• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.461-466
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• 2011

In this study, the fluorine doped $TiO_2$ was prepared as a photoelectrode in order to improve the efficiency of dye-sensitized solar cells and estimated the electrochemical characterizations. The energy conversion efficiency of the prepared dye-sensitized solar cells using fluorine doped $TiO_2$ was calculated from a current-voltage curve. The efficiency of prepared dye-sensitized solar cells was improved by about maximum three times by F-doping on $TiO_2$. It was suggested that the efficiency of dye-sensitized solar cells was improved by hybrid semiconductors of $TiO_2/TiOF_2$ in photoelectrode based on reduced $TiOF_2$ energy level via fluorine doping. It can be confirmed that the electron transport was faster but the electron recombination was slower by doping fluorine on $TiO_2$ in photoelectrode through intensity-modulated photocurrent spectroscopy and intensity-modulated photovoltage spectroscopy analysis.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.432.1-432.1
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• 2016

We demonstrated that the power conversion efficiency (PCE) of bilayer solar cell was significantly enhanced by inserting interfacial layer between the organic bilayer film and the Al electrode. Moreover, the water contact angle shows that the bilayer solar cells suffer from the undesirable surface component which limits the charge transport to the Al electrode. The AFM measurement has revealed that the pre- and post-thermal annealing treatments results in different morphologies of the interfacial layer which is critical for the higher PCE of the bilayer solar cells. Furthermore we have investigated the electrical properties of the bilayer solar cells and obtained insights into the detailed device mechanisms. The transient photovoltage measurements suggests that the significantly enhanced Voc is caused by reducing the recombination at the interface between the organic films and the Al electrode. By inserting the TiO2 layer between the bilayer film and Al electrode, the open circuit voltage (Voc) was increased from 0.37 to 0.66V. Consequently, the power conversion efficiency (PCE) of bilayer solar cells was significantly enhanced from 1.23% to 3.71%. As the results, the TiO2 interfacial layer can be used to form an ohmic contact layer, serveing as a blocking layer to prevent the penetration of the Al, and to reduce the recombination at the interface.

• Bulletin of the Korean Chemical Society
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• v.24 no.10
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• pp.1501-1504
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• 2003

Single-wall carbon nanotubes (SWCN) were integrated in $TiO_2$ film and the beneficial influence on the dyesensitized solar cells in terms of improved photocurrent was studied in the light of static J-V characteristics obtained both under illumination and in the dark, photocurrent transients, IPCE spectra and impedance spectra. Compared with a solar cell without SWCN, it is established that the photocurrent density of the modified cell increases at all applied potentials. The enhanced photocurrent density is correlated with the augmented concentration of electrons in the conduction band of $TiO_2$ and with increased electrical conductivity. Explanations are additionally corroborated with the help of SEM, Raman spectra and dye-desorption measurements.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.408.2-409
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• 2016

Theoretically, the dye-sensitized solar cells (DSSCs) are high efficiency solar cells. However DSSCs have low power conversion efficiency (PCE) than silicon based solar cells. In this study, we use the phosphor materials, such as $Y_2O_3:Eu$ (Red), $Zn_2SiO_4:Mn$ (Green), $BaMgAl_{14}O_{23}:Eu$ (Blue), to enhance the PCE of DSSCs. Three phosphors were prepared and used as an effective scattering layer on the transparent $TiO_2$ with doctor blade method. We confirmed that the three scattering layers improve the PCE and Jsc due to the light harvesting enhancement via increased the scattering and absorbance in visible range. Under the sun illumination AM 1.5 conditions, the PCE of the mesoporous $TiO_2$ based DSSCs is 5.18 %. The PCE of the DSSCs with Y2O3:Eu, $Zn_2SiO_4:Mn$ and $BaMgAl_{14}O_{23}:Eu$ as scattering layer were enhanced to 5.66 %, 5.72% and 5.82%, respectably. In order to compare the optical properties change, DSSCs were measured by EQE, reflectance and PCE. At the same time, FE-SEM and XRD were used to confirm the structural changes of each layer.

• 한국태양에너지학회:학술대회논문집
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• 2011.04a
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• pp.246-249
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• 2011

SolarPACES is an international cooperative network bringing together teams of national exports from around the world to focus on the development and marketing of concentrating solar power systems (also known as solar thermal power systems). It is one of a number of collaborative programs, called Implementing Agreements, managed under the umbrella of the International Energy Agency to help find solutions to worldwide energy problems. Technology development is at the core of the work of SolarPACES. Member countries work together on activities aimed at solving the wide range of technical problems associated with commercialization of concentrating solar technology, including large-scale system tests and the development of advanced technologies, components, instrumentation, and systems analysis techniques. In addition to technology development, market development and building of awareness of the potential of concentrating solar technologies are key elements of the SolarPACES program The Implementing Agreement specifies broad "Tasks," or thematic areas of work SolarPACES currently has three ongoing tasks, focusing on concentrating solar electric power systems (Task I), solar chemistry research (Task II), and solar technology and applications (Task III). An Operating Agent, nominated by the ExCo, is responsible for overseeing the work of each task Each task maintains a detailed program of work that defines all task activities, including their objectives, participants, plans, and budgets. In addition to technical reports of the activities and their participants, accomplishments and progress are summarized in the SolarPACES annual report. Many SolarPACES activities involve close cooperation among member countries (either through sharing of task activities or, occasionally, cost-sharing), although some cooperation is limited to sharing of information and results with other participants. In this paper, structure, works, and members of SolarPACES and Korean activies in the SolarPACES are introduced.

