• 한국재료학회지
• /
• 제20권4호
• /
• pp.228-234
• /
• 2010

In this paper, Fe-$TiO_2$ and Fe-fullerene/$TiO_2$ composite photocatalysts were prepared with titanium (IV) n-butoxide (TNB) by a sol-gel method. $TiO_2$, Fe-$TiO_2$ and Fe-fullerene/$TiO_2$ were characterized by scanning electron microscopy (SEM), Transmission electron microscope (TEM), specific surface area (BET), X-ray diffraction analysis (XRD) and energy dispersive X-ray spectroscopy (EDX). The photocatalytic activities were evaluated by the photocatalytic oxidation of methylene blue (MB) solution. XRD patterns of the composites showed that the photocatalyst composite contained a typical single and clear anatase phase. The surface properties shown by SEM presented a characterization of the texture on Fe-fullerene/$TiO_2$ composites and showed a homogenous composition in the particles for the titanium sources used. The EDX spectra for the elemental identification showed the presence of O, C and Ti elements. Moreover, peaks of the Fe element were observed in the Fe-$TiO_2$ and Fe-fullerene/$TiO_2$ composites. The degradation of MB solution by UV-light irradiation in the presence of photocatalyst compounds was investigated in complete darkness. The degradation of MB concentration in aqueous solution occurred via three kinds of physical phenomena: quantum efficiency of the fullerene; organo-metallic reaction of the Fe compound; and decomposition of $TiO_2$. The degradation rate of the methylene blue solution increased when using Fe-fullerene/$TiO_2$ compounds.

• 폴리머
• /
• 제29권2호
• /
• pp.156-160
• /
• 2005

Octamethylcyclotetrasiloxane$(D_4)$과 1,3,5-trimethyl-1,3,5-triphenylcyclotrisiloxane$(D_3^{Me,Ph)$을 1,1,3,3-tetramethyl-1,3-divinyldisiloxane(MVS)과 평형중합시켜 실리콘의 Si원자에 dimethyl 및 methylphenyl기가 도입된 $\alpha,\omega-vinyl$ poly(dimethyl-methylphenyl) siloxane prepolymer(VPMPS)를 제조하였으며, 또한 $D_4$와 1,3,5-trimethylcyclotrisiloxane$(D_3^:Me,H})$을 1,1,3,3-tetramethyldisiloxane(MS)와 평형중합시켜 Si원자에 dimethyl 및 methylhydrogen기가 도입된 $\alpha,\omega-hydrogen$ poly (dimethyl-methyl) siloxane prepolymer(HPDMS)를 제조하였다. Poly(acrylic acid)(PAA)을 chelating agent로 하여 nickel(II) nitrate와 iron(III) nitrate를 솔-젤 방법으로 PAA 금속염을 제조하고 이틀을 소결시켜 nickel ferrite 나노 입자를 제조하였다. 제조한 nickel ferrite는 XRD 패턴으로 확인하고 입자의 크기를 TEM으로 측정하였다 1,3-Divinyltetramethyldisilazane(VMS)으로 표면처리한 나노 실리카, nickel ferrite, VPMPS, HPDMS 및 촉매를 고속 교반기에 가하고 $130^{\circ}C$에서 컴파운딩하여 poly(organosiloxane) rubber nanocomposites를 제조하였다. Nickel ferrite 함유한 nanocomposite, POX-30과 POX-50을 각각 제조하였으며 이들의 기계적 및 열전도 특성 그리고 체적 저항을 측정하였다.

• 한국안광학회지
• /
• 제3권1호
• /
• pp.217-222
• /
• 1998

$SiO_2-TiO_2-AgO$ 코팅박막을 졸-겔법으로 현미경용 슬라이드 유리판과 씰리콘 기판에 제조하였다. 이 박막의 열처리온도는 $500^{\circ}C$가 적절하였으며 5회 반복코팅한 박막의 두께는 310nm였다. AgO가 10mol% 첨가된 박막의 표면은 균일한 구조를 보였으나 첨가량이 많아질수록 박막의 표면에 pin hole과 AgO의 석출에 기인한 cluster를 보였다. 열처리온도의 증가에 따라 IR흡수의 정도가 점차 감소하였고, AgO 첨가량의 증가에 따라 반사율은 점차 감소하였으며 색상은 light yellow에서 무채색 쪽으로 점차 전이하였다.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
• /
• pp.288-288
• /
• 2013

