• Steel and Composite Structures
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• 제27권4호
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• pp.465-477
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• 2018

In this research, vibration and smart control analysis of a concrete foundation reinforced by $SiO_2$ nanoparticles and covered by piezoelectric layer on soil medium is investigated. The soil medium is simulated with spring constants and the Mori-Tanaka low is used for obtaining the material properties of nano-composite structure and considering agglomeration effects. With considering first order shear deformation theory, the total potential energy of system is calculated and by means of Hamilton's principle in three displacement directions and electric potential, the six coupled equilibrium equations are obtained. Also, based an analytical method, the frequency of system is calculated. The effects of applied voltage, volume percent and agglomeration of $SiO_2$ nanoparticles, soil medium and geometrical parameters of structure are shown on the frequency of system. Results show that with applying negative voltage, the frequency of structure is increased.

• Advances in concrete construction
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• 제6권6호
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• pp.585-610
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• 2018

In this study, vibration analysis of a concrete foundation-reinforced by $SiO_2$ nanoparticles resting on soil bed is investigated. The soil medium is simulated with spring constants. Furthermore, the Mori-Tanaka low is used for obtaining the material properties of nano-composite structure and considering agglomeration effects. Using third order shear deformation theory or Reddy theory, the total potential energy of system is calculated and by means of the Hamilton's principle, the coupled motion equations are obtained. Also, based an analytical method, the frequency of system is calculated. The effects of volume percent and agglomeration of $SiO_2$ nanoparticles, soil medium and geometrical parameters of structure are shown on the frequency of system. Results show that with increasing the volume percent of $SiO_2$ nanoparticles, the frequency of structure is increased.

• Structural Engineering and Mechanics
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• 제69권5호
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• pp.547-555
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• 2019

In this study, vibration analysis of a concrete foundation-reinforced by $SiO_2$ nanoparticles resting on soil bed is investigated. The soil medium is simulated with spring constants. Furthermore, the Mori-Tanaka low is used for obtaining the material properties of nano-composite structure and considering agglomeration effects. Using third order shear deformation theory or Reddy theory, the total potential energy of system is calculated and by means of the Hamilton's principle, the coupled motion equations are obtained. Also, based an analytical method, the frequency of system is calculated. The effects of volume percent and agglomeration of $SiO_2$ nanoparticles, soil medium and geometrical parameters of structure are shown on the frequency of system. Results show that with increasing the volume percent of $SiO_2$ nanoparticles, the frequency of structure is increased.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.186-191
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• 2004

Sorption kinetics of 2-chlorophenol(2-ChP), 2,4-dichlorophenol(2,4-DChP) and 2,4,5-trichlorophenol (2,4,5-TChP), onto montmorillonite modified with hexadecyltrimethyl ammonium cations(HDTMA-mont) were investigated. One-site mass transfer model(OSMTM) and two compartment first-order kinetic model(TCFOKM) were used to analyze kinetics. As expected from the number of model parameters involved, the three-parameter TCFOKM was better than the two-parameter OSMTM in describing sorption and desorption kinetics of chlorophenols in HDTMA-mont. For all chlorophenols, the results of OSMTM analysis indicate that the predominant deprotonated speciation(at pH 9.15) exhibited higher mass transfer coefficient( $k_{s}$ ) than the protonated speciation(at pH 4.85). This is because the deprotonated speciation has stronger hydrophobic interaction than protonated speciation. Most sorption completes in three hours. The fraction of the fast sorption and the first-order sorption rate constants for the fast and slow compartments in TCFOKM were determined by fitting experimental data to the TCFOKM. The results of kinetics reveal that the fraction of the fast sorption( $f_1$) and the sorption rate constants in the fast compartments( $k_1$) were in the order 2,4,5-TChP > 2,4-DChP > 2-ChP, which agrees with the magnitude of the $K_{ow}$ . The first-order sorption rate constants in the fast compartment(10$^{0.8}$ - 10$^{1.22}$ h $r^{-1}$ ) were much larger than those in the slow compartment(10$^{-1}$.74/ - 10$^{-2}$.622/ h $r^{-1}$ ).> ).).

• 한국지하수토양환경학회지:지하수토양환경
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• 제8권1호
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• pp.48-56
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• 2003

간단한 모형시추공을 이용한 전기전도도 측정실험을 실시하고 이로부터 시추공에서의 수리상수 결정에 관련된 제반기초 환경을 검증하고 실험에 의한 모델방정식을 유도하였다. 실험은 상대적으로 높은 염도를 공내수로 하고 증류수를 지하수를 사용하여, 지하수의 유입과 유출되는 유량을 일정하게 유지한 상태에서 전기전도도를 측정하는 것으로 이루어졌다. 관찰의 주 대상은 지하수의 유량, 공내수와 지하수 사이의 염도차 및 밀도차에 따른 공내에서의 전기전도도 변화 양상에 있었다. 실험결과, 공내에서의 시간에 따른 전기전도도 변화가 매우 일정한 양상으로 나타남을 보였으며, 유량과 전기전도도 변화율 사이에 양호한 상관관계가 얻어졌다. 이 결과는 향후 추가될 일반적인 수리상수와 검층수리 상수들의 비교연구로 모델방정식에 대한 검증이 이루어진다면, 희석모델에 근거한 전기전도도검층 기법이 수리 상수 결정을 위한 효과적인 방법이 될 수 있음을 보여 주었다.

