• Journal of Soil and Groundwater Environment
• /
• v.16 no.6
• /
• pp.79-94
• /
• 2011

Black carbon (BC), a kind of high surface area carbonaceous material (HSACM), was isolated from Andong lake sediment. Sorption and desorption kinetics of naphthalene (Naph) and phenanthrene (Phen) in organic carbon (OC) and BC in the Andong lake sediment were investigated. Several kinetic models such as one-site mass transfer model (OSMTM), two-compartment first-order kinetic model (TCFOKM), and a newly proposed modified two-compartment first-order kinetic model (MTCFOKM) were used to describe the sorption and desorption kinetics. The MTCFOKM was the best fitting model. The MTCFOKM for sorption kinetics showed that i) the sorbed amounts of PAHs onto BC were higher than those onto OC, consistent with BET surface area; ii) the equilibration time for sorption onto BC was longer than those onto OC due to smaller size of micropore ($11.67{\AA}$) of BC than OC ($38.18{\AA}$); iii) initial sorption velocity of BC was higher than OC; and iv) the slow sorption velocity in BC caused the later equilibrium time than OC even though the fast sorption velocity was early completed in both BC and OC. The MTCFOKM also described the desorption of PAHs from the OC and BC well. After desorption, the remaining fractions of PAHs in BC were higher than those in OC due to stronger PAHs-BC binding. The remaining fractions increased with aging for both BC and OC.

• Journal of Climate Change Research
• /
• v.4 no.2
• /
• pp.77-93
• /
• 2013

Global warming accelerates both carbon (C) input through increased forest productivity and heterotrophic C emission in forest soils, and a future trend in soil C dynamics is uncertain. In this study, the Korean forest soil carbon model (KFSC model) was applied to 1,467,458 ha of Pinus densiflora forests in Korea to predict future C dynamics under RCP 8.5 climate change scenario (RCP scenario). Korea was divided into 16 administrative regions, and P. densiflora forests in each region were classified into six classes by their stand ages : 1 to 10 (I), 11 to 20 (II), 21 to 30 (III), 31 to 40 (IV), 41 to 50 (V), and 51 to 80-year-old (VI+). The forest of each stand age class in a region was treated as a simulation unit, then future net primary production (NPP), soil respiration (SR) and forest soil C stock of each simulation unit were predicted from the 2012 to 2100 under RCP scenario and constant temperature scenario (CT scenario). As a result, NPP decreased in the initial stage of simulation then increased while SR increased in the initial stage of simulation then decreased in both scenarios. The mean NPP and SR under RCP scenario was 20.2% and 20.0% higher than that under CT scenario, respectively. When the initial age class was I, IV, V or VI+, predicted soil C stock under CT scenario was higher than that under RCP scenario, however, the countertrend was observed when the initial age class was II or III. Also, forests having a lower site index showed a lower soil C stock. It suggested that the impact of temperature on NPP was higher when the forests grow faster. Soil C stock under RCP scenario decreased at the end of simulation, and it might be derived from exponentially increased SR under the higher temperature condition. Thus, the difference in soil C stock under two scenarios will be much larger in the further future.

• Journal of Soil and Groundwater Environment
• /
• v.27 no.6
• /
• pp.11-21
• /
• 2022

Sorption of phenanthrene (PHE) and pyrene (PYR) in several sorbents, i.e., natural soil, BionSoil^®, Pahokee peat, vermicompost and Devonian Ohio Shale and a surfactant (hexadecyltrimethyl ammonium chloride)-modified montmorillonite (HDTMA-M) were investigated. Pyrene exhibited higher sorption tendency than phenanthrene, as predicted by its higher octanol to water partition coefficient (K_ow). Several sorption models: linear, Freundlich, solubility-normalized Freundlich model, and Polanyi-Manes model (PMM) were used to analyze sorption isotherms. Linear isotherms were observed for natural soil, BionSoil^®, Pahokee peat, vermicompost, while nonlinear Freundlich isotherms fitted for Ohio shale and HDTMA-M. The relationship between sorption model parameters, organic carbon content (f_oc), and elemental C/N ratio was studied. In the binary competitive sorption of phenanthrene and pyrene in natural soil, competition between the solutes caused reduction in the sorption of each solute compared with that in the single-solute system. The ideal adsorbed solution theory (IAST) coupled with the single-solute Freundlich model was not successful in describing the binary competitive sorption equilibria. This was due to the inherent nature of linear sorption of phenanthrene and pyrene in natural soil. The result indicates that the applicability of IAST for the prediction of binary competitive sorption is limited when the sorption isotherms are inherently linear.

