• 한국지반공학회논문집
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• 제19권5호
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• pp.243-252
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• 2003

저투수성 오염토양을 정화하기 위한 방안으로 환경이중파일 공법을 제안하였다. 환경이중파일은 저투수성 오염지반에 적용되어 배수촉진, 오염정화, 말뚝에 의한 지반지지력 증가의 복합적인 기능을 수행하여 부지를 재활용할 수 있도록 하는 One Step Process 개념의 신기술이다. 기술의 현장적용성을 평가하기 위해 환경이중파일의 배수, 강도, 정화특성을 일련의 실험 등을 통해 평가하였으며, 정화 및 연약지반개량 효과를 얻을 수 있음을 확인할 수 있었다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2004년도 춘계학술발표회
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• pp.873-881
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• 2004

A serious of EK remediation tests on contaminated soil are performed under unsaturated conditions and analyzed for electrical potential, water content, pH and so on. The results indicated that electrical potential and pH distributions in the sample are dependent on the amount and inward/outward flow of hydrogen ion. Specially, for the closed system the water content is largely decreased with the flow of hydrogen. The maximum electrical conductivity is measured at the catholyte of CEM(Sealing) test and directly related to the remedial efficiency. Although pHs in the region near to the anode are similarly developed, the different concentration of lead is measured with the electrical gradient contrary to the lead concentration dependent on pH within the sample.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 추계학술발표회
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• pp.356-359
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• 2003

Polycyclic aromatic hydrocarbons (PAHs) are representative hydrophobic organic carbons (HOCs). Surfactant-enhanced electrokinetic (EK) remediation is an innovative in-situ technology that can effectively remove HOCs from low-permeability soils. In this study, the electrokinetic remediation using Tergitol 15-S-12, a nonionic surfactant, was conducted for the removal of phenanthrene from kaolinite. Tergitol 15-S-12 was used at concentrations of 1.5, 2.0, 2.5 and 7.5 g/L to enhance the solubility of phenanthrene. When the surfactant solution was applied to EK system, high electrical potential gradient was maintained and the amount of electroosmotic flow decreased. Removal efficiency of phenanthrene was proportional to the concentration of Tergitol 15-S-12 because the solubility and mobility of phenanthrene was enhanced by surfactant micelle. Therefore, the suitable concentration of nonionic surfactant Tergitol 15-S-12 is expected to improve the removal efficiency of PAHs in EK remediation.

• Journal of Ecology and Environment
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• 제35권4호
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• pp.307-311
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• 2012

This study was conducted to evaluate the dynamics of soil respiration (total soil and heterotrophic respiration) following fertilizer application in red pine forests. Fertilizer (N:P:K = 113:150:37 kg/ha), which reflects current practices in Korean forest, was applied in April 2011, and total soil and heterotrophic respiration rates were monitored from April 2011 to March 2012. Monthly variation of total soil and heterotrophic respiration rates were similar between the fertilizer and control treatments, as soil temperature was the dominant factor controlling the both rates. Total soil respiration rates during the study period were not significantly different between the fertilizer (0.504 g $CO_2\;m^{-2}\;h^{-1}$) and control (0.501 g $CO_2\;m^{-2}\;h^{-1}$) treatments. However, the proportion of heterotrophic respiration was higher in the fertilizer (78% of total soil respiration rates) than in the control (62% of total soil respiration rates) treatments. These results suggest that current fertilizer practices in Korea forest soil do not substantially affect total soil respiration rates.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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• pp.202-205
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• 2001

In this study, the electrokinetic remediation test for the kaolin contaminated by lead was performed and voltage, zeta potential, pH distribution, current, contamination transport in soil sample were studied and finite differential numerical analysis program(HERP) for a contaminated soil were compared with those of test. From the result of HERP, in the anode it was represented that the rest concentration was decreased with the voltage. Hence, if treatment time was continued for a long in the constant voltage, comparing with sample having no change in the rest concentration, it is considered that the voltage gradient is the control factor of the rest concentration.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2000년도 추계학술대회
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• pp.96-98
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• 2000

