• Journal of Soil and Groundwater Environment
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• v.23 no.6
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• pp.1-8
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• 2018

In this study, formaldehyde and benzene were selected as the arbitrary chemicals in accidental leakage to environment, and their physicochemical and biological characteristics and toxicity were studied. Also, the fate of these chemicals in soil and groundwater was studied based on the results of previous studies. They can be released into the atmosphere as gas or vapor phase, which then can be photochemically degraded. Since they have relatively high water solubility, they are likely to have high mobility in water and soil. Volatilization of these chemicals from soil is affected by the soil moisture content. Biodegradation of formaldehyde and benzene is one of the important pathways as well. Therefore, it is necessary to study the environmental impacts of leakage accidents of flammable chemicals such as formaldehyde and benzene. Further research on the fate of flammable chemicals in the environment is needed to take appropriate response actions to leakage accidents of flammable chemicals, and this will contribute to the development of practical guidelines to cope with leakage accidents.

• Journal of the Korean Society of Clothing and Textiles
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• v.36 no.11
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• pp.1237-1245
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• 2012

The effect of hydrophilicity and hydrophobicity of PET fabric on the detergency of particulate soil were investigated as functions of the concentration of hydrophilic and hydrophobic chemicals, surfactant concentration, ionic strength, adhesion and removal time, and pH. The detergency of the particulate soil was determined by the adhesion of particles to and their removal from fabric, the PET fabric and ${\alpha}-Fe_2O_3$ were used as textile materials and for the model of particulate soil, respectively. The hydrophilic and hydrophobic finish for PET fabric was treated with a polyester, silicone and fluorine organic compound of resin respectively. The adhesion of particulate soil to fabric treated with hydrophobic chemicals were slightly higher but its removal from fabric treated with hydrophobic chemicals was largely higher than fabric treated with a hydrophilic chemical regardless of solution conditions such as the concentration of hydrophilic and hydrophobic chemicals, surfactant concentration, ionic strength, adhesion and removal time, and pH. Therefore, hydrophobic treatment for fabric had a more positive effect than the hydrophilic treatment on the detergency of particulate soil.

• Journal of Soil and Groundwater Environment
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• v.24 no.1
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• pp.1-9
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• 2019

This study presents a technical perspective to the fate characteristics of phenol and m-cresol, which represent some of the most common organic chemicals found in chemical spill accidents, and likely to persist in soil and groundwater due to their highly stable physicochemical properties. Some cases of domestic and foreign chemical accidents linked to phenol and m-cresol contamination were compiled. Due to their low organic carbon-water partitioning coefficient (Koc), phenol and m-cresol tend to migrate into groundwater and remained as dissolved phase. On the other hands, phenol and m-cresol can be readily decomposed by microbes in soil and groundwater under appropriate conditions. Therefore, the fate characteristics of these chemicals are highly contingent on environmental conditions. Thus, if a great quantity of leakage is occurred by chemical accidents, the up-to-date and correct information about fate characteristics taking into account both the chemical and environmental conditions is greatly needed to minimized the potential hazards from these chemicals.

• Korean journal of applied entomology
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• v.25 no.1 s.66
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• pp.47-51
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• 1986

A study was undertaken to investigate the distribution of Streptomyces spp. in soil in Korea. Among the different types of soil surveyed, the highest population of Streptomyces spp. recording $5.6{\times}10^5\;CFU/g$ was observed in upland soil. With reference to the soil depth, most of their population was distributed from soil surface to 5cm depth and the highest value was found in $0{\sim}2cm$ soil depth. Comparing the population of Streptomyces spp. with different soil color (by Munsell soil color chart), the highest value of $9.2{\times}10^\;CFU/g$ was showed in Oliver yellow soil (2.5Y, 6/4). On the basis of the acidity of soil samples subjected to Streptomyces spp. isolation, it is considered that the optimum pH range for Streptomyces spp. in soil lies between 6.0 to 7.5, showing the highest value of $1.05{\times}10^6CFU/g$ at pH 7.5. Among the colors of isolated colonies, gray and white colonies occupied 60% and 26% of the total isolates respectively.

• Journal of Environmental Health Sciences
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• v.22 no.3
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• pp.116-122
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• 1996

This study has been focused on the applicability of microwave treatment of soil contaminated by volitile organic chemicals. Substrates studied were sand and sandy soil. These substrates were impregnated with toluene, tetrachloroethylene, o-xylene and p-dichlorobenzene. The microwave treatment was conducted in a modified domestic microwave oven: 2450 MHz, 700 W. The sandy soil temperature added water went up rapidly to about 130$\circ$C for 4 minutes. And then, the temperature appeared to plateau out. A series of tests were performed to depict the effectiveness of microwave treatment technique to organic contaminants from soils. Removal efficiencies in sandy soil and sand were increased with increasing water content and exposure time. Microwave radiation penetrates the soil and heats water throughout the matrix. Therefore, addition of a certain amount of water to the contaminated soil can efficiently enhance the ability of the soil to absorb microwave energy and promote the evaporation of the volitile contaminants. And the vapour pressure of impregnated organic contaminants becomes lower. the removal efficiency becomes poor.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.36 no.4 s.107
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• pp.41-48
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• 2004

To make a basepaper for multipurposed seed paper, old news print (ONP) and mixed office waste paper (MOW), modified and unmodified with a commercial cellulase, were investigated. Each handsheet was applied with different chemicals such as insecticides, germicides and herbicides. The interactions behaviors of chemicals used with base papers were evaluated by means of the contents of chemicals impregnation and dissolving behaviors in water and soil. The ONP and MOW treated with the cellulase had higher impregnation and dissolving capacities in both water and soil than untreated ONP and MOW. However, the modified ONP showed lower impregnation and dissolving capacities compared to the modified MOW. The content of impregnation of chemicals would be affected with the degree of microfibrils produced by the modification treatment. Otherwise, dissolving capacities of chemicals depend on the affinity of the residual lignin in the paper.

