• 한국환경과학회지
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• 제23권6호
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• pp.1131-1142
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• 2014

In this study, the variations of the carbon dioxide fluxes were investigated with soil temperatures in the grassplot and seasonal variations of carbon dioxide concentrations and fluxes were analysed. Soil temperatures, carbon dioxide concentrations and fluxes were measured on the grassplot in Pukyong National University. Field measurements were carried out 25 times from March in 2010 to March in 2011 with nine points on the grassplot. Seasonal variations of carbon dioxide concentrations and fluxes showed an inverse relation. In summer, carbon dioxide concentrations are lower and carbon dioxide fluxes are higher. In winter, carbon dioxide concentrations are higher and carbon dioxide fluxes are lower. On the grassplot, carbon dioxide emission rate increase when the soil temperature is more than $20^{\circ}C$ and the emission rate decrease when the soil temperatures are less than $10^{\circ}C$. When the accumulated rainfall for five days before measurement day is 20~100 mm, it is showed that the more rainfall, the more carbon dioxide emissions. Carbon dioxide emission rate from the grassplot to the upper atmosphere was increased or decreased by the factors such as soil temperature, growth and wither of grass and rainfall. The results of this study showed that the emission of carbon dioxide in the grassplot is dominantly controlled by seasonal factors (especially soil temperature and rainfall).

• 한국토양비료학회지
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• 제47권6호
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• pp.486-490
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• 2014

This study was conducted to investigate the effect of carbonized biomass from crop residues on soil carbon storage during soybean cultivation. The carbonized biomass was made by field scale mobile pyrolyzer. The treatments consisted of control without input and three levels of carbonized biomass inputs as $59.5kg10a^{-1}$, C-1 ; $119kg10a^{-1}$, C-2 ; $238kg10a^{-1}$, C-3. Soil samples were collected during the 113 days of experimental periods, and analyzed soil pH and moisture contents. Soil carbon contents and soybean yield were measured at harvesting period. For the experimental results, soil pH ranged from 6.8 to 7.5, and then increased with increasing carbonized material input. Soil moisture contents were slightly higher by 0.1~1.5% than the control, but consistent pattern was not observed among the treatments. Soil carbon and organic carbon contents in the treatments increased at 24 and 15% relative to the control at 15 days after sowing, respectively. Loss rate of SOC (soil organic carbon) relative to its initial content was 7.2% in control followed by C-1, 6.8%> C-2, 3.5%>C-3, 1.1% during the experimental periods. The SOC change rate decreased with increasing carbonized biomass rate. It was appeared that soybean yields were $476.9kg10a^{-1}$ in the control, and ranged from 453.6 to $527.3kg10a^{-1}$ in the treatments. However, significant difference was not found among the treatments. It might be considered that the experimental results will be applied to soil carbon sequestration for future study.

• 한국작물학회:학술대회논문집
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• 한국작물학회 2017년도 9th Asian Crop Science Association conference
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• pp.340-340
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• 2017

Rice straw is very important to maintain fertility in agricultural soil with several aspects such as carbon and nitrogen cycles in Korea. Recently, concerning about climate change, carbon sequestration in agricultural land has become one of the most interesting and debating issues. Rice straw is most representative source of organic material produced in agricultural sectors. In order to evaluate changes of soil carbon treated by rice straw during cultivating rice in paddy field, we carried out to treat rice straw with 0, 0.5, 1, 1.5, and $2.0ton\;ha^{-1}$ at $50{\times}50{\times}20cm$ blocks made of wood board, and analyze contents of fulvic acid and humic acid form, and total carbon periodically. The experiment was conducted in 2013-2016, and sampled with interval in a month. The organic material was applied to treatment blocks in 2 weeks ago in rice transplanting of each year. Total carbon in beginning time is low as $7.9g\;kg^{-1}$. The contents of total carbon with treatments of rice straw after experiment are recorded as 8.7, 11.2, 9.5, 10.5, and $10.9g\;kg^{-1}$ applied by 0, 0.5, 1, 1.5, and $2.0ton\;ha^{-1}$, respectively. When trend lines were calculated on changes of soil carbon in periods of experiments, The trend equations of soil carbon changes with treatments of 0, 0.5, 1, 1.5, and $2.0ton\;ha^{-1}$ were Y=0.0015X+8.479, Y=0.073X+8.2577, Y=0.0503X+8.4477, Y=0.0822X+8.2103, and Y=0.082X+8.5736. These trends suggested several results. When rice straw was applied in cultivating paddy fields, most carbon in rice straw would be decomposed regardless the amount of rice straw in soil. We calculated sequestration rate of applied rice straw as about 0.1% per year during rice cultivation in paddy fields. It means that if farmer want to increase 1% soil organic matter by using application of rice straw returned after cultivation, famer should apply rice straw continuously for ten years. The change of soil carbon as fulvic acid, humic acid, and humane is showed that only content of carbon as mumine is increased significantly while fulvic acid and humic acid were changed in range of 10 to 30% among total carbon in soil. In conclusion, to sequestrate soil carbon with rice straw, it is important for rice straw to apply continuously every year. The amount of rice straw applied is not much effected to increase soil organic matter.