• Bulletin of the Korean Chemical Society
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• 제15권7호
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• pp.581-584
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• 1994

A comparative investigation of the complexations of divalent metal ions (Cd, Cu, and Pb) by a well characterized soil humic acid (HA) from Okchun Metamorphic Belt was carried out in 0.05 M $KNO_3$ and pH of 4.5 using ion selective electrodes. A continuous distribution model based on the Scatchard Plot was used to determine the stability constants, because the constants obtained by this modeling technique takes the variations in binding energies into consideration without regards to the manner in which M(II) ion is bound on HA. The mean value of log $K_i$ were $4.05{\pm}0.60,\;4.92{\pm}0.36,\;and\;5.63{\pm}0.34\;{\ell}\;mol^{-1}$ for Cd(II)-, Pb(II), and Cu(II)-humate complexes respectively. The values of intrinsic constant (log $K_{int}$; binding at strongest site) were $7.12{\pm}0.30,\;6.59{\pm}0.32,\;and5.07{\pm}0.56\;{\ell}\; mol^{-1}$ in the order Cu(II) > Pb(II) > Cd(II) ion.

• 한국환경농학회지
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• 제15권4호
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• pp.442-447
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• 1996

화본과 잡초를 방제하기 위하여 사용되고 있는 quizalofop-ethyl의 토양흡착 양상을 구명하기 위하여 실험을 수행한 결과는 다음과 같다. 제초제 quizalofop-ethyl이 토양흡착 평형에 도달하는 시간은 24시간이었으며 흡착등은 곡선에서 plateau를 형성하지 않았을 뿐만 아니라 토양 유기물 함량이 많을수록 온도가 높을 수록 흡착량은 증가하였다. Freundlich plot의 상관계수(r)값은 연곡통 0.998, 남원통 0.995이며 흡착상수(K)는 연곡통 4.710, 남원통 10.414였다.

• 공업화학
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• 제32권5호
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• pp.581-588
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• 2021

In this study, soil slurry bioreactors were used to treat soils containing 16 polycyclic aromatic hydrocarbons (PAHs) for 35 days. Five different soil samples were taken from manufactured gas plant (MGP) and coal tar disposal sites. Soil properties, such as carbon content and particle distribution, were measured. These properties were significantly correlated with percent biodegradation and degradation rate. The cumulative amount of PAH degraded (P), degradation rate (K_m), and lag phase (𝜆) constants of PAHs in different MGP soils for 16 PAHs were successfully obtained from nonlinear regression analysis using the Gompertz equation, but only those of naphthalene, anthracene, acenaphthene, fluoranthene, chrysene, benzo[k]fluoranthene, benzo(a)pyrene, and benzo(g,h,i)perylene are presented in this study. A comparison between total non-carcinogenic and carcinogenic PAHs indicated higher maximum amounts of PAH degraded in the former than that in the latter owing to lower partition coefficients and higher water solubilities (S). The degradation rates of total non-carcinogenic compounds for all soils were more than four times higher than those of total carcinogenic compounds. Carcinogenic PAHs have the highest partitioning coefficients (K_oc), resulting in lower bioavailability as the molecular weight (MW) increases. Good linear relationships of K_m, 𝜆, and P with the octanol-water partitioning coefficient (K_ow), MW, and S were used to estimate PAH remaining, lag time, and biodegradation rate for other PAHs.

• 한국해양공학회지
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• 제16권6호
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• pp.44-48
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• 2002

In lateral ground flow, slope stability, and land slide problems, H-piles have often been used, on a horizontally deforming ground, to prevent the failure of mass of soil in a downward and outward movement of a slope. Here, theoretical equations are derived to estimate the lateral force, assuming that the Mohr-Coulomb's plastic states occur in the ground, just around H-piles. In this study, some model experiments were performed to check the lateral forces determined from theoretical equations, using several pile widths, heights and various interval ratios between H-piles for sand specimens. The solution of the theoretical equation, derived from previous studies, showed reasonable characteristics for constants of soil, as well as for the interval, widths, and heights of H-Pile.

• Journal of Microbiology and Biotechnology
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• 제14권5호
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• pp.901-905
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• 2004

The degradation and mineralization of crude oil were investigated over 50-days in three soils, loamy sand, sand, and combusted loamy, which were artificially contaminated with crude oil (50 g $kg^{-1}$) and inoculated with Nocardia sp. H17-1. The degradation efficiency of total petroleum hydrocarbon (TPH) in sand was the highest at 76% among the three soils. The TPH degradation rate constants $(k_{TPH})$ in loamy sand, sand, and combusted loamy sand were 0.027 $d^{-1}$, 0.063 $d^{-1}$, and 0.016 $d^{-1}$, respectively. In contrast, the total amount of $CO_2$ evolved was the highest at 146.1 mmol in loamy sand. The $CO_2$ evolution rate constants (k_{CO2})$ in loamy sand, sand, and combusted loamy sand were 0.057 $d^{-1}$, 0.066 $d^{-1}$, and 0.037 $d^{-1}$, respectively. Therefore, it seems that the degradation of crude oil in soils can be proportional to the soil pore space and that mineralization can be accelerated with the increase of organic substance.