• Journal of Korean Society on Water Environment
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• v.24 no.5
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• pp.533-536
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• 2008

Korean water quality guidelines for agricultural were derived to protect agricultural water uses according to the Canadian methodology. The adverse effect of heavy metals in agricultural water was of concern due to its persistence, bioaccumulation and ecotoxicity to crop plants. The ecotoxicity data of cadmium, copper, lead, and zinc were collected for the crops grown in Korea, and used to estimate the species maximum acceptable toxicant concentration (SMATC), which corresponds to the water quality guideline. Values of irrigation per year and soil bulk density were revised to reflect the Korean situation. The estimated guideline values for cadmium, copper, lead, and zinc were 0.01, 0.5, 0.1, and 1.0 mg/L, respectively. These values are in agreement with the agricultural water quality guidelines of foreign countries and current Korean water quality standard for the protection of public health. Current water quality standards in agricultural uses were for management of public water resource, and was not prepared to protect crop plants from contaminants. The results of this study will be a basis for the designation of Korean water quality guidelines for the protection of agricultural water uses in the future.

• Journal of Environmental Impact Assessment
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• v.29 no.3
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• pp.157-181
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• 2020

Sediments from rivers, lakes and marine ports serve as end points for pollutants discharged into the water, and at the same time serve as sources of pollutants that are continuously released into the water. Until now, the contaminated sediments have been landfilled or dumped at sea. Landfilling, however, was expensive and dumping at sea was completely banned due to the London Convention. Therefore, this study applied contaminated sedimentation soil of 'Royal Palace Livestock Complex' as soil purification method. Soil remediation methods were applied to pretreatment, composting, soil washing, electrokinetics, and thermal desorption by selecting overseas application cases and domestically applicable application technologies. As a result of surveying the site for pollutant characteristics, Disolved Oxigen (DO), Suspended Solid (SS), Chemical Oxygen Demand (COD), Total Nitrogen (TN), and Total Phosphorus (TP) exceeded the discharged water quality standard, and especially SS, COD, TN, and TP exceeded the standard several tens to several hundred times. Soil showed high concentrations of copper and zinc, which promote the growth of pig feed, and cadmium exceeded 1 standard of Soil Environment Conservation Act. In the pretreatment technology, hydrocyclone was used for particle size separation, and the fine soil was separated by more than 80%. Composting was performed on organic and Total Petroleum Hydrocarbon (TPH) contaminated soils. TPH was treated within the standard of concern, and E. coli was analyzed to be high in organic matter, and the fertilizer specification was satisfied by applying the optimum composting conditions at 70℃, but the organic matter content was lower than the fertilizer specification. As a result of continuous washing test, Cd has 5 levels of residual material in fine soil. Cu and Zn were mostly composed of ion exchange properties (stage 1), carbonates (stage 2), and iron / manganese oxides (stage 3), which facilitate easy separation of contamination. As a result of applying acid dissolution and multi-stage washing step by step, hydrochloric acid, 1.0M, 1: 3, 200rpm, 60min was analyzed as the optimal washing factor. Most of the contaminated sediments were found to satisfy the Soil Environmental Conservation Act's standards. Therefore, as a result of the applicability test of this study, soil with high heavy metal contamination was used as aggregate by applying soil cleaning after pre-treatment. It was possible to verify that it was efficient to use organic and oil-contaminated soil as compost Maturity after exterminating contaminants and E. coli by applying composting.

• Korean Journal of Remote Sensing
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• v.20 no.3
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• pp.175-188
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• 2004

The objectives of this study were to estimate leaf area index (LAI) as a function of image-derived vegetation indices, and to compare measured and estimated LAI to the results of crop model simulation. Soil moisture, crop phenology, and LAI data were obtained several times during the 2001 growing season at monitoring sites established in two central Missouri experimental fields, one planted to com (Zea mays L.) and the other planted to soybean (Glycine max L.). Hyper- and multi-spectral images at varying spatial. and spectral resolutions were acquired from both airborne and satellite platforms, and data were extracted to calculate standard vegetative indices (normalized difference vegetative index, NDVI; ratio vegetative index, RVI; and soil-adjusted vegetative index, SAVI). When comparing these three indices, regressions for measured LAI were of similar quality $(r^2$ =0.59 to 0.61 for com; $r^2$ =0.66 to 0.68 for soybean) in this single-year dataset. CERES(Crop Environment Resource Synthesis)-Maize and CROPGRO-Soybean models were calibrated to measured soil moisture and yield data and used to simulate LAI over the growing season. The CERES-Maize model over-predicted LAI at all corn monitoring sites. Simulated LAI from CROPGRO-Soybean was similar to observed and image-estimated LA! for most soybean monitoring sites. These results suggest crop growth model predictions might be improved by incorporating image-estimated LAI. Greater improvements might be expected with com than with soybean.

