extracts, namely carrageenan obtained from Grateloupia elliptica and algin obtained from Laminaria, were employed as adhesive agents to synthesize solid adhesives for paper. Carrageenan from Grateloupia elliptica with the highest adhesive strength and lgin from Laminaria with the highest compressive strength was selected. The selected carrageenan and algin were mixed in a ratio of 7:3, and the mixture was employed as an adhesive agent. At a high temperature, sodium stearate(used as a solidifying material) oxidized the seaweed extracts. Consequently, carrageenan and algin were added to the final manufacturing process. The adhesive strength of the final synthesized solid adhesive is found to be 3.02 MPa and the compressive strength is found to be 30.5 N. Compared to the adhesive strength (2.95 MPa) and compressive strength (30.11 N) of commercial solid adhesives, the obtained results indicate superior adhesion characteristics. Furthermore, the proposed adhesive is environment-friendly because the presence of volatile organic compounds, formaldehyde, and heavy metals(such as chromium, lead, and cadmium) were not detected. Moreover, when used, the flatness of paper was twice that of commercial solid paper adhesives. Hence, the proposed adhesive can provide excellent adhesion, stability, and usability.

• 한국CDE학회논문집
• /
• 제5권3호
• /
• pp.242-254
• /
• 2000

This paper describes an efficient solid modeling method for thin-walled plastic or sheet metal parts, based on the non-manifold offsetting operations. Since the previous methods for modeling and converting a sheet into a solid have adopted the boundary representations for solid object as their topological framework, it is difficult to represent the exact adjacency relationship between topological entities of a sheet model and a mixture of wireframe and sheet models that can appear in the meantime of modeling procedure, and it is hard to implement topological operations for sheet modeling and transformation of a sheet into a solid. To solve these problems, we introduce a non-manifold B-rep and propose a sheet conversion method based on a non-manifold offset algorithm. Because the non-manifold offset aigorithm based on mathematical definitions results in an offset solid with tubular and spherical thickness-faces we modify it to generate the ruled or planar thickness-faces that are mostly shown in actual plastic or sheet metal parts. In addition, in order to accelerate the Boolean operations used the offset algorithm, we also develope an efficient face-face intersection algorithm using topological adjacency information.

• 대한화학회지
• /
• 제68권2호
• /
• pp.82-86
• /
• 2024

This paper presents the solid-state synthesis of insoluble Prussian blue (Fe₄[Fe(CN)₆]₃·xH₂O, PB) in a ball mill, utilizing the fundamental components of PB. Solid-state synthesis offers several advantages, such as being solvent-free, quantitative, and easily scalable for industrial production. Traditionally, the solid-state synthesis of PB has been limited to the reaction between iron(II/III) ions and hexacyanoferrate(II/III) complex ions, essentially an extension of the solution-based coprecipitation method to solid-state reaction. Taking a bottom-up approach, a reaction is designed where the reactants consist of the basic building blocks of PB: Fe²⁺ ions and CN^- ions. The reaction, with a molar ratio of Fe²⁺ and CN^- corresponding to 1:2.8, yields PB, while a ratio of 1:6.6 results in a mixture of potassium hexacyanoferrate(II) (K₄Fe(CN)₆), potassium chloride (KCl), and potassium cyanide (KCN). This synthetic approach holds promise for environmentally friendly methods to synthesize multimetallic PB with maximum entropy in nearly quantitative yield.

• 한국결정성장학회지
• /
• 제16권5호
• /
• pp.210-215
• /
• 2006

본 연구에서는 순 Cu 및 Nb 혼합분말에 대하여 Ar 분위기 중 고에너지 볼밀처리를 실시하여 기계적 합금화(MA) 효과를 조사하였다. $Cu_xNb_{100-x}$(x=5-50) 조성의 혼합분말을 각각 120시간까지 MA 처리 한 결과, Cu의 bcc-Nb 과포화 고용체가 30 at% Cu까지 넓어짐을 X선 회절분석, DSC 열분석 및 저온비열 측정을 통한 초전도 천이온도 변화로부터 알수 있었다. 120시간 MA 처리한 $Cu_{30}Nb_{70}$ 조성합금의 열분석 결과 broad한 발열반응만이 관찰되었으며, 볼밀처리에 의하여 계에 축적되는 에너지는 볼밀시간에 따라 증가하여 7.5kJ/mol 에 포화됨을 알 수 있었다. Miedema et al.의 계산에 의하면 $Cu_{30}Nb_{70}$ 혼합분말과 과포화 고용체의 자유에너지 차가 7kJ/mol이며, 본 연구에서 MA에 의하여 계에 축적된 에너지 값과 거의 같은 사실로부터 이 계에서 열역학적으로 과포화 고용체가 충분히 얻어질 수 있음을 나타내는 것으로 판단된다.