• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.6
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• pp.583-590
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• 2013

Variable emittance radiators can be used in a thermal management system in space because their total emittance changes depending on the temperature of the system. When the temperature of the system decreased, the emittance also decreased so as to minimize the heat loss to the environment. In contrast, when the temperature of the system increased, the emittance also increased such that radiation cooling could occur. Thermochromic materials, whose emittance is a function of the temperature, are often used in variable emittance radiators because no additional parts are needed. In this study, we fabricated a variable-emittance coating by using a sol-gel method based on LSMO ($La_{1-x}Sr_xMnO_3$) and experimentally characterized the emittance change with respect to temperature. Furthermore, we also examined the stability of LSMO film in space environments by exposing it to extremely low pressure and temperature.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.31 no.4
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• pp.166-173
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• 2021

The rutile phase of TiO₂ forms a stable phase at high temperatures compared to anatase phase, but the stable temperature range of anatase changes depending on the synthesis conditions. In this study, nano-sized TiO₂ was synthesized by the Sol-gel method using TiOSO₄ and a mixed solvent of ethanol and distilled water, and the phase change of anatase and rutile according to pH and heat treatment temperature was investigated. Changes in the ratio of anatase and rutile were observed by changing the pH (3, 5, 7, 9) and heat treatment temperature (500, 600, 700, 800, 900℃) conditions of the prepared TiO₂. As a result of observing these changes through XRD and FE-SEM analysis, anatase TiO₂ at 500℃ and rutile TiO₂ at 900℃ were observed. According to the pH, at these intermediate temperatures of 600, 700 and 800℃, the ratio of anatase and rutile changes. At 700℃, it was concluded that pH = 3~5 had a larger ratio of anatase TiO₂, and pH = 7~9 had a larger ratio of rutile TiO₂.

• Corrosion Science and Technology
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• v.12 no.1
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• pp.27-33
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• 2013

According to its merits about high curing speed and low emission of volatile organic compounds, UV curable inorganic-organic coating technology has been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. Based on the tetra-ethylorthosilicate(TEOS) and methacryloxypropyl trimethoxysilane(MPTMS), inorganic sol was synthesized and formed hybrid networks with UV curable acrylic monomer, 6-hexanediol diacrylate(HDDA), trimethylolpropane triacrylate(TMPTA), pentaerylthritol triacrylate(PETA). Several methods were used to test their properties such as salt spray test, potentiodynamic measurement, tape peel test, etc. It was shown that anti-corrosive property and stability of storage were affected by the molecular ratios of inorganic and organic compounds. It was not only the stability of storage, but had a excellent anti-corrosive, paint adhesive, and anti-solvent properties in a final molar ratios of 0.6/0.04/0.86/0.005 (TEOS/MPTMS/Acetone/HNO3) and 0.08/0.106/0.081/0.02 (TMPTA/HDDA/PETA/photo initiator).

• Applied Chemistry for Engineering
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• v.4 no.3
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• pp.482-487
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• 1993

Organic nonlinear optical materials such as MNA(2-Methyl-4-nitro-aniline), Carbazole 1(5-Nitro-9-hydroxyethyl Carbazole), Carbazole 2(5-Nitro-9-ethyl Carbazole) and DR 1(Disperse Red 1) were incorporated into silica matrix to form a composite thin films. The thermal stability and degree of degradation were compared to these organic-inorganic composite film. Among those films, Carbazole 1 and DR 1 which have terminal -OH group showed enhanced stability for thermal degradation. The effect of polarization and degree of relaxation for the composite thin films incorporated with Carbazole 1 were measured by the absorbance change of UV spectra with time. With polarization treatment of Carbazole 1 incorporated composite film, the intensity of UV absorbance was remarkably reduced. And slow relaxation of Carbazole 1 molecule was suggested from the slightly recovered intensity of UV absorbance after removing the electric field at rooma temperature.

• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2178-2182
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• 2011

Recently, the synthesis of ordered macroporous materials has received much attention due to its potential use as photonic band gap materials.$^1$ In this study, we have used the three-dimensional (3D) latex array template impregnated with benzenesulfonic acid (BSA), which is capable of catalyzing the reaction using tetraethyl orthosilicate (TEOS) as a precursor and distilled water. The polystyrene (PS) templates were reacted with TEOS in $scCO_2$ at 40 $^{\circ}C$ and at 80 bar. In the reactor, TEOS was filtrated into the PS particle lattice. After the reaction, porous silica materials were obtained by calcinations of the template. The stability test of the PS template in pure $CO_2$ was conducted before the main experiment. Scanning electron microscopy (SEM) images showed that the reaction in $scCO_2$ takes place only on the particle surface. This new method using $scCO_2$ has advantages over conventional sol-gel processes in its capability to control the fluid properties such as viscosity and interfacial tension. It has been found that the reaction in $scCO_2$ occurs only on the particle surface, making the proposed technique as more rapid and sustainable method of synthesizing inverse opal materials than conventional coating processes in the liquid phase and in the vapor phase.