• Korean Journal of Environmental Agriculture
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• v.24 no.2
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• pp.106-116
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• 2005

This experiment was conducted to investigate available extraction capacity and potential mobility of heavy metal according to the distribution property and contamination level of heavy metals in soils and to suggest a reform measure of soil environment assessment methodology applied with soil quality and the official soil heavy metal test methods in domestic and foreign countries. The soils were collected from the natural forest paddy with long-term application of same type fertilizer, and paddies near metal mine and industrial complex. The post-treatment methods of soil were partial extraction, acid digestion and sequential extraction methods. For the heavy metal contents with different soil properties, it was shown that their natural forest and paddy soil were slightly low and similar to the general paddy soil, while their paddies near metal mine and industrial complex were higher than the standard level of Soil Environment Protection Act. Heavy metal concentrations in the soils with different soil properties had difference between $HNO_3\;and\;HNO_3+HCl$ extractant by US-EPA 3051a method. There were highly significant positive relationships in both two methods. It was appeared that the higher extractable concentration ratio with 0.1N-HCl to total heavy metal content with $HNO_3+HCl$ extractant the greater total heavy metal content. There were highly significant positive correlationship between total heavy metal content and extractable content with 0.1N-HCl. For extractable capacity of soil extractable solution compared to the total heavy metal content it was appeared that it extractable method with 0.1N-HCl was higher than those with EDTA and DTPA. In extractable ratio with 0.1N-HCl in the contaminated paddy soils near mine and industrial complex, it was shown that the lower soil pH, the higher total heavy metal content. The order of a potential mobility coefficient by distribution of heavy metal content with ie different typies in the soil was Cd>Ni>Zn>Cu>Pb. It could be known that contamination characteristics of heavy metals with different types of soils were affected by different heavy metal components, contamination degree and soil chemical properties, and heavy metal concentration with different extractable methods had great variations with adjacent environment. To be compared with assessment methodology of soil environment impact at domestic and foreign countries with our results, it might be considered that there was necessary to make a single analysis method based on total heavy metal content with environmental overloading concept because of various analysis methods for total heavy metal content and present analysis method with great variation according to soil environment. In spite of showing higher concentration of heavy metal with acidic digestion than the extractable method, it might be considered that there is need to be adjusted the national standard of soil heavy metal contamination.

• Journal of Soil and Groundwater Environment
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• v.16 no.2
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• pp.1-5
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• 2011

We surveyed the citizens opinion about springs in Seoul for two years from 2008 to 2009. It was found that spring water was mostly used by citizens older than 50, and that 29.5% of citizens used purified tap water as drinking water, 27.2% of them used boiled tap water, 21.1% of them used spring water, and 12.1% of them used bottled water. Citizens who store spring water more than a day are 76.7%. Although many citizens (70.3%) knew that water quality had been tested, 40% of them didn't care about checking the certificate of water quality analysis. Once recognized that the spring water was unfit for drinking exceeded standard of drinking water, 85% of citizens would rather not use the spring water.

• Journal of the Korean GEO-environmental Society
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• v.14 no.10
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• pp.29-37
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• 2013

In this study, we constructed the test embankment with four kinds of sections(2 kinds of bottom ash; tire shred-bottom ash mixture, weathered soil) in field and had been monitoring the behaviour of the test embankment and change of ground water quality for 1 year. In the geotechnical aspects, there was no relative difference of deformation in 4 test materials section and we could not see the possibility of the strength-reduction of coal ash materials by freezing inside of the embankment. In addition, no settlement was observed in the test sections because the base soil of the test sections was rigid enough that no consolidation was occurred. In the examination of water quality, all of the heavy metals and negative ions were detected below the drinking water standards except for sulfate($SO_4^{2-}$). In the beginning of measurement, higher concentrations of sulfate from 4 test sections were detected than drinking water standard for 20 days after beginning of the test but the concentrations decreased below the drinking water standard after 50 days after the tests.

• Journal of Soil and Groundwater Environment
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• v.26 no.4
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• pp.8-19
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• 2021

In this study, the evaluation standard for nitrate nitrogen contamination degree (WELCUP) was established using six factors that influence the groundwater quality in Jeju Island. To do this, weightings, ranges, and ratings were assigned for each factor and the relative possibility of nitrate nitrogen contamination degree was evaluated using WELCUP index for each well. As a result of calculating the WELCUP index using groundwater quality data of 5,112 wells in Jeju Island for 27 years (1993-2019), all 61 wells with the WELCUP index value higher than 100 are distributed in Daejung and Hangyung watershed with relatively large area of farmland in Jeju Island. In particular, as the ratio of private wells is more than 64%, it is necessary that systematic management is needed for private wells in terms of nitrate nitrogen contamination. Consequently, based on the results of applying the WELCUP evaluation standard, it is necessary to select the prioritization of nitrate nitrogen contamination pathways project for groundwater wells in Jeju Island.