• 한국지반환경공학회 논문집
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• 제22권3호
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• pp.37-43
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• 2021

본 연구는 토지피복의 변화에 따른 토양 탄소의 변화량을 산정하고자 하였다. 다양한 토양탄소 모형가운데 InVEST Carbon Storage and Sequestration 모듈을 사용하였다. 토지피복은 토양 탄소에 영향을 주는 대표적인 인자 중 하나이다. 따라서 본 연구에서는 대한민국 전역을 대상으로 2000년과 2010년의 토지피복 변화에 따른 토양 탄소의 총량을 비교하였으며, 각 행정구역별(시도)의 변화량을 산정하였다. 대한민국의 토지피복 변화는 주로 시가 및 건조지역의 증가와 초지의 감소 등으로 나타났으며, 이로 인한 토양 탄소의 변화를 나타냈다. 대한민국의 총 토양 탄소 변화량은 10년 사이 11.48(million t) 감소한 것으로 나타났다. 행정구역별 토양탄소량은 대부분의 시도에서 감소를 나타냈으나, 예외적으로 제주도는 토양탄소량이 증가한 것으로 나타났다. 제주도를 제외한 시도 중 감소량이 제일 적은 시도는 서울로 나타났으며, 감소량은 0.033(million t)으로 나타났다. 반대로 가장 많은 감소량을 보인 시도는 경북으로 총 2.893(million t)이 감소하였다. 제주도는 유일한 총 토양 탄소 증가 지역으로 0.547(million t)이 증가하였으며, 10년 사이 농업지역이 2.1배 증가함을 보였다. 토양탄소의 경우 전국단위의 실측 자료 구축이 부족함을 보이며, 추후 다중 모형을 이용하여 연계분석을 통해 검증을 진행해야 할 것이다.

• 한국지반환경공학회 논문집
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• 제20권12호
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• pp.33-39
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• 2019

The upsurge of population, internal migration, economic activities and developmental works has brought significant land use and land cover (LULC) change over the period of 1990 and 2010 in the Bagmati basin of Nepal. Along with alteration on various other ecosystem services like water yield, water quality, soil loss etc. carbon sequestration is also altered. This study thus primary deals with evaluation of LULC change and its impact on the soil carbon storage for the period 1990 to 2010. For the evaluation, InVEST (Integrated Valuation of Ecosystem Services and Tradeoffs) Carbon model is used. Residential and several other infrastructural development activities were prevalent on the study period and as a result in 2010 major soil carbon reserve like forest area is decreased by 7.17% of its original coverage in 1990. This decrement has brought about a subsequent decrement of 1.39 million tons of carbon in the basin. Conversion from barren land, water bodies and built up areas to higher carbon reserve like forest and agriculture land has slightly increased soil carbon storage but still, net reduction is higher. Thus, the spatial output of the model in the form of maps is expected to help in decision making for future land use planning and for restoration policies.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1998년도 공동 심포지엄 및 추계학술발표회
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• pp.57-59
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• 1998