Column experiments were peformed to evaluate the efficiency of surfactant flushing for remediation of non-aqueous phase liquid (NAPL) in the soil under controlled conditions. In column experiment less than 0.1 % of the original mass of tetrachloroethylene (PCE), remained in the column after 15 pore volumes of 1% sorbitan monooleate solution were passed through columns. To determine the influence of soil parameters that may affect the remediation process, column tests were repeated with different values of grain size, application rate, surfactant type, surfactant concentration, and solution viscosity (polymer mixed with surfactant). Experimental works suggest that surfactant flushing has a great potential to rapidly remove mass from NAPL in the soil.

• 한국지반공학회논문집
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• 제18권1호
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• pp.49-57
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• 2002

오염지반 정화를 위한 Electrokinetic 처리 과정에서 지반에 전류를 적용하면 흙물 시스템 내에서 발생하는 유체의 이동 현상과 계면의 특성 변화가 발생하여 Electrokinetic 반응에 영향을 미친다. 본 논문에서는 지반 내에서 발생하는 전기적, 화학적 변수와 그 변화 특성을 규명하고자 실내실험을 수행하여, 시료의 전압, 전류, 제타포텐셜, pH등의 전기 화학적 현상을 연구하였으며 이러한 인자들의 특성변화를 모델링하는 기법을 제시하였다. 그 결과 정화 도중 전압, 전류 변화를 각 농도에서 시간에 따른 지수함수로 표현할 수 있었으며 제타포텐셜의 변화를 pH와 오염농도에 따라 모델링 할 수 있었다.

• 대한지하수환경학회지
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• 제3권2호
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• pp.60-69
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• 1996

산업의 급진적인 발달로 수많은 유해물질이 잔연계로 유출되고 있으며 이들 오염물질은 환경매 체중 최종 수용체인 토양에 유입되어 지하수까지도 위해를 주고 있다. 한편 토양 및 지하수는 유해물질에 의해 일단 오염되면 인위적으로 복원하기 전에는 치유가 되지 않는 특성을 가지고 있어 미국이나 서구유럽의 국가 등 우리보다 산업화가 먼저 이루어진 나라에서는 오염부지 정화 및 관련기술의 개발에 막대한 예산을 투자하고 있다. 그러나 우리나라는 토양오염으로 인한 실태파악이 미비하고 오염부지정화를 위한 관련기술의 개발이 아직 초기단계로 적정관리를 위한 기반이 취약한 설정이다. 따라서 본보에서는 오염부지의 적정 관리를 위해 외국에서 개발·이용되고 있는 정화기술과 오염부지 복구시 관리절차에 대해 살펴보았다.

• Nuclear Engineering and Technology
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• 제34권1호
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• pp.1-8
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• 2002

After kaolin clay was artificially contaminated with Co$^{2+}$ ion, the remediation characteristics were analyzed by the electrokinetic method. Ethanoic buffer was injected in the soil column and $CH_3$COOH was continuously inputted to the cathode reservoir to restrain the pH increase. Since the pH of the cathode side of the soil column was 4.0 initially and increased to only 6.5 after remediation for 43.6 hours, precipitate, Co(OH)$_2$, was not formed in the column. The effluent rate increased with the passage of time and Co$^{2+}$ removal in the column at the initial time were mainly controlled by ion migration. 13.1% of the total amount of Co$^{2+}$ in the soil column was removed in 10 hours, 46.8% of the total Co$^{2+}$ in 20.8 hours, 71.7% of the total Co$^{2+}$ in 30.1 hours, and 94.6% of the total Co$^{2+}$ in 43.6 hours. Meanwhile, residual concentrations in the column calculated by the developed model were similar to those by experiment. experiment.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 추계학술발표회
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• pp.310-313
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• 2003

The precipitation of heavy metals within the region of pH jump is inevitable in the conventional electrokinetic remediation technology. This study prevents the interest species from precipitating through the injection of flushing solutions in which HCl, acetic acid, citric acid, EDTA and SDS dissolved. The cumulative flow resulted from electroosmosis appear in order of Citric acid