• The Korean Journal of Ecology
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• v.23 no.1
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• pp.9-15
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• 2000

The effects of clearcutting on soil chemical ingredients and stream water quality have been investigated at a natural deciduous forest catchment within the Seoul National University Research Forest in Mt. Paekun, Chunnam province during the periods of 1993 to 1998. Soil chemical ingredients and stream water qualities were monitored at a 13 ha clearcutting site and a non-treatment site nearby. During the first and second years after harvesting, the levels of total-N, and exchangeable ions (K/sup ＋/, Na/sup ＋/, Ca/sup 2＋/, Mg/sup 2＋/) decreased compared to the values of before harvesting. During the fifth years after harvesting, these levels were significantly higher than those during the first and second years after harvesting. But the chemical characteristics of soil were not changed at all. pH of water in the harvesting area was 6.5 in stream water. Among the nutrients, Cd, Pb, Cu, and phosphate were not found, and the level of BOD reached at the level of the domestic use suitable for drinking. Turbidity, odor, taste, NH/sub 4//sup ＋/ -N, NO/sub 3//sup -/-N, standard plate count, and coliform were also low enough to be used as the domestic use for drinking by the near villagers. During the first and second years after harvesting, BOD increased to about 1 ppm. For that reason, the harvesting planning should be built in the harvesting area in consideration of the control of water quality in the stream.

• Journal of Environmental Science International
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• v.30 no.8
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• pp.659-671
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• 2021

The physicochemical properties of soil and the yield and quality of rice (Oryza sativa L. cv. Sailmi) were assessed using Italian ryegrass (Lolium multiflorum Lam. cv. Kowinearly)-rice double cropping systems in the paddy fields at Goseong and Miryang in southern Korea. The average temperatures during the ripening period were approximately 1 ℃ higher than the optimal temperature for rice ripening and the sunshine duration was reduced by frequent rainfall. Consequently, it was slightly below the optimal conditions required for rice ripening. In the soil at Goseong, winter Italian ryegrass cropping increased the pH, electrical conductivity, and the contents of organic matter, total nitrogen (T-N), available P₂O₅, K, Ca, and Mg than winter fallowing. Particularly, the contents of T-N and available P₂O₅increased significantly. In the soil at Miryang, Italian ryegrass slightly increased the electrical conductivity and the T-N, Mg, and Na contents. Therefore, winter Italian ryegrass cropping improved the physicochemical properties of paddy soils; however, Italian ryegrass-rice double cropping slightly reduced the culm length at both Goseong and Miryang, without markedly changing the panicle length or number compared to fallow-rice cropping. Furthermore, at Goseong, Italian ryegrass-rice double cropping slightly decreased the spikelet number and milled rice yield, and increased the ripened grain rate; however, at Miryang, contrasting results were observed. In addition, fallow-rice cropping revealed no differences in the head rice or opaque rice rates. The protein content was slightly increased in Italian ryegrass-rice double cropping, without significant changes in the amylose content or Toyo value, compared to that in fallow-rice cropping. The peak and breakdown viscosities were slightly decreased. These results indicate that winter Italian ryegrass cropping might alter rice taste but may not exhibit remarkable negative effects on rice cultivation. Therefore, Italian ryegrass-rice double cropping system is recommended for paddy fields in southern Korea. Nevertheless, to increase the rice yield and quality, fertilization standards for rice cropping that consider the changes in the T-N and organic matter contents in paddy fields caused by winter Italian ryegrass cropping need to be established.

• Journal of Soil and Groundwater Environment
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• v.20 no.6
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• pp.55-61
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• 2015

Based on the literature study for the determination of perchlorate in soil we chose the ion chromatography as a measurement method and decided to use 70 mM KOH as an eluent to avoid the interference derived from the co-elution of pyrophosphate (P₂O₇⁴⁻), tripolyphosphate (P₃O₁₀⁵⁻). Also we proposed to use air dried soil through 0.15 mm sieve and distilled water as an extractant. Under the these basic concepts, we carried out the experiments to set up the detail procedure like solid to liquid ratio (S/L ratio), extraction time, device for extraction and indicating factors for quality control (e.g. precision, accuracy, MDL, LOQ). In case of time and device for extraction, 5 hours of mechanical shaking or 1 hour of centrifugation showed better precision and accuracy than that of sonication for 1 hour According to these results, we proposed the extraction method combining 5 hours of mechanical shaking with 1 hour of centrifugation. From the aspect of S/L ratio, the ratio of 1/2 or 1/3 showed resonable precision and accuracy. In case of the ratio of 1/2, there would be some problems in the separation process when the proportion of fine particle is high. Therefore, we proposed the extraction ratio of solid to liquid as 1/3 instead of 1/2. With the consideration of cost effectiveness and soil salinity, we proposed the use of cartridge for removing the interfering anions like chloride, sulfate and carbonate in specific sample such as saline soil.