The headspace method has been acknowledged as a cost-effective and convenient method to analyze volatile organic compounds(VOCs) in soil. The headspace analysis is based on equilibrium partitioning of VOCs among water, air and soil in a closed system. However, the headspace method cannot be applied to soils where most of the VOCs remain sorbed even at high temperature. In this study, it was investigated how the sorption characteristics of VOCs varied with soil with different organic carbon contents and temperature. This study showed that all the VOCs were volatilized, not sorved, only in the soil with 5% organic carbon at 45$^{\circ}C$ or higher. Some fraction of VOCs remained in soil with 8% organic carbon at $65^{\circ}C$ of higher. Most of the VOCs remained sorbed in soil with 12% organic content even at 95$^{\circ}C$. This result suggested that the headspace method can be applied only to soils with little organic carbon content (less than 5%). In this case, 45$^{\circ}C$ seems to be high enough to volatilize all the VOCs from soil. Large particles still showed a significant sorption capacity for VOCs from soil. Large Particles still showed a significant sorption capacity for VOCs despite of their low level of organic carbon content. It was also shown that the organic carbon sorption coefficients (Koc) of VOCs varied with soils with different organic carbon content. This suggests that not only the organic matter content of soil but also the property of the organic matter in soil influence the sorption of VOCs to soil.

• 한국염색가공학회지
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• 제8권1호
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• pp.83-89
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• 1996

Carbon black has been used as a particulate soil to prepare artificial soiled fabrics for detergent study but it has two major defects. The one is the difficulty of quantitative analysis of carbon black for evaluate the detergency, the other is that there is no reliable correlation between the removal of carbon black and oily soil which is the major component of natural soil. In this study ferric oxinate was used as a particulate soil since it is in black color and can be soiled on fabric by suspension in water or by solution in chloroform and it is easily analysed quantitatively by extracting it from soiled fabric with chloroform to get correct value of soil removal. The characteristics of soil removal of ferric oxinate were compared with that of carbon black and Sudan black, an oil soluble dye, which had been proved that it's detergency correlated with that of oily soil The soil removal of ferric oxinate and Sudan black estimated from quantitative analysis and from K/S value were in good agreement whereas the result calculated by simple reflectance was consistently low. The soil removal of ferric oxinate was exceeded from that of carbon black without regard to surfactants, Triton and Las, but the effect of washing conditions such as temperature and washing time on soil removal of both soils with different suffactants showed no considerable difference. Though the soil removal of Sudan black was little effected by the conditions, the soil removal in Triton exceeded considerably that of in Las, which is the characteristic of oily soil. Thus the soil removal of Sudan black was in good agreement with ferric oxinate in Triton, a non-ionic surfactant, and with carbon black in Las, an artionic surfactant. We concluded that ferric oxinate is a more realistic model particulate soil for artificial soiled cotton fabric washed with non-ionic surfactant than carbon black.

• 한국토양비료학회지
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• 제40권1호
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• pp.36-42
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• 2007

지구온난화, 기후변화 및 온실가스 배출 및 저감기술에 관한 많은 연구가 수행되고 있으나, 토양 내 유기탄소의 축적을 통한 온실가스 배출억제에 대한 연구는 매우 미진하며, 특별히 우리나라 농경지의 주요 이용형태인 논토양에 대해서는 유기탄소의 축적량 산정을 포함한 변동 등에 대한 연구가 매우 미흡하다. 본 연구에서는 도서를 제외한 우리나라 전국적인 논 토양 유기탄소의 연차별 모니터링을 통하여 토양에서 유기탄소의 연차간 변동을 평가하였으며 토양의 생성학적, 물리적 특성에 따라 토양유기탄소의 변화에 대한 해석을 시도하였다. 연구결과, 토양 생성분류학적으로 우리나라의 주된 논토양인 Inceptisol 에서 토양유기탄소량이 1999년에 비하여 2003년에 증가하는 경향이었던 것으로 나타났으며, 논의 이용형태별로는 염해답이나 미숙답에서 보다 보통답, 사질답, 배수불량답에서 토양유기탄소가 증가하는 것으로 나타났다. 표토의 토성별로 양토에서 보다 미사 식양토 및 미사양토에서 유기탄소의 증가가 높게 나타났다. 지형적으로는 곡간지에서 보다 평탄지에서 토양유기탄소의 증가율이 높게 나타났다. 결론적으로, 본 연구의 결과를 통하여, 1999년 이후 논토양에서 토양유기탄소의 양이 증가하는 경향을 나타내고 있으며 ($+0.11g\;kg^{-1}yr^{-1}$) 이는 대기중의 이산화탄소를, 논 토양의 유기탄소 축적기능을 통해, 토양 중에 저장함으로써 논토양이 온실가스 흡수원으로서의 역할을 하는 것으로 해석할 수 있다.

