• Applied Chemistry for Engineering
• /
• v.29 no.2
• /
• pp.196-200
• /
• 2018

In this study, the intermediate layer in Pd-based hydrogen separation membrane was synthesized to minimize the surface roughness and defects using powder-type and sol-type metal oxides. The surface properties and gas permeation characteristics were analysed by SEM and $N_2$ gas permeation test. The coating layer composed of sol type metal oxides has smooth surface, especially the layer coated by $TiO_2$ sol has little pin holes, cracks and defects. The binary layer composed of powder type and sol type metal oxides has similar flux characteristics to a single sol type layer. The Pd-based composite membrane improved by the binary intermediate layer exhibited $0.32mol/m^2s$ of the hydrogen permeation flux with a selectivity ($H_2/N_2$) of ~10,890 at 672 K and a pressure difference of 1 bar.

• Journal of the Korean Mathematical Society
• /
• v.44 no.5
• /
• pp.1121-1137
• /
• 2007

There are 7 types of 4-dimensional solvable Lie groups of the form ${\mathbb{R}^3}\;{\times}_{\varphi}\;{\mathbb{R}}$ which are unimodular and of type (R). They will have left. invariant Riemannian metrics with maximal symmetries. Among them, three nilpotent groups $({\mathbb{R}^4},\;Nil^3\;{\times}\;{\mathbb{R}\;and\;Nil^4)$ are well known to have lattices. All the compact forms modeled on the remaining four solvable groups $Sol^3\;{\times}\;{\mathbb{R}},\;Sol_0^4,\;Sol_0^'4\;and\;Sol_{\lambda}^4$ are characterized: (1) $Sol^3\;{\times}\;{\mathbb{R}}$ has lattices. For each lattice, there are infra-solvmanifolds with holonomy groups 1, ${\mathbb{Z}}_2\;or\;{\mathbb{Z}}_4$. (2) Only some of $Sol_{\lambda}^4$, called $Sol_{m,n}^4$, have lattices with no non-trivial infra-solvmanifolds. (3) $Sol_0^{'4}$ does not have a lattice nor a compact form. (4) $Sol_0^4$ does not have a lattice, but has infinitely many compact forms. Thus the first Bieberbach theorem fails on $Sol_0^4$. This is the lowest dimensional such example. None of these compact forms has non-trivial infra-solvmanifolds.

• Proceedings of the KSME Conference
• /
• 2001.06b
• /
• pp.676-681
• /
• 2001

ABS is a safety device, which adds hydraulic system to the existing brake system to prevent wheel from locking, so we can obtain maximum braking force on driving. The hydraulic system to control braking pressure consists of sol-flow type using solenoid valve, flow control valve or consists of sol-sol type using two solenoid valve. In this paper, the hydraulic system in ABS is composed of sol type using a 3port-2position solenoid valve, and vehicle system is composed of 1/4 vehicle model. And slip ratio is controlled using PWM (Pulse-Width-Modulation) control algorithm. Braking friction coefficient and tracking friction coefficient which are described by slip ratio's function have maximum value when slip ratio has its value from 0.1 to 0.3. And slip ratio is controlled constantly in this boundary value even in the variation of road's condition in some boundary.

• Journal of Technologic Dentistry
• /
• v.29 no.1
• /
• pp.121-131
• /
• 2007

A preparation process's conditions of aqueous sol which contains anatase-type nano titania particles with photocatalyic properties was established by using Yoldas process, so called, DCS(Destabilization of Colloidal Solution) process in this study. And crystal size change and phase transformation of titania particles in aqueous titania sol depending on reaction conditions was investigated by a light scattering method and XRD analysis of frozen dried powders, respectively. This sol with photo catalytic nano titania particles was used to the following hydrophilic hybrid coating film's fabrication and its properties was evaluated. Subsequently, for coating film using the above mentioned aqueous titania sol, non-aqueous titania sol was prepared without any chemical additives and its time stability according to aging time was investigate. By using the above mentioned aqueous titania sol and non-aqueous sol, a complex oxide coating sol for metal and ceramic substrate and a organic-inorganic hybrid coating sol for polymer substrate was prepared and it's hydrophilicity depending on UV irradiation conditions was evaluated. As a conclusions, the following results were obtained. (1)Aqueous titania sol The average particle size of titania in formed aqueous titania sol was distributed between 20$\sim$90nm range depending on reaction conditions. And the crystal phase of titania powders obtained by frozen drying method was changed from amorphous state to anatase and subsequently transformed to rutile crystal phase and it is attributed to concentration gradient in aqueous sol. (2)Non-aqueous titania sol Non-aqueous titania sol was prepared using methanol as a solvent and a little distilled water for hydrolysis and nitric acid as a catalyst were used. The obtained non-aqueous titania sol was stable at room temperature for 20 days. Additionally, non-aqueous titania sol with addition of chealating reagent such as acethylaceton and ethylene glycol prolonged the stability of sol by six months. (3)Complex sol and hybrid sol with super hydrophilicity The above mentioned aqueous titania sol as a main photocataylic component and non-aqueous titania sol as a binder for coating process was used to prepare a complex sol used for metal, ceramic and wood material substrate and also to prepare the organic-inorganic hybrid sol for polymer substrate such as polycarbonate and polyethylene, in which process APMS(3-Aminopropyltrimethoxysilane), GPTS(3-Glycidoxypropyl-trimethoxysilane) as a hydrophilic silane compound and HEMA(2-Hydroxyethyl methacrylate) as a forming network in hybrid coating film were used. The hybrid coating film such as prepared through this process showed a superhydrophilicity below 1$10^{\circ}$ depending on processing conditions and a pencil's hardness over 6 H.

