• Title/Summary/Keyword: Soil chemicals

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A study on the removal of heavy metals from soils using electrokinetic soil processing and ion exchange membrane (전기장과 이온교환막을 이용한 토양에서의 중금속 제거에 대한 연구)

  • 김순오
    • Economic and Environmental Geology
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    • v.32 no.1
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    • pp.43-51
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    • 1999
  • In order to remediate hazardous waste site, a process of electrokinetically purging chemicals from saturated soil is examined by laboratory experiments. Electrokinetic soil remediation is one of the most promising soil decontamination processes that habe igh removal efficiency and time-effectiveness in low-permeability soils such as clay. Being combined with several mechanisms-electromigration, elec troosmosis, diffusion and electrolysis of water, electrokinetic soil processing can remove non-polar organics as well as ionic contaminants. The objectives of this study are; 1) the exploration of the feasibility of electrokinetic soil processing on the removal of heavy metals, 2) the investigation of applicability to the tailing-soils in aban doned mining area, 3) the examination of effects of soil pH and conductivity on the transport phenomena of elements in soils, and 4) the investigation of the applicability of the ionexchange membrance to the efficient collection of heavy metals removed from contaminated soils. With the result of this study, it is suggested that the removal efficiency is significantly influenced by applied voltage & current, type of purging solutions, soil pH, permeability and zeta potentials of soil. Although further study should be needed, it is possible to collect removed heavy metals with ion-exchange membrance in cathode compartment.

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An Analysis of the Ageing Effect on the Removal of Cesium and Cobalt from Radioactive Soil by the Electrokinetic Method

  • Kim Gye-Nam;Oh Won-Zin;Won Hui-Zun;Jung Chong-Hun
    • Nuclear Engineering and Technology
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    • v.36 no.4
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    • pp.304-315
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    • 2004
  • The ageing effects of radionuclides in radioactive soil on remediation using the electrokinetic method were analyzed. Comparative experiments were conducted for the reactive soil around a TRIGA research? reactor contaminated with $^{137}Cs\;and\;^{60}Co$ for 15 years and the non-reactive soil that was intentionally contaminated with $Cs^+\;and\;Co^{2+}$ for 3 days. It was observed that because of an aging effect on $^{137}Cs$, the efficiency of removing it decreased. $H_{2}SO_4$ used as an additive to increase the removal efficiency showed a higher removal capability than other chemicals for both $^{137}Cs\;and\;^{60}Co$. The efficiency of removing radionuclides from the radioactive soil in the column was proportional to the capability of the added chemical to extract radionuclides. It took 10 days to achieve a $54\%$ removal of $^{137}Cs$ and a $97\%$ removal of $^{60}Co$ from the soil. The volume of the soil wastewater discharged from the soil column by the electrokinetic method was $20\%$ below that for soil washing.

Evaluation of Streptomyces saraciticas as Soil Amendments for Controlling Soil-Borne Plant Pathogens

  • Wu, Pei-Hsuan;Tsay, Tung-Tsuan;Chen, Peichen
    • The Plant Pathology Journal
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    • v.37 no.6
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    • pp.596-606
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    • 2021
  • Soil-borne diseases are the major problems in mono cropping. A mixture (designated LTM-m) composed of agricultural wastes and a beneficial microorganism Streptomyces saraceticus SS31 was used as soil amendments to evaluate its efficacy for managing Rhizoctonia solani and root knot nematode (Meloidogyne incognita). In vitro antagonistic assays revealed that SS31 spore suspensions and culture broths effectively suppressed the growth of R. solani, reduced nematode egg hatching, and increased juvenile mortality. Assays using two Petri dishes revealed that LTM-m produced volatile compounds to inhibit the growth of R. solani and cause mortality to the root knot nematode eggs and juveniles. Pot and greenhouse tests showed that application of 0.08% LTM-m could achieve a great reduction of both diseases and significantly increase plant fresh weight. Greenhouse trials revealed that application of LTM-m could change soil properties, including soil pH value, electric conductivity, and soil organic matter. Our results indicate that application of LTM-m bio-organic amendments could effectively manage soil-borne pathogens.