• Journal of the Korean Society of Environmental Restoration Technology
• /
• v.12 no.2
• /
• pp.95-105
• /
• 2009

Land Use Changes (LUCs) have effects on greenhouse gas emissions and carbon stocks in soil and vegetation. Therefore, predictions for LUC are very important for achieving quantitative targets of $CO_2$ reduction rates. Some research exists on carbon fluxes and carbon cycles to estimate carbon stocks in terrestrial ecosystems in Korea. However, these researches have limitations in terms of helping us understand future potential reductions of $CO_2$ that reflect the influence of LUC. The aim of this study is to analyze the reduction levels of $CO_2$ emissions while considering LUC scenarios that effect carbon fluxes for LCS basic study in the year 2030. In this study, a common approach to model the effects of LUC on carbon stocks is the use of CA-Markov technical process with LUC patterns in the past. Potential reduction of $CO_2$ is calculated by change of land use that contains different soil organic carbon, each land use type, and biomass in vegetation. An IPCC analytical method of natural carbon sink and coefficient results from previous study in Korea is used as a calculation method for potential reduction of $CO_2$. As a result, 12,419 KtC will be reduced annually, which is 8.3% percent of 2005 $CO_2$ emissions in Korea. This will result in 3,226 hundred million won of economic efficiency. In conclusion, conservation of natural carbon sinks is necessary even if the amount of potential reduction change is little.

• Journal of the Korean Society of Environmental Restoration Technology
• /
• v.26 no.5
• /
• pp.33-46
• /
• 2023

In this study, carbon storage in the aboveground biomass, litter layer, and soil layer was calculated for abandoned mining restoration areas to determine the level of carbon storage after the restoration project through comparison with the ecological reference. Five survey sites were selected for each abandoned mining restoration area in Boryeong-si, Chungcheongnam-do, and the ecological reference that can be a goal and model for the restoration project. The carbon storage in the restoration area was 0~21.3Mg C ha^-1, the deciduous layer 3.3~6.0Mg C ha^-1, and the soil layer(0-30cm) 8.3~35.1Mg C ha^-1, showing a significant difference in carbon storage by target site. The total carbon storage was between 6.1 and 35.3% of the ecological reference, with restoration area ranging from 14.0 to 62.4 Mg C ha^-1. The total carbon storage in the restoration area and the ecological reference differed the most in the aboveground biomass and was less than 12%. Based on these results, forest restoration area need to improve the carbon storage of forests through continuous management and monitoring so trees can grow and restore productivity in the early stages of the restoration project. The results of this study can be used as primary data for preparing future forest restoration indicators by identifying the storage of abandoned mining restoration areas.

• Journal of Ecology and Environment
• /
• v.43 no.1
• /
• pp.43-60
• /
• 2019

Background: Tropical montane forests played an important role in the provision of ecosystem services. The intense degradation and deforestation for the need of agricultural land expansion result in a significant decline of forest cover. However, the expansion of agricultural land did not completely destruct natural forests. There remain forests inaccessible for agricultural and grazing purpose. Studies on these forests remained scant, motivating to investigate biomass and soil carbon stocks. Data of biomass and soils were collected in 80 quadrats ($400m^2$) systematically in 5 forests. Biomass and disturbance gradients were determined using allometric equation and disturbance index, respectively. The regression modeling is employed to explore the spatial distribution of carbon stock along disturbance and environmental gradients. Correlation analysis is also employed to identify the relation between site factors and carbon stocks. Results: The result revealed that a total of 1655 individuals with a diameter of ${\geq}5cm$, representing 38 species, were measured in 5 forests. The mean aboveground biomass carbon stocks (AGB CS) and soil organic carbon (SOC) stocks at 5 forests were $191.6{\pm}19.7$ and $149.32{\pm}6.8Mg\;C\;ha^{-1}$, respectively. The AGB CS exhibited significant (P < 0.05) positive correlation with SOC and total nitrogen (TN) stocks, reflecting that biomass seems to be a general predictor of SOCs. AGB CS between highly and least-disturbed forests was significantly different (P < 0.05). This disturbance level equates to a decrease in AGB CS of 36.8% in the highly disturbed compared with the least-disturbed forest. In all forests, dominant species sequestrated more than 58% of carbon. The AGB CS in response to elevation and disturbance index and SOC stocks in response to soil pH attained unimodal pattern. The stand structures, such as canopy cover and basal area, had significant positive relation with AGB CS. Conclusions: Study results confirmed that carbon stocks of studied forests were comparable to carbon stocks of protected forests. The biotic, edaphic, topographic, and disturbance factors played a significant variation in carbon stocks of forests. Further study should be conducted to quantify carbon stocks of herbaceous, litter, and soil microbes to account the role of the whole forest ecosystem.

