• International Journal of Advanced Culture Technology
• /
• v.3 no.2
• /
• pp.110-117
• /
• 2015

10 wt% (Ni-Co) catalysts with different Ni and Co content : 10%Ni, 9%Ni1%Co, 7%Ni3%Co, 5%Ni5%Co, 3%Ni7%Co, and 10%Co; were prepared using sol-gel method followed by incipient wetness impregnation method. To investigate the catalytic activity including the stability, dry methane reforming were demonstrated over the pelletized catalysts at $620^{\circ}C$ under atmospheric pressure in a $CH_4:CO_2:N_2$ feedstock for 360 min. The results showed that bimetallic catalysts with the Co content equal to or greater than 3% were more stable than monometallic catalysts (10%Ni and 10%Co). The temperature programmed hydrogenation interpreted that the additional of Co into Ni catalyst improved the carbon resistance from methane cracking. Promoted this type of bimetallic catalyst using 1wt% K (trimetallic catalyst) prevented the carbon formation on the catalyst. The temperature programmed desorption of $CO_2$ indicated that this trimetallic catalyst has a greater number of strong basic sites. Moreover, the appearance of K lowered the number of weak basic sites and decreased the conversion of methane by 12 %.

• The Transactions of the Korean Institute of Power Electronics
• /
• v.20 no.6
• /
• pp.526-533
• /
• 2015

A new algorithm is proposed for the estimation of equivalent grid impedance at the point of common coupling of a grid-tie inverter output. The estimated impedance parameter can be used for the improvement of the performance and the stability of the distributed generation system. The estimation error is inevitable in the conventional estimation method because of the axis rotation due to PLL. In the conventional estimation error, the d-q voltage and current are used for the calculation of the impedance with active and reactive current injections. Conversely, in the proposed algorithm, the negative sequence current is injected, and then the negative sequence voltage is measured for the impedance estimation. As the positive and negative sequence current controller is independent and the PLL is based on the positive sequence component only, the estimation of the equivalent impedance can be achieved with high accuracy. Simulation and experimental results are compared to validate the proposed algorithm.

• The Transactions of the Korean Institute of Electrical Engineers B
• /
• v.51 no.9
• /
• pp.515-521
• /
• 2002

This paper presents the scheme that improves control responsibility and stability of the controlled-PM electromagnet levitation system with zero Power controller. A magnetically levitation system is used widely because friction can almost be disappeared. But it is difficult to control due to restraint of controllable area and nonlinear characteristics of electromagnetic force, which is proportioned to a square of the magnetic flux density and is in inverse proportion to a square of the air-gap. So, the application of observer theory in which the levitation system is considered to be a linear dynamic model has resulted in omitting the time dependence on mover's speed. Consequently, the performance of the observer is quite poor during transients. Therefore, this paper proposed the controlled-PM electro-magnetic levitation control method in which the variable load is estimated by using the reduced order extended luenverger observer and its system is controlled at a new zero power equilibrium air-gap position. It is also verified that the proposed control method improve the control performance through simulation and experiment.

• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 2006.09a
• /
• pp.487-488
• /
• 2006

Novel bisphenol-based wholly aromatic poly(ether sulfone-ketone) copolymer containing pendant sulfonate groups were prepared by direct aromatic nucleophilic substitution polycondensation of 4,4-difluorobenzophenone, 2,2'-disodiumsulfonyl-4,4'-fluorophenylsulfone (40mole% of bisphenol A) and bisphenol A. Polymerization proceeded quantitatively to high molecular weight in N-methyl-2-pyrrolidinone at $180^{\circ}C$. Organic-inorganic composite membranes were obtained by mixing organic polymers with hydrophilic $SiO_2$ (ca. 20nm) obtained by sol-gel process. The polymer and a series of composite membranes were studied by FT-IR, $^1HNMR$, differential scanning calorimetry (DSC) and thermal stability. The proton conductivity as a function of temperature decreased as $SiO_2$ content increased, but methanol permeability decreased. The nano composite membranes were found to posse all requisite properties; Ion exchange capacity (1.2meq./g), glass transition temperatures $(164-183\;^{\circ}C)$, and low affinity towards methanol $(4.63-1.08{\times}10^{-7}\;cm^2/S)$.

• Journal of Energy Engineering
• /
• v.25 no.2
• /
• pp.65-78
• /
• 2016

Initial studies of the photocatalyst has been developed from the field relating to the conversion and storage of solar energy. Recently, the study of the various organic decomposition compound and the water purification and waste water treatment by ultraviolet irradiation in the presence of light or a photocatalyst are being actively investigated. In addition, the oxidized material-carbon nanotubes, graphene-nanocomposites have been studied. Such a complex is suitable as a material constituting the solar cells and photolysis nanoelectronics, including the flexible element due to thermal and chemical stability.

• Proceedings of the KIEE Conference
• /
• 2007.07a
• /
• pp.1363-1364
• /
• 2007

The composites such as Sn-CNTs, $SnSb_{0.5}$-CNTs and $CoSb_3$-CNTs have attracted much attention in the past years owing to their good overall properties. In these samples, intermetallic compounds show high specific capacities. Recently, interest in metal oxides such as $Al_{2}O_{3}$, MgO and $TiO_2$ has been largely stimulated by the realization that they can improve the cycling stability of the Li-ion battery electrodes. The reversible capacity of the $TiO_2$/CNTs composite reaches 168 mAh $g^{-1}$ at the first cycle and remains almost constant during long-term cycling. In this study, a nanocomposite of $TiO_2$/CNTs was prepared by sol-gel method and its electrochemical properties as anode materials for Li-ion batteries were studied by galvanostatic cycling, cyclic voltammograms (CV) and electrochemical impedance spectroscopy (EIS).