Degradation of Diazinon and Dursban in Submerged Soil (담수양중(湛水壤中) Diazinon 과 Dursban 의 분해(分解)에 관(關)하여)

  • Choi, Jong-Woo;Lee, Kyu-Seung
    • Korean Journal of Environmental Agriculture
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    • v.6 no.2
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    • pp.1-11
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    • 1987
  • The degradation of two chemicals seem to be clearly affected by soil microbial activity in submerged soil $conditions(30{\pm}1^{\circ}C)$. The Active ingredient of Diazinon disappeared about 5 times faster than that of Dursban. By Applying 300% higher concentrations of both chemicals. under the above soil conditions, however, degradation was retarded by about one day. Some of the metabolites of Diazinon were as follows: 0.0-diethyl phosphorothioate and sulfotep as hydrolytic products, and diazoxon, 0.0-diethyl-0-[2-(1-hydroxy-1, 1-dimethyl)-6-methyl]-pyrimidinyl phosphorothioate and 2-isopropyl-6-methyl-pyrimidine-4-one as degradation products of monooxygenase. But 0. 0-diethyl phosphorothioate was the only methabolite of Dursban.

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Sorption Characteristics of Procymidone and 3,5-Dichloroaniline on Microplastic Films (미세플라스틱 필름의 프로시미돈과 3,5-다이클로로아닐린 흡착 특성)

  • Ji Won Yang;Youn-Jun Lee;Eun Hea Jho
    • Korean Journal of Environmental Agriculture
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    • v.42 no.3
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    • pp.184-192
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    • 2023
  • Microplastics are generated by the breakdown of plastic wastes in agricultural soil and residual pesticides in agricultural soil can adsorb on microplastics. In this study, the sorption characteristics of procymidone (PCM) and one of its metabolites, 3,5-dichloroaniline (DCA), on low-density polyethylene (LDPE) and polyvinyl chloride (PVC) microplastics were investigated. The sorption and desorption tests were carried out for 72 h using LDPE or PVC microplastic films to study the sorption isotherms of PCM and DCA and kinetics for sorption and desorption of PCM. The results show that the sorption data of PCM and DCA were better described by the Freundlich isotherm model (R2=0.7568-0.9915) than the Langmuir isotherm model (R2=0.0545-0.5889). The sorption potential of PVC for both PCM and DCA was greater than that of LDPE. The sorption data of PCM on PVC and LDPE were fitted better to the pseudo-second-order kinetic model than the pseudo-first-order kinetic model. The PCM sorption on LDPE was about three times faster than that on PVC. Both microplastic films released the sorbed PCM back to water, and more PCM was released from PVC than LDPE, but the desorption rate was faster with LDPE than PVC. Overall, the results show that different microplastics have different sorption characteristics for different chemicals. Also, the sorbed chemicals can be released back to environment suggesting the potential of contaminant spread by microplastics. Thus, the management practices of microplastics in agricultural soil need to consider their interaction with the chemical contaminants in soil.

On the Extension of Insecticidal Activity and the Preparation of New Mixture with Diazinon (농약의 약효증진을 위한 첨가제 효과에 관하여;Diazinon제를 중심으로)

  • Cho, Jeong-Rye;Lee, Kyu-Seung
    • Korean Journal of Environmental Agriculture
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    • v.15 no.1
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    • pp.105-115
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    • 1996
  • In this paper, we reviewed the degradation factors of diazinon which was known to be easily degraded by soil microorganisms and lost of its activity. Under submerged soil condition, the contribution of microorganisms to diazinon degradation was about 40% and these microorganisms preferred soil humus as substrates to diazinon itself. The effect of monooxygenase activity in submerged soil was more important than esterase activity on diazinon degradation and these enzymes were inhibited by several chemicals such as piperonyl butoxide(PBO), EPN and tricyclazole. From these results, new formulation type of diazinon (PBO and triphenyl phosphate were added to commercial diazinon formulation by 0.1% respectively.) and diazinon mixture formulation (diazinon was mixed with EPN, tricyclazole and carbofuran in equal amount) were prepared. The new formulation type of diazinon showed better insecticidal activity by 12% and more delayed diazinon degradation in ten days than commercial diazinon.