• Proceedings of the Korean Ceranic Society Conference
• /
• 2003.10a
• /
• pp.206.2-206
• /
• 2003

• Journal of Sensor Science and Technology
• /
• v.29 no.6
• /
• pp.420-426
• /
• 2020

A metal oxide semiconductor gas sensor is operated by measuring the changes in resistance that occur on the surface of nanostructures for gas detection. ZnO, which is an n-type metal oxide semiconductor, is widely used as a gas sensor material owing to its high sensitivity. Various ZnO nanostructures in gas sensors have been studied with the aim of improving surface reactions. In the present study, the sol-gel and vapor phase growth techniques were used to fabricate nanostructures to improve the sensitivity, response, and recovery rate for gas sensing. The sol-gel method was used to synthesize SnO₂ nanoparticles, which were used as the seed layer. The nanoparticles size was controlled by regulating the process parameters of the solution, such as the pH of the solution, the type and amount of solvent. As a result, the SnO₂ seed layer suppressed the aggregation of the nanostructures, thereby interrupting gas diffusion. The ZnO nanostructures with a sol-gel processed SnO₂ seed layer had larger specific surface area and high sensitivity. The gas response and recovery rate were 1-7 min faster than the gas sensor without the sol-gel process. The gas response increased 4-24 times compared to that of the gas sensor without the sol-gel method.

• Journal of Korean Society for Atmospheric Environment
• /
• v.19 no.1
• /
• pp.57-66
• /
• 2003

TiO$_2$ sol was prepared by sol-gel method, and this sol was coated in ceramic and glass bead by dip-coating method. The coated catalyst was applied to degrade benzene in the gas phase by exposing to UV -lamp (365 nm) in a batch reactor. The removal efficiency of the benzene was compared by changing various conditions such as the kind of chemical additives, the coating beads (ceramic and glass), solution pH, the initial concentration of TiO$_2$ sol, UV intensity, and benzene concentration. The physical structure of TiO$_2$ sol used in this study was found to be pu-rely anatase type from XRD analysis. The results showed that ceramic bead was effective as the coating agent rath-er than glass bead. The significant change in the benzene removal efficiency of benzene did not occur with chang-ing coating frequency and the initial concentration of TiO$_2$ sol. The removal efficiency of benzene increased with increasing UV intensity, and with acidic treatment of TiO$_2$-coated ceramic bead.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.02a
• /
• pp.350-350
• /
• 2013

Sol-gel법을 이용하여 p-Si 기판위에 yttrium이 도핑된 ZnO (YZO)를 성장하였다. ZnO의 precursor로는 zinc acetate dihydrate를, yttrium의 source로는 yttrium acetate hydrate를 사용하였으며, 용매와 안정제로는 각각 2-methoxy ethanol과 monoethanolamine (MEA)를 사용하였다. yttrium의 doping 농도에 따른 영향을 알아보기 위하여 1~4 at.%로 제작된 YZO sol을 각각 p-type Si 기판에 성장하였으며, 이 후 furnace를 이용하여 500oC에서 1시간 동안 열처리하였다. 성장된 YZO 박막의 표면과 두께를 SEM을 통하여 확인하였으며, XRD를 통한 구조적인 특성을 분석한 결과 모든 박막에서 뚜렷한 c-축 배양성을 갖는 ZnO (0002)피크를 확인하였다. Hall effect를 통하여 YZO는 모두 n-type 특성을 나타낸다는 것을 확인하였으며, 광학적인 특성은 PL을 통해서 분석하였다. n-YZO/p-Si 이종접합의 전류-전압 특성을 분석한 결과 뚜렷한 정류특성을 나타내었다.

• Korean Journal of Microbiology
• /
• v.32 no.3
• /
• pp.208-214
• /
• 1994

We screened many species from a wide variety of bacterial genera for a new type II restriction endonuclease. The purification and characterization of SolI from a soil isolate, Streptoverticillium olivoverticillatum are described here. The enzyme turned out to be an isoschizomer of BamHI. It recognized the hexanucleotide sequence of 5'-G$\downarrow$GATCC-3' and cleaved as in dicated by the arrow, generating a 4 base 5' extension. Unlike its isoschizomer, BamHI, the activity was sensitive to dam methylation within the recognition sequence. Following ammonium sulfate fractionation of the crude extract, heparin-agarose and Affi-gel Blue column chromatography were employed to purify the enzyme. SolI required at least 0.2 mM of $MgCl_2$ for the cleavage to occur. The enzyme exhibited its maximal activity in the absence of NaCl, but was inhibited completely in the presence of 120 mM NaCl. The pH and temperature optima for activity were pH 8.6 and $40^{\circ}C$, respectively. The molecular weight of SolI was estimated to be 43,000 Da by Superose-12 gel filtraion chromatography.

• KSTLE International Journal
• /
• v.10 no.1_2
• /
• pp.23-26
• /
• 2009

In this work the tribological characteristics were compared between ZnO coatings on glass substrate prepared by sputtering and sol-gel methods. In order to assess the effects of processing method on the tribological characteristics, the friction and wear properties of the coatings were measured by using a reciprocating type of micro-tribotester. The sputtered ZnO coatings were prepared on a glass substrate at room temperature, $150^{\circ}$, and $300^{\circ}$. The ZnO coatings prepared by sol-gel method were heat-treated in air atmosphere at $550^{\circ}$ for one hour. The crystal structure and surface morphology of the coatings were measured by X-ray diffraction (XRD) and Atomic Force Microscope (AFM), respectively. The experimental results showed that overall the sputtered coatings exhibited better friction and wear properties than coatings prepared by sol-gel method. The sputtered coating grown at room temperature had a relatively low friction coefficient of 0.14 and superior wear resistance compared with the other coatings. Nevertheless, sol-gel method of coating ZnO on glass is beneficial for economical coating of a large surface area.