• 한국세라믹학회지
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• 제33권7호
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• pp.755-760
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• 1996

Sol-gel processing was used to prepare PZT fibers. Titanium isopropoxide Zirconium n-butoxide and lead acetate trihydrate were used as starting materials and TEA(triethanolamine) was added to form stabilized Pb-Ti-Zr complex alkoxide, Effects of catalysts and various solvents on the state of precursor sol gelation reaction fiber spinnability pyrolysis and crystallization were also investiated.

• 한국세라믹학회지
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• 제32권1호
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• pp.17-24
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• 1995

The TEA complex polymeric sol was prepared by the alkoxide sol-gel method. The purpsoe of this experiment was to vefity the particle shape in the sol from the investigation of the rheological properties. TEA retarded hydrolysis rate by the reaction with alkoxide enough to make a stable transparent sol in the wide range of composition. From the results of the viscosity change with time, the optimum mole ratio for spinning was selected as 0.5 mole of TEA, 3 mole of H2O and the optimum viscosity was 104 cPs. The rheological behavior of the sol showed that the particle shape in the sol was linear, which was adequate for fiber drawing.

• 자원리싸이클링
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• 제18권6호
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• pp.30-37
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• 2009

소디움실리케이트 수용액으로부터 나트륨이온이 제거된 핵생성 산화실리케이트 수용액과 실리케이트 수용액을 pH 10~11로 조절하여 혼합한 다음, $20{\sim}80^{\circ}C$에서 솔-젤 반응하여 실리카 솔 입자를 제조하였다. 이 때 yellow silicomolybdate method를 이용하여 소디움실리케이트와 나트륨이온이 제거된 실리케이트 수용액의 특성과 이들 출발용액으로부터 솔-젤 반응에 의해 제조된 실리카 솔의 입자특성에 대하여 고찰하였다. $SiO_2$를 2 wt% 함유한 소디움실리케이트 수용액은 약 95% 이상의 반응성 실리케이트를 함유하며, 솔-젤 반응에 참여하는 반응성 실리케이트는 전체 실리카 기준 약 50% 정도이다. 반응온도가 증가함에 따라 silanol(Si-OH) 결합구조의 흡수피크 세기는 감소하고, siloxane(Si-O-Si) 결합구조의 흡수피크 세기가 증가하였다. 반응조건별로 제조된 실리카 솔 수용액의 zeta potential은 -40~-60 mV 범위로 분산성이 좋은 상태를 유지하였다. 실리카 솔 입자크기는 5~10 nm로 반응온도 증가에 따라 크기가 약간 감소하였다. 실리카 솔 제조 후, 2차 입자 성장을 위하여 실리케이트 수용액을 재 첨가하였을 경우에 실리카 솔입자 크기가 약 20 nm로 증가하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.9-16
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• 2000

A survey over the role of sol-gel processing and metal alkoxides in the thin film preparation is given. The basic chemistry of the sol-gel process is complex due to the different reactivities of the network forming and the wide variety of reaction parameters. Despite the important progress in the investigations of the mechanisms of thin film formation, a direct relation of reaction parameters to functional oxide properties is still very difficult.

• Bulletin of the Korean Chemical Society
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• 제19권9호
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• pp.927-933
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• 1998

Polycrystalline powder of vanadium-doped forsterite (Vδ $Mg_2SiO_4$) was synthesized by the $H_2O_2$-assisted sol-gel method. The vanadium dopant, which was added as VO$(OMe)_3$ in methanol, went through several redox reactions as the sol-gel reaction proceeded. Upon adding VO$(OMe)_3$ to a mixture of $Mg(OMe)_2$ and Si$(OEt)_4$ in methanol, V(V) reduced to V(IV). As hydrolysis reaction proceeded, the V(IV) oxidized all back to V(V). Apparently, some of the V(V) reduced to V(IV) during subsequent gelation by condensation reaction. The V(IV) remained even after heat treatment of the gel in highly oxidizing atmosphere. The crystallization of the xerogel around 880 ℃ readily produced single phase forsterite without any minor phase. Using the polycrystalline powder as feeding stock, single crystals of vanadium-doped forsterite were grown by the floating zone method in oxidizing or reducing atmosphere. The doping was limited in low level because of the high partitioning of the vanadium in liquid phase during melting. The greenish single crystal absorbed visible light of 700∼1100 nm. But, no emission was obtained in near infrared range.

• 한국결정성장학회지
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• 제5권2호
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• pp.142-151
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• 1995

금속 알콕사이드법에 의해 복합 알콕사이드를 합성하고, 이를 sol - gel법으로 가수분해 반응시켜 얻은 전구체를 소성하여 barium hexaaluminate를 제조하였다. 복합 알콕사이드 합성시 알코올의 종류 및 양, 반응시간을 변화시켜 barium hexaaluminate 전구체 물성에 미치는 영향을 관찰하였으며, 가수 분해시 물의 양 및 반응온도, 그리고 숙성시간에 따른 barium hexaaluminate의 비표면적과 입자크기에 미치는 영향을 알아보았다.

• 한국응용과학기술학회지
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• 제20권4호
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• pp.346-352
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• 2003

BaTiO$_3$, powders were prepared by sol-gel process from different aging time and reaction temperature. Particle shape, size and crystal structure of prepared $BaTiO_3$ powders were analyzed by SEM, XRD and FT-IR. Effect of aging time alternation didn't particularly show up. Spherical nano-sized $BaTiO_3$ powders were obtained from condition more than reaction temperature $55^{\circ}C$, and obtained sintered $BaTiO_3$ powders of tetragonal phase from heat-treatment at $1,100^{\circ}C$.

• 한국대기환경학회지
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• 제17권4호
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• pp.363-370
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• 2001

In this study, TiO$_2$, the popular photocatalyst, was used to decompose ethanol. TiO$_2$was prepared by the sol -gel method and coated on pyrex stick. A 15W, UV-A lamp was used as the UV light source and il gas chromatography (HP 5890) was used to confirm the concentrations of ethanol, $CO_2$and the intermediates. Variation of preparation parameters and calcination temperature for TiO$_2$photocatalysts in the sol -gel method caused changes of ethanol decomposition activity. The best ethanol photodecomposition activity was obtained on the sample when prepared with 0.14 mol of HCI, a mol of ethanol and 1.3 mol of TTIP ware mixed in sol-gel process and calcinated at 50$0^{\circ}C$ for 3 hours. Acetaldehyde was detected as an intermediate and decomposed to carbon dioxide and water at the end of the reaction.

• 한국결정성장학회지
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• 제5권4호
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• pp.332-342
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• 1995

실리콘 알콕사이드 용액의 졸-겔 전이에 있어서 반응조건에 중요한 영향을 미치는 인자에 대하여 Raman 분광분석을 기초로 해서 고찰해 보았다. 촉매의 종류, 용매, 건조제어용 화학첨가제 및 물의 양과 같은 여러 가지 인자가 졸-겔 과정에 있어 전이메카니즘에 영향을 주었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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• pp.401-402
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• 2005

The important parts of material science in the film preparation fields and sol-gel technology are presented. For the present work, a series of amorphous films was prepared in air by sol-gel method without using some alkoxide stabilizer, which reduces the reactivity of the metal alkoxides. The choice of precursors can affect the chemical-reaction kinetics, microstructures and properties of the product. In this report author compared the crystallization behavior of oxide functional films derived from the same precursors, stressing the influence of experiment conditions and where it was possible to obtain the uniform amorphous or crystalline dielectric films. A short analysis of sol-gel technology and thin film methods about development of dielectric materials has been given.