• Title/Summary/Keyword: Softening Effect

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Blending effect of pyrolyzed fuel oil and coal tar in pitch production for artificial graphite

  • Bai, Byong Chol;Kim, Jong Gu;Kim, Ji Hong;Lee, Chul Wee;Lee, Young-Seak;Im, Ji Sun
    • Carbon letters
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    • v.25
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    • pp.78-83
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    • 2018
  • Pyrolyzed fuel oil (PFO) and coal tar was blended in the feedstock to produce pitch via thermal reaction. The blended feedstock and produced pitch were characterized to investigate the effect of the blending ratio. In the feedstock analysis, coal tar exhibited a distinct distribution in its boiling point related to the number of aromatic rings and showed higher Conradson carbon residue and aromaticity values of 26.6% and 0.67%, respectively, compared with PFO. The pitch yield changed with the blending ratio, while the softening point of the produced pitch was determined by the PFO ratio in the blends. On the other hand, the carbon yield increased with increasing coal tar ratio in the blends. This phenomenon indicated that the formation of aliphatic bridges in PFO may occur during the thermal reaction, resulting in an increased softening point. In addition, it was confirmed that the molecular weight distribution of the produced pitch was associated with the predominant feedstock in the blend.

Numerical simulation of reinforced concrete nuclear containment under extreme loads

  • Tamayo, Jorge Luis Palomino;Awruch, Armando Miguel
    • Structural Engineering and Mechanics
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    • v.58 no.5
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    • pp.799-823
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    • 2016
  • A finite element model for the non-linear dynamic analysis of a reinforced concrete (RC) containment shell of a nuclear power plant subjected to extreme loads such as impact and earthquake is presented in this work. The impact is modeled by using an uncoupled approach in which a load function is applied at the impact zone. The earthquake load is modeled by prescribing ground accelerations at the base of the structure. The nuclear containment is discretized spatially by using 20-node brick finite elements. The concrete in compression is modeled by using a modified $Dr{\ddot{u}}cker$-Prager elasto-plastic constitutive law where strain rate effects are considered. Cracking of concrete is modeled by using a smeared cracking approach where the tension-stiffening effect is included via a strain-softening rule. A model based on fracture mechanics, using the concept of constant fracture energy release, is used to relate the strain softening effect to the element size in order to guaranty mesh independency in the numerical prediction. The reinforcing bars are represented by incorporated membrane elements with a von Mises elasto-plastic law. Two benchmarks are used to verify the numerical implementation of the present model. Results are presented graphically in terms of displacement histories and cracking patterns. Finally, the influence of the shear transfer model used for cracked concrete as well as the effect due to a base slab incorporation in the numerical modeling are analyzed.

TMCP 강의 용접열영향부 인성에 관한 연구

  • 신민태;윤중근;김희진
    • Journal of Welding and Joining
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    • v.4 no.3
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    • pp.43-49
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    • 1986
  • Weldability of the TMCP steel manufactured by controlled rolling followed by accelerated cooling process was investigated. For comparison, two other steel plates produced by different manufacturing processes were selected; normalized and controlled rolled. Tandem submerged arc welding with both side one run technique was carried out. The results of this study can be summarized as follows; TMCP steel having the lowest carbon equivalent shows the best combination of mechanical properties, not only in the base metal but also in the heat affected zone. In the HAZ, the accelerated colling effect imarted on the trengthis releved by the weld thermal cycles, and thus the strength of the welded joint decrease substantially accompanied with the fracture in the HAZ. On the other hand, not only the softening but the fine microstructure can preserve the high toughness of TMCP steel in the HAZ.

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Weldability of $620^{\circ}C$ Grade High Cr Ferrite Cast Steel for Turbine Casing ($620^{\circ}C$급 터빈 케이싱용 고Cr 페라이트강의 용접성)

  • Byeon Ji-Cheol;Bang Guk-Su;Gwon Hui-Gyeong;Ji Byeong-Ha
    • Proceedings of the KWS Conference
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    • 2006.05a
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    • pp.274-276
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    • 2006
  • Weldability of high Cr ferritic steel for $620^{\circ}C$ grade turbin casing were investigated. The effect of carbon content on the cold and hot cracking susceptibility and HAZ softening was determined. The cast steel with higher carbon content showed higher HAZ hardness because of the dissolution of cabonitrides during welding thermal cycle. Moreover, it showed higher solidification cracking sensitivity because of the little S-ferrite formation in weld metal. Both steels showed HAZ softening at $900^{\circ}C$ peak temperature after PWHT.

