• Title/Summary/Keyword: Solar light

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Degradation of Humic Acid Using N-Doped TiO2 (질소를 도핑한 TiO2를 이용한 부식산 분해)

  • So, Ji-Yang;Rhee, Dong-Seock
    • Journal of Industrial Technology
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    • v.31 no.B
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    • pp.119-125
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    • 2011
  • N-doped Titanium oxides were prepared by using urea as a source of nitrogen. The photoactivities of the doped $TiO_2$ were evaluated on the basis of degradation of humic acid in aqueous solutions with different light sources, ultraviolet lamp, fluorescent lamp and solar light. XRD analysis was conducted to identify the crystal structure of the synthesized photocatalysts. N-doped $TiO_2$ and $pure-TiO_2$ was anatase type. SEM results showed that spherical particles were formed, which are the characteristics of the anatase form. N doped $TiO_2$ showed higher $UV_{254}$ decrease ratio and DOC removal ratio compared to $pure-TiO_2$. The humic acid degradation reaction using the UV-A lamp and UV-C lamp was assigned to pseudo-first order reaction. For solar light, only $pure-TiO_2$ and $N-TiO_2$ exhibited the pseudo-first order reaction.

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Light Scattering Effect Based Silica in Dye-sensitized $TiO_2$ Photovoltaic Cells ($TiO_2$ 광전극의 광산란 특성을 이용한 염료감응형 태양전지)

  • Wang, Jiao;Jin, En Mei;Zhao, Xingguan;Park, Kyung-Hee;Gu, Hal-Bon;Park, Bok-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.213-213
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    • 2010
  • In this thesis, we studied to increased to solar conversion efficiency of DSSC (dye-sensitized solar cell) using nanocrystalline $TiO_2$ semiconductor. We are preparation of $TiO_2$ photoelectrode, assembly the DSSC and put a focus in analyses electrochemical properties of DSSC and using Silica powder in $TiO_2$ photoelectrode for increase light scattering effect and improved conversion efficiency. It attempt to investigate the morphology of the photoelectrode and photovoltaic effects using field emission scanning electron microscopy (FE-SEM) and photovoltaic properties under illumination with AM 1.5 simulated sunlight. We got 146 % enhanced power conversion efficiency when the optimal content of quartz glass powder was 5 wt.% than that another content.

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Photovoltaic Properties of Organic Photovoltaic cell (유기물을 이용한 Photovoltaic cell의 광기전력 특성)

  • Kim, S.K.;Lee, H.D.;Chung, D.H.;Oh, H.S.;Hong, J.I.;Park, J.W.;Kim, T.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.123-126
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    • 2003
  • Recently, there is a growing concern on the photovoltaic effects using organic materials. This is a phenomena which converts the solar energy into the electrical one. We have fabricated a device structure of $ITO/PEDOT:PSS/CuPc/C_{60}/BCP/AI$. The PEDOT:PSS layer is made by spin coating, and the other organic layers are made by thermal vapor deposition. By measuring the current-voltage characteristics with an illumination of light, we have obtained value of Voc=0.38V, Jsc=$0.5mA/cm^{2}$. And a fill factor and efficiency are about 0.314 and 0.083%, respectively. A 500W xenon lamp(ORIEL) is used for a light source, and the light intensity illuminated into the device was about 10mW.

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The photocatalytic water splitting into $H_2$ and $O_2$ mimicking a Z-scheme mechanism (광합성을 모사한 광촉매 물분해 수소 제조)

  • Jeon, Myung-Seok;Hong, Joon-Gi;Chun, Young-Gab;Choi, Ho-Suk
    • Journal of the Korean Solar Energy Society
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    • v.23 no.4
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    • pp.29-35
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    • 2003
  • We studied the water splitting into $H_2$ and $O_2$ using two different semiconductor photo catalysts and redox mediator, mimicking the Z-scheme mechanism of the photosynthesis, $H_2$ evolution took place on a Pt-$SrTiO_2$ (Cr-Ta doped) photocatalyst using $I^-$ electron donor under the visible light irradiation. The Pt-$WO_3$ photocatalyst showed an excellent activity of the $O_2$ evolution using $IO_3^-$ electron acceptor under visible light. $H_2$ and $O_2$ gases evolved in the stoichiometric ratio($H_2/O_2$=2) under visible light using a mixture of the Pt-$WO_3$ and Pt-$SrTiO_3$ (Cr-Ta doped) suspended in NaI aqueous solution. We proposed a two-step photo-excitation mechanism using redox mediator under the visible irradiation.

Application of Sun Control Devices and Energy Conservation (Theory and Practice) (주광제어 장치를 이용한 건물의 에너지 절약(이론 및 실제))

  • Han, Hyun-Joo;Cho, Yil-Sik;Song, In-Choon
    • Solar Energy
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    • v.10 no.2
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    • pp.77-85
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    • 1990
  • In the present analysis, a number of sun control devices are examined for their performance in promoting the interior visual environment. Two exemplary cases are introduced for their excellence in harnessing the concept of daylighting and passive concepts. Of these, the Johnson Controls branch office building in Salt Lake City manifests the effectiveness of light shelves and clerestory windows in implementing these concepts. Distinct optical characteristics are found for overhangs, light shelves, louvers, and blinds as they interfere with the path of sunlight. Substantial amount of energy could be saved if the fundamentals of these devices are truly understood in their application to residential and commercial buildings. Sustained efforts should be made in this regard by the builders, architects, energy consultants, and educators who make contributions in energy management.