• Korean Journal of Agricultural Science
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• v.38 no.3
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• pp.493-504
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• 2011

This study was carried out to safety evaluation, the practical application and improvement of design method of the agricultural reservoir due to raising embankments. Also, it was to compare and analyze the pore water pressure (PWP), seepage (leakage) quantity and piping phenomenon according to high water table and rapid drawdown. The seepage analysis by finite element analysis was used for steady state and transient condition. The pore water pressure distribution for steady state and transient condition showed positive(+) PWP on the upstream slope, it was gradually changed negative(-) PWP on the downstream slope. The PWP in the core ranged from 100 ~ -33 kPa, the seepage line in the incline-type core suddenly decreased towards the lower levels from the higher levels. The PWP according to rapid drawdown is remained in the vicinity of the upstream slope, therefore, it is investigated to be in an unstable state by the slope stability analysis. The PWP after raising embankments showed smaller than in the before raising embankments. It was likely to be the piping phenomenon because the gradients in the before raising embankments showed largely at downstream slope, and the stability for piping in the after raising embankments increased stable state. The seepage quantity per 1 day and the leakage per 100m for the steady state and transient condition appeared to be safe against the piping. It reduced slightly regardless of the transient condition before the raising embankments and it decreased largely about 2.4 times in the early days after the raising embankments.

• Journal of The Korean Society of Agricultural Engineers
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• v.58 no.2
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• pp.31-44
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• 2016

This study analyzed pore water pressure, earth pressure and settlement through field monitoring on the project site in which raising embankments are being built through backside extension, and compared the behaviors of seepage analysis, slope stability analysis and stress-strain during flood water levels and rapid drawdown under steady state and transient condition. The variation of pore water pressure showed an increase during the later period in both upstream and downstream slope, with downstream slope more largely increased than upstream slope overall. The variation of earth pressure increased according to the increase of embankment heights, while the change largely showed in the upstream slope, it was slowly increased in the downstream slope. The settlements largely increased until 23 m as embankment heights increased, and showed very little settlement overall. Under a steady state and transient conditions, the seepage quantity per day and leakage quantity per 100 m of embankment against total storage were shown to be stable for piping. The hydraulic gradient at the core before and after raising embankments was greater than the limit hydraulic gradient, showing instability for piping. The safety factor of upstream and downstream slopes were shown to be very large at a steady state, while the upstream slopes greatly decreased at a transit conditions, downstream slopes did not show any significant changes. The horizontal settlements, the maximum shear strain and stress are especially distributed at the connecting portion of the existing reservoir and the new extension of backside. Accordingly, the backside extension method should be designed and reinforced differently from the cases of other types reservoirs.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.16 no.5
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• pp.247-255
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• 2023

In order to create a virtual reality space in the metaverse, accurate tracking sensors and implementation are required. Most government agencies and corporations performs tracking to use their own tracking sensors and a base stations, such as VIVE. The VIVE method may have tracking problems due to spatial constraints and obstacles or nearby structures, and it is also that the number of people that can be accommodated within the space is also limited. In this paper, we designed and implemented metaverse using an IR sensor tracking system to freely track the spatial virtual reality metaverse, and we experimented contents in metaverse by placing IR sensors additionally on the floor and ceiling if needed in order to flexibly configure the metaverse space. As a result of the experiment, the tracking stability of the IR-tracking system was approximately 12% higher than the VIVE method. Additionally, adding more tracking sensors on the floor increases tracking stability and allows for a stable representation of virtual space.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.2
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• pp.71-76
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• 2019

Recently, the demand of labels for product management is increasing, as the automation system becomes more common. the development of functional labels which can be used in various environments has been rapidly proceeded. In the case of a printed circuit board, barcode labels with thermal and chemical stability are generally used due to a high temperature process around $300^{\circ}C$ and chemical cleaning in the manufacturing process. However, the yellowing phenomenon of labels that can lower the resolution of printed barcode image still needs to be prevented. In this study, we prepared a composite coating layer using a silica inorganic binder and a titanium dioxide white pigment, and developed a functional labels with thermal and chemical stability. The silica inorganic binder prepared by sol-gel process was confirmed to show excellent adhesion and abrasion resistance with the polyimide film. The white coating layer could be formed on the polyimide film with mixing the silica inorganic binder and titanium dioxide white pigment. The prepared coating layer showed excellent whiteness and glossiness above $400^{\circ}C$. The excellent chemical stability of the coating layer was also confirmed by the chemical treatment with acidic (pH 1.6) and basic (pH 13.6) cleaners.

• Bulletin of the Korean Chemical Society
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• v.31 no.2
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• pp.309-314
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• 2010

The surface modified $LiMn_2O_4$ materials with Li-Fe composites were prepared by a sol-gel method to improve the electrochemical performance of $LiMn_2O_4$ and were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), and transmission electron microscopy (TEM)-EDS. XRD results indicate that all the samples (modified and pristine samples) have cubic spinel structures, and XRD, XPS, and TEM-EDS data reveal the formation of $Li(Li_xFe_xMn_{2-2x})O_4$ solid solution on the surface of particles. For the electrochemical properties, the modified material demonstrated dramatically enhanced reversibility and stability even at elevated temperature. These improvements are attributed to the formation of the solid solution, and thus-formed solid solution phase on the surface of $LiMn_2O_4$ particle reduces the dissolution of Mn ion and suppresses the Jahn-Teller effect.