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The Trend and Achievements of Erosion Control Research in Japan (일본(日本)에 있어서의 사방공학연구(砂防工學硏究)의 동향(動向))

  • Woo, Bo-Myeong
    • Journal of Korean Society of Forest Science
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    • v.20 no.1
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    • pp.51-60
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    • 1973
  • The trend and achievments of soil erosion control research in Japan were investigated through observation tours and reference work and following facts were found to be important aspects which should be considered in the soil erosion control research program in Korea. Experiments on forest and water relations, and ground water phenomena at the water source zone in Tokyo University. Studies on land-slides and erosion control dam in Kyoto University. Studies on mud-flow and snow avalanches in Hokkaido University. Studies on sanddune fixation and disaster damage prevention forests in Kyushu University. Studies on forest denudations in Nagoya University. Studies on Greening-works and soil erosion prevention chemicals in Tokyo Agriculture University. Training on planning of erosion control works and prevention of disaster damages in Forest Research Institute. Experiments on soil erosion phenomena and infiltration in Tohoku Branch, FRI. Experiments on erosion and surface stratum failure of steep slopes and their prevention methods in Railway Technical Research Institute.

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The Effect of Liquid Fertilizer Contained Amio acids on Growth of Bentgrass(Agrostis palustris Huds) and the Chemical Characteristics of Soil (아미노산 액비가 벤트그라스잔디(Bentgrass)의 생장과 토양에 미치는 영향)

  • 김영선;이규승;함선규
    • Proceedings of the Turfgrass Society of Korea Conference
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    • 2004.01a
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    • pp.24-31
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    • 2004
  • This experiment was carried out to study an effect of liquid fertilizer contained amino acids(LFcAA) on the growth of Bentgrass(Agrostis palustris Huds. penncross) and the change of soil chemicals characteristics. In tested soil, the utilization rate of nitrogen in treatment was more than control. Fresh weight, dry weight and concentration of T-N, Mg and chlorophyll were increased in grass treated LFcAA. These results suggested that treatment of LFcAA was promoted utilization of nitrogen in soil and growth of bentgrass.

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Effects of Parent Rocks on Soil Microbial Diversity (모암이 토양미생물 다양성에 미치는 영향)

  • Suh, Jang-Sun;Kwon, Jang-Sik;Chon, Gil-Hyong
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.3
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    • pp.127-133
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    • 2003
  • The effect of parent rocks to the soil microbial diversity were investigated in soils developed from granite, limestone and basalt parent rocks. In the soils, microbial populations were positively related to the soil chemicals, such as soil pH with ftuorescent Pseudomonas, and soil EC with actinomycetes, fungi, mesophilic Bacillus and alkaliphilic bacteria. Gram negative bacteria, spore forming Bacillus, were maintained relatively same levels of population between granite, limestone and basalt soils. Among the species of Burkholderia, Pseudomonas and Ralstonia were dominated in the granite soils, Pseudomonas, Burkholderia and Phyllobacterium in the limestone soils, and Burkholderia in the basalt soils.

Microbial Amelioration of Acid Mine Drainage Impaired Soil using the Bacterial Consortia of Klebsiella sp. and Raoultella sp.

  • Park, Seon Yeong;Lee, Gi Won;Kim, Chang Gyun
    • Journal of Soil and Groundwater Environment
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    • v.26 no.1
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    • pp.34-44
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    • 2021
  • Acid mine drainage (AMD) resulting from pyrite oxidation in mining areas, subsequently leads to soil acidification accompanied by lowering pH and high concentration of metals and metalloids in its surrounding environment. Regarding to this, the microbial amelioration has been considered as a promising option for a more cost-effective and eco-friendlier countermeasure, compared to the use of alkaline chemicals. This study was aimed to evaluate influencing factors in microbially-mediated amelioration of acidic soil spiked by simulated AMD. For this, microcosm experiments were conducted by acid-neutralizing bacterial consortium (dominated by Klebsiella sp. and Raoultella sp.) under the various conditions of AMD spikes (0-2,500 mg SO42-/L), together with acidic mine soil (0-100 g) or sphagnum peat (0-5 g) in the 200 mL of nutrient medium. The employed bacterial consortium, capable of resisting to high level of sulfate concentration (up to 1,500 mg SO42-/L) in low pH, generated the ammonium while concomitantly reduced the sulfate, subsequently contributing to the effective soil stabilization with an evolution of soil pH up to neutral. Furthermore, it demonstrates that suitable condition has to be tuned for successful microbial metabolism to facilitate with neutralization during practical application.