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Single Shot White Light Interference Microscopy for 3D Surface Profilometry Using Single Chip Color Camera

  • Srivastava, Vishal;Inam, Mohammad;Kumar, Ranjeet;Mehta, Dalip Singh
    • Journal of the Optical Society of Korea
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    • v.20 no.6
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    • pp.784-793
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    • 2016
  • We present a single shot low coherence white light Hilbert phase microscopy (WL-HPM) for quantitative phase imaging of Si optoelectronic devices, i.e., Si integrated circuits (Si-ICs) and Si solar cells. White light interferograms were recorded by a color CCD camera and the interferogram is decomposed into the three colors red, green and blue. Spatial carrier frequency of the WL interferogram was increased sufficiently by means of introducing a tilt in the interferometer. Hilbert transform fringe analysis was used to reconstruct the phase map for red, green and blue colors from the single interferogram. 3D step height map of Si-ICs and Si solar cells was reconstructed at multiple wavelengths from a single interferogram. Experimental results were compared with Atomic Force Microscopy and they were found to be close to each other. The present technique is non-contact, full-field and fast for the determination of surface roughness variation and morphological features of the objects at multiple wavelengths.

Daylighting Performance of Topside Lighting Systems for Different Orientations (방위에 따른 정측창 시스템의 채광성능 평가)

  • Kong, Hyo-Joo;Lee, Jin-Seoung;Ahn, Hyun-Tae;Kim, Jeong-Tai
    • Journal of the Korean Solar Energy Society
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    • v.29 no.1
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    • pp.11-17
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    • 2009
  • Daylighting is core of sustainable design in most buildings. Well-designed daylighting systems can significantly reduce or even eliminate the electric lighting loads during the day time, including air conditioning energy loads. Among window systems. the topside lights systems including monitor lighting, sawtooth lighting, sunscoop and, lightscoop is one of the most popular apparatus to improve the lighting quantity. Also they are important both in terms of energy savings and visual quality. The objective of this study is to analyse daylighting performance of topside lighting system for different orientations. Four types of topside lighting system were tested and comparpd: monitor lighting, sawtooth lighting, lightscoop and sunscoop. Totally 25 measuring points of illuminance on the horizontal plane were monitored from 09:00 to 17:00 on October 6, 2008. Agilent data logger and photometric sensors Li-cor were used. Comparisons with a light factor is discussed. The results found in this study would mean that there were no significant differences in light factor between three cases.

Effect of Transparency of CNT counter electrodes on the Efficiency of DSSCs

  • Lee, Won-Jae;Ramasamy, Easwaramoorthi;Lee, Dong-Yun;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.615-616
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    • 2005
  • Carbon Nanotubes (CNT) on flexible indium tin oxide (ITO) PET films were prepared for dye-sensitized solar cell (DSSC). These CNTs were prepared by spray coating method for various amount of light transparency. Also, Pt counter electrode was prepared by electro deposition method. All $TiO_2$ electrodes were deposited on ITO-PET films by spray coating method. Micro structural images show that CNT counter electrodes prepared by spray-coating have more dense structure with increasing spraying time (0 to 60 seconds). DSSC consisting of $TiO_2$ electrode and CNT counter electrode was fabricated with various amount of light absorption. DSSC have higher light energy conversion efficiency with increasing the thickness of CNT counter electrode. CNT counter electrode is at least compatible to that of CNT counter electrode.

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Hybrid between Inorganic Material and Biological Photosystem1 for Light Energy Application

  • Kim, Yeong-Hye;Nam, Gi-Tae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.272-272
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    • 2013
  • The attractive features of photosynthetic reaction center proteins for energy application make them useful in solar energy conversion to hydrogen fuel or electrical energy. Almost unity charge separation quantum yield and its rapid speed of ~1ns, absorbance region in visible light (480~740 nm) and high proportion of photosynthetically active solar energy of 48.5% allowed photosystem1 to exploited as a bio-material for photo-energy devices. Directionality of photosystem1 in electron transfer can solve main problem in two-step water splitting process where back reaction deteriorates the overall efficiency. In the study, photosystem1 was extracted from spinach and the photo-induced excited electron in the reaction center was utilized in various field of light energy application. First, hydrogen evolving system realized by photodeposition of platinum at the end of the electron transfer chain, with combining specific semiconductor to oxidize water in the first step of Z-scheme. The evaluation by gas-chromatography demonstrated hydrogen evolution through the system. For the further application of photoelectrical material on electrode, photosystem1 have been controlled by copper ion, which is expected to assemble photosystem in specific orientation followed by maximized photoelectrical ability of film. The research proposed concrete methods for combining natural protein and artificial materials in one system and suggested possibility of designing interface between biological and inorganic materials.

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Preparation and characterization of TiO2 anti-reflective layer for textured Si (100)

  • Choe, Jin-U;Nam, Sang-Hun;Jo, Sang-Jin;Bu, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.322-322
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    • 2010
  • Recently, anti-reflective films (AR) are one of the most studied parts of a solar cell since these films improve the efficiency of photovoltaic devices. Also, anti-reflection films on the textured silicon solar cells reduce the amount of reflection of the incident light, which improves the device performance due to light trapping of incident light into the cell. Therefore, we preformed two step processes to get textured Si (100) substrate in this experiment. Pyramid size of textured silicon had approximately $2{\sim}9\;{\mu}m$. A well-textured silicon surface can lower the reflectance to 10%. For more reduced reflection, TiO2 anti-reflection films on the textured silicon were deposited at $600^{\circ}C$ using titanium tetra-isopropoxide (TTIP) as a precursor by metal-organic chemical vapor deposition (MOCVD), and the deposited TiO2 layers were then treated by annealing for 2 h in air at 600 and $1000^{\circ}C$, respectively. In this process, the treated samples by annealing showed anatase and rutile phases, respectively. The thickness of TiO2 films was about $75{\pm}5\;nm$. The reflectance at specific wavelength can be reduced to 3% in optimum layer.

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