We report the catalytic activity of Au/$TiO_2$ and Pt/$TiO_2$ nanocatalysts under CO oxidation fabricated by arc plasma deposition (APD), which is a facile dry process with no organic materials involved. Using APD, the catalyst nanoparticles were well dispersed on $TiO_2$ powder with an average particle size (2~4 nm) well below that of nanoparticles prepared by the sol-gel method (10 nm). We found that the average particle size of the dispersed gold nanoparticles can be controlled by changing the plasma discharge voltage of APD. Accordingly, the amount of loaded gold on the $TiO_2$ powder increased with increasing discharge voltage, but the specific surface area of the Au/$TiO_2$ samples decreased. As for catalytic reactivity, Au/$TiO_2$ showed a higher catalytic activity than Pt/$TiO_2$ in CO oxidation. The catalytic activity of the Au/$TiO_2$ samples showed size dependence where higher catalytic activity occurred on smaller gold nanoparticles. The study suggests that APD is a simple way to fabricate catalytically active nanocatalysts.

• 공업화학
• /
• 제16권1호
• /
• pp.107-111
• /
• 2005

$V_2O_5$ 분말을 과산화수소에 용해시켜 $V_2O_5$ 겔을 졸-겔법으로 합성한 후 물성과 전기화학적 특성을 NMR, 선형전압전류법 등을 이용하여 조사하였다. $V_2O_5$ xerogel에 삽입된 $Li^+$ 이온의 량에 따라 NMR 스펙트라의 화학적이동값이 다르게 나타났으며 xerogel 구조 내에서 다른 환경의 리튬이온 자리가 존재함을 알 수 있었다. 합성에 이용한 $V_2O_5$의 초기농도 변화와 pH 변화에 따른 xerogel의 전기화학적 특성은 큰 차이가 나타나지 않았으며, 전지용량은 이온교환수지법으로 제조한 xerogel과 비슷한 140 mAh/g으로 나타났다.

• 대한환경공학회지
• /
• 제37권6호
• /
• pp.357-362
• /
• 2015

새로운 형태의 $TiO_2$가 합성된 코코넛 껍질 분말 복합체를 제조하기 위해 솔-젤 합성법과 열처리를 사용하였고, 제조된 TCSPC는 MB를 대상으로 제거효율을 평가하였다. TCSPC를 제조하기 위한 최적의 조건은 반응표면분석법의 중심합성설계법을 사용하여 조사하였다. 소성온도가 $400^{\circ}C$에서 $600^{\circ}C$ 증가함에 따라 BET 비표면적은 $254m^2/g$에서 $398m^2/g$로 증가하고 기공용적, 기공률 또한 증가하며, 그 이유는 소성공정 시 발생한 열분해(pyrolysis)에 의해 코코넛 껍질 분말이 가지고 있는 헤미셀룰로우스, 셀룰로우스, 그리고 리그닌과 같은 물질들의 polymerization 반응 때문인 것으로 판단된다. 코코넛 껍질 분말의 양이 10 g에서 20 g으로 증가 할수록 BET 비표면적은 $303m^2/g$에서 $398m^2/g$로 증가하였으며, 30 g으로 증가 시에는 BET 비표면적은 $345m^2/g$으로 감소하는 경향을 나타내었다. Response optimization을 사용하여 얻은 최적의 합성조건은 소성온도 $642^{\circ}C$, 코코넛 껍질 분말 주입량이 22.7 g으로 나타났다.

• 대한화장품학회:학술대회논문집
• /
• 대한화장품학회 2003년도 IFSCC Conference Proceeding Book I
• /
• pp.178-191
• /
• 2003

OMC is essentialiy necessary compound in sun goods as organic UV protecting products. But the skin-trouble problem is raising because of skin penetration of OMC. In this study, non-capsulated pure OMC was compared with Organic-Inorganic-Nano-hybrid OMC for skin penetration force and SPF degree. Organic- Inorganic Nano-Hybrid OMC is OMC trapped in the pore of the mesoporous silica synthesized by the sol-gel method after OMC is nanoemulsified in the system of the hydrogenated Lecithin/ Ethanol/caprylic/capric triglyceride/OMC/water. OMC- nano- emulsion was obtained by a microfluidizing process at 1000bar and then micelle size in the nanoemulsion solution is 100-200nm range. Mesoporous silica nano-hybrid OMC was prepared by the process; surfactant was added in dissolved OMC-Nanoemulsion, then the rod Micelle was formed. OMC-nanoemulsion was capsulated in this rod Micelle and then silica precursor was added in the OMC-nanoemulsion solution. Through the hydrolysis reaction of the silica precursor, mesoporous silica concluding OMC-Nanocapsulation was obtained. The nano-hybrid surface of this OMC-Nanoemulsion-Inorganic system was treated with polyalkyl-silane compound. OMC-Mesoporous silica Nano-hybrids coated with polyalkyl-silane compound show the higher sun protecting factor (SPF Analyzer: INDEX 10-15) than pure OMC and could reduce a skin penetration of OMC. The physico-chemical properties of these nano-hybrids measured on the SPF index, partical size, strcture, specific surface area, pore size, morphology, UV absorption, rate of the OMC dissolution using SPF Analyzer, Laser light scattering system, XRD, BET, SEM, chroma Meter, HPLC, Image analyzer, microfluidizer, UV/VIS. spectrometer.