• 농업과학연구
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• 제43권3호
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• pp.353-359
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• 2016

Soil organic carbon (SOC) retention has gradually gotten attention due to the need for mitigation of increased atmospheric carbon dioxide and the simultaneous increase in crop productivity. We estimated the statistical maximum value of soil organic carbon (SOC) fixed by clay content using the Korean detailed soil map database. Clay content is a major factor determining SOC of subsoil because it influences the vertical mobility and adsorption capacity of dissolved organic matter. We selected 1,912 soil data of B and C horizons from 13 soil series, Sangju, Jigog, Jungdong, Bonryang, Anryong, Banho, Baegsan, Daegog, Yeongog, Bugog, Weongog, Gopyeong, and Bancheon, mainly distributed in Korean upland. The ranges of SOC and clay content were $0-40g\;kg^{-1}$ and 0 - 60%, respectively. Soils having more than 25% clay content had much lower SOC in subsoil than topsoil, probably due to low vertical mobility of dissolved organic carbon. The statistical analysis of SOC storage potential of upland subsoil, performed using 90%, 95%, and 99% maximum values in cumulative SOC frequency distribution in a range of clay content, revealed that these results could be applicable to soils with 1% - 25% of clay content. The 90% SOC maximum values, closest to the inflection point, at 5%, 10%, 15%, and 25% of clay contents were $7g\;kg^{-1}$, $10g\;kg^{-1}$, $12g\;kg^{-1}$, and $13g\;kg^{-1}$, respectively. We expect that the statistical analysis of SOC maximum values for different clay contents could contribute to quantifying the soil carbon sink capacity of Korean upland soils.

• 한국토양비료학회지
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• 제48권6호
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• pp.736-743
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• 2015

Organic matter plays important roles in soil ecosystem in terms of carbon and nitrogen cycles. Due to recent concerns on climate change, carbon sequestration in agricultural land has become one of the most interesting and debating issues. It is necessary to understand behavior of soil carbon for evaluating decomposition or sequestration of organic matter and analyzing potential carbon decomposition pattern about the kinds of organic matter sources to cope with well. In order to evaluate decomposition of soil carbon according to organic material during cultivating rice in paddy field, we treated organic material such as hairy vetch, rice straw, oil cake fertilizer, and manure compost at $50{\times}50{\times}20cm$ blocks made of wood board, and analyzed carbon contents of fulvic acid and humic acid fraction, and total carbon periodically in 2013 and 2014. Soil sampling was conducted on monthly basis. Four Kinds of organic matter were mixed with soil in treatment plots on 2 weeks before transplanting of rice. The treatment of animal compost showed the highest changes of total carbon, which showed $7.9gkg^{-1}$ in May 2013 to $11.6gkg^{-1}$ in October 2014. Fulvic acid fraction which is considered to easily decompose ranged from 1 to $2gkg^{-1}$. Humic acid fraction was changed between 1 to $3gkg^{-1}$ in all treatments until organic material had been applied in 2014. From May to August in the second year, the contents of humic acid fraction increased to about $4gkg^{-1}$. The average of humic fraction carbon at treatments of animal compost was recorded highest among treatments during two years, $2.1gkg^{-1}$. The treatment of animal compost has showed the lowest ratio of fulvic acid fraction, humic acid fraction compared with other treatments. The average ratio of fulvic fraction carbon in soil ranged from 16 to 20%, and humic fraction carbon ranged from 19 to 22%. In conclusion, animal compost including wood as bulking agent is superior in sequestrating carbon at agricultural land to other kinds of raw plant residue.