• Journal of Applied Biological Chemistry
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• v.61 no.4
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• pp.335-340
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• 2018

Hemoglobin (Hb) is a member of heme-protein that can perform catalytic non-specific chain reaction in the presence of hydrogen peroxide ($H_2O_2$). Catalytic ability of Hb to degrade pyrene was demonstrated using soil contaminated with $^{14}C$ pyrene and 10 mg pyrene /kg soil. The composition of soil was similar to previously used soil except that it had lower organic carbon content. Bench scale laboratory tests were conducted in the presence of buffer only, $H_2O_2$ only, or Hb with $H_2O_2$ for 24 h. After 24 h reaction, 0.1 and 1.3% of $^{14}C$ pyrene in contaminated soil were mineralized with $H_2O_2$ only or Hb plus $H_2O_2$. No mineralization to $^{14}CO_2$ was detected with buffer only. Approximately 12.2% of pyrene was degraded in the presence of $H_2O_2$ only while 44.0% of pyrene was degraded in the presence of Hb plus $H_2O_2$ during 24 h of catalytic reaction. When degradation intermediate products were examined, two chemicals were observed in the presence of $H_2O_2$ only while 25 chemicals were found in the presence of Hb plus $H_2O_2$. While most degradation products were simple hydrocarbons, four of the 27 chemicals had aromatic rings. However, none of these four chemicals was structurally related to pyrene. These results suggest that Hb catalytic system could be used to treat pyrene-contaminated soil as an efficient and speedy remediation technology. In addition, intermediate products generated by this system are not greatly affected by composition change in soil organic matter content.

• Korean Journal Plant Pathology
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• v.10 no.4
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• pp.325-332
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• 1994

In order to find out formulation and effect of soil amendment on Fusarium wilt of sesame caused by Fusarium oxysporum f. sp. vasinfectum, the study was conducted during the last two years of 1992 to 1993. Among 14 chemicals (1%, w/w) added to soil including CaO individually, Al2(SO4)3, Alum, and CaO suppressed mycelial growth and conidial germination of F.oxysporum f. sp. vasinfectum. CaCl2 suppressed mycelial growth only, while glycerine, KCl, K2 HPO4, and triple superphosphate suppressed conidial germination. Suppression rate was ranged from 21 to 100% on mycelial growth. The 8 chemicals were finally selected. Among the 4 organic compounds, composted pine bark showed definite suppression on mycelial growth and conidial germination of the fungus, whereas milled alfalfa leaves was only effective on conidial germination of Fusarium wilt pathogen. The antagonist Trichoderma harzianum grew well in the soil medium amended with the composted pine bark and chemicals mixture (CPM) amendment (1%, w/w) and suppressed mycelial growth of the fungus effectively. In pot test, Fusarium wilt of sesame was completely controlled by CPM amendment.

• Journal of Applied Biological Chemistry
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• v.44 no.4
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• pp.194-198
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• 2001

Contaminated sites are often abandoned for an extended period of time, thus organopollutants becoming sequestered. The information on the initial concentrations of the contaminants would be helpful for the economic bioremediation of the chemicals. The present study estimated the initial concentrations of atrazine and phenanthrene through multiple regression analyses using soil properties and the amount of chemicals available in situ. Percentage mineralized or extracted was best correlated with organic C or logarithm of organic C, and the $R^2$ values were 0.548 and 0.894 for atrazine and phenanthrene, respectively. Estimation of the initial concentration of the chemicals was then calculated from both the percentage mineralized or extracted and the amount of chemicals extracted or mineralized. Results showed that the estimation of the initial concentration of the chemical at the time of contamination is feasible.

• Korean Journal of Environmental Agriculture
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• v.1 no.1
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• pp.65-70
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• 1982

This experiment was conducted to see the effect of repeated application of IBP granular formulation(17%, 0,0-diisopropyl-S-benzyl thiophosphate) on the biodegradation of IBP and diazinon〔0,0-diethyl 0-(2-isopropyl-4-methyl-5-pyrimidinyl) phosphorothioate〕 in silt loam soil with 2.1% organic matter under flooded condition. The persistence of IBP in the soil was shortened by increasing the frequencies of application of the chemical. Enhanced degradation ability in the soil caused by repeated application of IBP was prolonged about 53 days, while the ability did not influence diazinon persistence in the soil. The half-lives of IBP in sterilized soil autoclaved at $121^{\circ}C$ for 30 minutes were about 3 times longer than those in viable soil, suggesting that microbial process was a major factor for IBP degradation in the soil. The total colony number of soil microbes showed little difference between the soils with and without repeated application of IBP. A possible concern of specific soil microorganisms on the pesticide degradation in soil was discussed.