• Korean Journal of Environmental Biology
• /
• v.34 no.2
• /
• pp.73-78
• /
• 2016

Bhutanese forests have been well preserved and can sequester the atmospheric carbon (C). In spite of its importance, understanding Bhutanese forest C dynamics was very limited due to the lack of available data. However, forest C model can simulate forest C dynamics with comparatively limited data and references. In this study, we aimed to simulate Bhutanese forest C dynamics at 6 plots with the Forest Biomass and Dead organic matter Carbon (FBDC) model, which can simulate forest C cycles with small amount of input data. The total forest C stock ($Mg\;C\;ha^{-1}$) ranged from 118.35 to 200.04 with an average of 168.41. The C stocks ($Mg\;C\;ha^{-1}$) in biomass, litter, dead wood, and mineral soil were 3.40-88.13, 4.24-24.95, 1.99-20.31, 91.45-97.90, respectively. On average, the biomass, litter, dead wood, and mineral soil accounted for 36.0, 5.5, 2.5, and 56.0% of the total C stocks, respectively. Although our modeling approach was applied at a small pilot scale, it exhibited a potential to report Bhutanese forest C inventory with reliable methodology. In order to report the national forest C inventory, field work for major tree species and forest types in Bhutan are required.

• Atmosphere
• /
• v.28 no.4
• /
• pp.393-402
• /
• 2018

This study investigated future changes in the Arctic permafrost features and related biogeochemical alterations under global warming. The Community Land Model (CLM) with biogeochemistry (BGC) was run for the period 2005 to 2099 with projected future climate based on the Special Report on Emissions Scenarios (SRES) A2 scenario. Under global warming, over the Arctic land except for the permafrost region, the rise in soil temperature led to an increase in soil liquid and decrease in soil ice. Also, the Arctic ground obtained carbon dioxide from the atmosphere due to the increase in photosynthesis of vegetation. On the other hand, over the permafrost region, the microbial respiration was increased due to thawing permafrost, resulting in increased carbon dioxide emissions. Methane emissions associated with total water storage have increased over most of Arctic land, especially in the permafrost region. Methane releases were predicted to be greatly increased especially near the rivers and lakes associated with an increased chance of flooding. In conclusion, at the end of $21^{st}$ century, except for permafrost region, the Arctic ground is projected to be the sink of carbon dioxide, and only permafrost region the source of carbon dioxide. This study suggests that thawing permafrost can further to accelerate global warming significantly.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.10 no.2
• /
• pp.69-77
• /
• 1986

A study was made of the effect of zeolite in detergent on the removal of soils correlating the characteristics of soil components. The detergency of natural soil was increased with increasing zeolite concentration but the effect on detergency was inferior to STPP. In case of carbon black based artificial soils. The detergency of soil containning non-polar oily soil was not improved by zeolite but the detergancy was increased with increasing zeolite concentration when polar oily soils were added to the soil. In case of iron black based artificial soils. Though the detergency was better than that of carbon black based soils, the detergency was not improved by zeolite regardless of oily soil components. The effect of zeolite on removal of oily soil was studied with tripalmitin and palmitic acid as model soils. The effect of zeolite and STPP on the removal of tripalmitin, the detergency was increased with in creasing STPP concentration but not zeolite.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2004.04a
• /
• pp.277-284
• /
• 2004

Batch experiments were conducted to investigate the sorption and desorption behaviors of PAHs (naphthalene, phenanthrene and pyrene) in soils. Three different soils montmorillonite KSF (foc =0.14%), masato (foc =0.08%), and diatomite (foc =0.007%) were investigated. The results of sorption-desorption experiment indicate that the sorption affinity of PAHs was in the order of montmorillonite > masato > diatomite. The Freundlich model was well fitted to the sorption and desorption data. Sorption affinity increased as loc increased. Desorption of PAHs from soils was biphasic composed of reversible and irreversible compartments. Desorption-resistance of phenanthrene in soils was also determined. The biphasic desorption model was used to explain desorption-resistance of phenanthrene in soils. The linear term represents reversible sorption fraction and Langmuinian-type term represents desorption-resistant fraction.