• 한국태양에너지학회:학술대회논문집
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• 2011.11a
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• pp.320-323
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• 2011

SolarPACES is an international cooperative network bringing together teams of national experts from around the world to focus on the development and marketing of concentrating solar power systems (also known as solar thermal power systems). It is one of a number of collaborative programs, called Implementing Agreements, managed under the umbrella of the International Energy Agency to help find solutions to worldwide energy problems. Technology development is at the core of the work of Solar PACES. Member countries work together on activities aimed at solving the wide range of technical problems associated with commercialization of concentrating solar technology, including large-scale system tests and the development of advanced technologies, components, instrumentation, and systems analysis techniques. In addition to technology development, market development and building of awareness of the potential of concentrating solar technologies are key elements of the Solar PACES program. The Implementing Agreement specifies broad "Tasks," or thematic areas of work. SolarPACES currently has three ongoing tasks, focusing on concentrating solar electric power systems (Task I), solar chemistry research (Task II), and solar technology and applications (Task III). An Operating Agent, nominated by the ExCo, is responsible for overseeing the work of each task. Each task maintains a detailed program of work that defines all task activities, including their objectives, participants, plans, and budgets. In addition to technical reports of the activities and their participants, accomplishments and progress are summarized in the SolarPACES annual report. Many SolarPACES activities involve close cooperation among member countries (either through sharing of task activities or, occasionally, cost-sharing), although some cooperation is limited to sharing of information and results with other participants. In this paper, structure, works, and members of SolarPACES and Korean activies in the SolarPACES are introduced.

• Bulletin of the Korean Chemical Society
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• v.35 no.4
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• pp.1050-1056
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• 2014

Dye sensitized solar cells were fabricated using natural dyes extracted from beetroot, rose and strawberry. The ZnO nanorod working electrode has been prepared by simple hydrothermal method. The crystallinity and morphology of the prepared electrode has been studied using X-ray diffraction and scanning electron microscopy techniques. The effect of natural dye extract temperature, pH of the dye and the solvent used for dye preparation on the solar cell characteristics have been studied. The efficiency of strawberry extract sensitized ZnO nanorod solar cells are found to be better than the other solar cells sensitized using beetroot and rose extracts.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.274-274
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• 2006

Recently, conjugated polymer solar cells have attracted a great deal of attention. In this work, we applied the various scanning probe techniques to characterize composite materials typically used to fabricate polymer solar cells: poly-3(hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and P3HT/PCBM/Au nanoparticle (NP) samples. The latter is studied due to the idea of using the gold NP surface plasmon to enhance the optical absorption of the composite films. AFM is used to characterize the film morphology whereas conducting AFM is used to study the charge transport properties at the nanoscale. We found that there is a direct correlation between the nanoscale charge transport measurements and the device efficiencies.

• Prospectives of Industrial Chemistry
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• v.20 no.2
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• pp.13-24
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• 2017

태양전지는 온실 가스 감축에 효과가 큰 기후 변화 대응 기술이다. 현재 상업화에 성공한 실리콘 태양전지의 뒤를 이어 박막 태양전지, 페로브스카이트 태양전지 등 차세대 태양전지가 가격과 효율 등을 극복하기 위하여 매우 많이 연구되고 있다. CZT(S,Se) 박막 태양전지는 차세대 태양전지의 유력 후보군인 CIGS, CdTe, 페로브스카이트 태양전지 등에 비해 범용 무독성 원소를 광흡수층으로 사용한다는 장점을 가지고 있지만 아직까지는 이들보다 효율이 낮아 상용화하기에는 많은 문제를 가지고 있다. CZT(S,Se) 박막태양전지의 기본적인 물성, 공정 등을 알아보고 고효율을 달성하는 방법에 대하여 알아보고자 한다.

• Journal of the Korean Solar Energy Society
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• v.23 no.2
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• pp.71-79
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• 2003

The goal of this paper is to measure and compare the performance of solar heat pump for refrigerants. To accomplish the goal, solar heat pump with aluminum roll bond type evaporator and indoor heat exchanged(condenser) was built. The test results showed that the COP and heating capacity of HFC-32/125/134a(23/25/52 wt%, $CH_2F_2/CF_3CHF_2/CF_3CH_2F$) were higher than those of HCFC-22$(CHClF_2)$. A study proved that best conditions to use heating system that is about $40m^2$ and $80m^2$. The COP range of the whole system was from 4 to 6 according to the solar collector's area variation. Hydrochlo-rofluorocarbon HCFC-22$(CHClF_2)$ is included in the compound to be controlled. HFC-32/125/134a(23/25/52 wt%, $CH_2F_2/CF_3CHF_2/CF_3CH_2F$) is the most suitable replacement HCFC-22$(CHClF_2)$ in solar heat pump application. The solar heat pump system was designed to show the best efficiency that the room temperature make $18\sim20^{\circ}C$ and $23\sim25^{\circ}C$ in Seoul during the fall season.