• 한국재료학회지
• /
• 제21권1호
• /
• pp.67-71
• /
• 2011

La doped CuO-ZnO-$Al_2O_3$ powders are prepared by sol-gel method with aluminum isopropoxide and primary distilled water as precursor and solvent. In this synthesized process, the obtained metal oxides caused the precursor such as copper (II) nitrate hydrate and zinc (II) nitrate hexahydrate were added. To improve the surface areas of La doped CuO-ZnO-$Al_2O_3$ powder, sorbitan (z)-mono-9-octadecenoate (Span 80) was added. The synthesized powder was calcined at various temperatures. The dopant was found to affect the surface area and particle size of the mixed oxide, in conjunction with the calcined temperature. The structural analysis and textual properties of the synthesized powder were measured with an X-ray Diffractometer (XRD), a Field-Emission Scanning Electron Microscope (FE-SEM), Bruner-Emmett-Teller surface analysis (BET), Thermogravimetry-Differential Thermal analysis (TG/DTA), $^{27}Al$ solid state Nuclear Magnetic Resonance (NMR) and transform infrared microspectroscopy (FT-IR). An increase of surface area with Span 80 was observed on La doped CuO-ZnO-$Al_2O_3$ powders from $25m^2$/g to $41m^2$/g.

• 멤브레인
• /
• 제15권2호
• /
• pp.105-113
• /
• 2005

표면 개질한 다공성 금속 지지체에 초음파 분무 열분해법을 이용하여 silica막을 합성하고, 고온 기체 선택 투과 분리 특성을 조사하였다. Tetraethyl orthosilicate (TEOS)를 전구체로 하여 지지체 세공을 통한 감압 진공을 하면서 873K에서 표면에 defect 없이 균일한 양질의 silica막이 형성되었다. 투과 온도 523 K에서 silica막의 수th/질소 및 수증기/메탄을 분리 계수가 각각 17 및 16 정도의 우수한 선택 투과 성능을 나타냈다. 다공성 금속 지지체의 불균일한 기공에 silica 분체 및 $\gamma-alumina$층을 중간층으로 도입하고, 그 위에 열분해법에 의한 silica를 합성한 결과, Knudsen 확산에 의한 투과 영역의 세공이 완전히 제거되어 높은 수소 및 수증기 선택성을 가지는 복합 막이 형성되었다.

• Bulletin of the Korean Chemical Society
• /
• 제35권3호
• /
• pp.913-918
• /
• 2014

Five mol % tungsten-doped tin oxide ($W_{0.05}Sn_{0.95}O_2$, TTO5) was prepared by co-precipitation of $SnCl_4{\cdot}5H_2O$ and $WCl_4$, followed by calcination at $1000^{\circ}C$. The as-prepared TTO5 was in the pure cassiterite phase with a particle size of ~50 nm and optical bandgap of 2.51 eV. Herein it was applied for the formation of TTO5/$TiO_2$ heterojunctions by covering the TTO5 surface with $TiO_2$ by sol-gel method. Under visible-light irradiation (${\lambda}{\geq}420$ nm), TTO5/$TiO_2$ showed a significantly high photocatalytic activity in removing gaseous 2-propanol (IP) and evolving $CO_2$. It is deduced that its high visible-light activity is caused by inter-semiconductor holetransfer between the valence band (VB) of TTO5 and $TiO_2$, since the TTO5 nanoparticle (NP) exhibits the absorption edge at ~450 nm and its VB level is located more positive side than that of $TiO_2$. The evidence for the hole-transport mechanism between TTO5 and $TiO_2$ was also investigated by monitoring the holescavenging reaction with 1,4-terephthalic acid (TA).