• Proceedings of the Korean Vacuum Society Conference
• /
• 2000.02a
• /
• pp.100-100
• /
• 2000

Aluminium oxide (Al2O3) films have been investigated for many applications such as insulating materials, hard coatings, and diffusion barriers due to their attractive electrical and mechanical properties. In recent years, application of Al2O3 films for dielectric materials in integrated circuits as gates and capacitors has attracted much attention. Various deposition techniques such as sol-gel, metalorganic decomposition (MOD), sputtering, evaporation, metalorganic chemical vapor deposition (MOCVD), and pulsed laser ablation have been used to fabricate Al2O3 thin films. Among these techniques, reactive sputtering has been widely used due to its high deposition rate and easy control of film composition. It has been also reported that the sputtered Al2O3 films exhibit superior chemical stability and mechanical strength compared to the films fabricated by other processes. In this study, Al2O3 thin films were deposited on Pt/Ti/SiO/Si2 and Si substrates by DC reactive sputtering at room temperature with variation of the Ar/O2 ratio in sputtering ambient. Crystalline phase of the reactively sputtered films was characterized using X-ray diffractometry and the surface morphology of the films was observed with Scanning election microscopy. Effects of Th Ar/O2 ratio characteristics of Al2O3 films were investigated with emphasis on the thickness dependence of the dielectric properties. Correlation between the dielectric properties and the microstructure was also studied

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.02a
• /
• pp.190-190
• /
• 2010

Zinc oxide is the most attractive material due to the large direct band gap (3.37 eV), excellent chemical and thermal stability, and large exciton binding energy (60 meV). Recently, ZnO nanorods were used as the high efficient antireflection coating layer of solar cells based on silicon (Si). In this reports, we studied the effects of rapid thermal annealing (RTA) treatment on optical properties of ZnO nanorods. For fabrication of ZnO nanorods, there are many methods such as hydrothermal method, sol-gel method, and metal organic chemical vapor deposition method. Among of them, we used the conventional wet chemical method which is simple and low temperature growth. In order to synthesize the ZnO nanorods, the ZnO films were deposited on Si substrate by RF magnetron sputtering at room temperature and the samples were dipped to aqua solution containing the zinc nitrate and hexamethylentetramines (HMT). The synthesis process was achieved in keeping with temperature of $90-95^{\circ}C$ and under constant stirring. The morphology of ZnO nanorods on glass and Si was characterized by scanning electron microscopy. For the analysis of antireflection performance, the reflectance and transmittance were measured by spectrophotometer. And for analyzing the effects of RTA treatment on ZnO nanorods, crystalline properties were investigated by X-ray diffraction measurements and optical properties was estimated by photoluminescence spectra.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.28 no.1
• /
• pp.214-224
• /
• 2002

High concentrated $TiO_2$ nano colloids were synthesized by sol-gel method. Reactions were performed in $TiCl_4$/HCl/$H_2O$ aqueous solution and the conditions of particles such as shape, size and aggregation, etc. were controlled by polymerization and adsorption of acrylamide in surface of $TiO_2$ nano particles. And also, aminopropyltriethoxysilane was added instead of acrylamide and compared each other. The prepared colloids were well dispersed and showed the strong absorption peaks at 350nm-370nm which is blue shifted to 20-30nm, compared to macro particles. The obtained techniques from $TiO_2$ nato colloids synthesis were utilized in coating on boron nitride powders which are nonpolar and isoelectronic materials of carbon. Their surface morphology, structure, thermal stability and U. V absorption chracteristics were examined by SEM(Scanning Electron Microscopy), XRD(X-ray diffraction), TG/DTA(Thermogravimetric and Differential Thermal Analysis), UV-VIS(Ultraviolet-Visible Spectroscopy).

• PNF and Movement
• /
• v.18 no.1
• /
• pp.55-64
• /
• 2020

Purpose: The purpose of this study was to compare the strength and walking ability of chronic stroke patients following either proprioceptive neuromuscular facilitation (PNF) pattern training with pressure biofeedback units (feedback group) or PNF pattern training without pressure biofeedback units (control group). Methods: Eighteen participants with chronic stroke were recruited from a rehabilitation hospital. They were divided into two groups: a feedback group (n = 8) and a control group (n = 10). They all received 30 minutes of neurodevelopmental therapy and PNF training for 15 minutes five times a week for three weeks. Muscle strength and spatiotemporal gait parameters were measured. Muscle strength was measured by hand-held dynamometer; gait parameters were measured by the Biodex Gait trainer treadmill system. Results: After the training periods, the feedback group showed a significant improvement in hip abductor muscle strength, hip extensor muscle strength, step length of the unaffected limb, and step time of the affected limb (p<0.05). Conclusion: The results of this study showed that proprioceptive neuromuscular facilitation pattern training with pressure biofeedback units was more effective in improving hip muscle strength and walking ability than the proprioceptive neuromuscular facilitation pattern training without pressure biofeedback units. Therefore, to strengthen hip muscles and improve the walking ability of stroke patients, using pressure biofeedback units to improve trunk stability should be considered.