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Effect of Post Weld Heat Treatment on the Mechanical Properties of 2.25Cr-1Mo Steels Valves and Piping (용접후열처리가 2.25Cr-1Mo 강 밸브 및 배관재 물성에 미치는 영향)

  • Kim, Hongdeok;Lee, Yoseob;Lee, Jaegon;Lee, Kyoungsoo
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.11 no.1
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    • pp.33-38
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    • 2015
  • The effects of post weld heat treatment(PWHT) on the mechanical properties of 2.25Cr-1Mo steels were investigated. As the PWHT temperature or holding time increased, the strength of low alloy steels progressively decreased due to softening process. After the conventional PWHT, the strength was larger than the minimum value of materials specification. The Charpy impact energy was hardly affected by the conventional PWHT. The trend of mechanical properties was analyzed in terms of tempering parameter. Most materials replaced from a power plant met the requirements of materials specification except for one heat. Same heat of materials with low impact energy were attributed to the voids formed during casting process.

FEM Analysis of Blanking of Mild Steel Sheet at Various Punch Speeds (연강 판재의 속도에 따른 블랭킹의 유한요소해석)

  • Song, Shin-Hyung;Choi, Woo Chun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.25 no.6
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    • pp.458-461
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    • 2016
  • In this study, a finite element analysis for high-speed blanking of mild steel is performed. A thermomechanically coupled simulation model of a blanking process was developed using ABAQUS/Explicit. Through a simulation of the high-speed blanking process of mild steel, the influence of the punch speed, tool edge radius, and work material thickness on the development of the plastic heat and punch load were studied. The results of the study revealed that a higher punch speed caused thermal softening of the work material and decreased the punch load. Decreasing tool edge radius could help reduce the punch load. In addition, the results of the study revealed that the thermal softening effect was more dominant in the blanking of a mild steel sheet with a greater thickness as compared to that in the blanking of a mild steel sheet with a lower thickness.

Effect of Static Softening on Hot Plastic Deformation Behaviour for 304Stainless Steel (304 스테인레스강의 고온소성변형특성에 미치는 정적연화 효과)

  • 조상현;김유승;유연철
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1997.10a
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    • pp.185-188
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    • 1997
  • Static restoration during hot interrupted deformation of 304 stainless steel was studied in the temperature range from 900 to 1100$^{\circ}C$ under various strain rate of 0.05∼ 5/sec and pass strain of 1/4∼3 times peak strain. The static restoration was dependent on the pass strain, deformation temperature and strain rate. Fractional softening(FS) values increased with increasing strain rate, deformation temperature and pass strain. Recystallization kinetics was well explained by the Avrami equation and the time for 50% recrystallization was evaluated using equation of t0.5=2.01${\times}$10-10$\varepsilon$-.156$\varepsilon$ -0.81Dexp(196.66/RT)

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A Local Softening Method for Reducing Die Load and Increasing Service Life in Trimming of Hot Stamped Part (핫스템핑 부품의 전단가공에서 전단 하중의 감소 및 트리밍 금형 수명 향상을 위한 국부 연화 방법)

  • Choi, H.S.;Lim, W.S.;Kang, C.G.;Kim, B.M.
    • Transactions of Materials Processing
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    • v.20 no.6
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    • pp.427-431
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    • 2011
  • In general, hot stamped component is trimmed by costly and time consuming laser cutting when the material strength is over 1,500MPa. The aim of this work was to demonstrate that the trimming die life is improved and the trimming load is decreased by lowering the strength of the region to be trimmed. The model employed in this study was a hat shape, similar to the cross section of many hot stamped products. FE-analysis of hot stamping process was performed to evaluate the effect of tool shape on cooling rate at the area to be trimmed. The best tool shape was thus identified, which created slower cooling and lower hardness at the region to be trimmed. The wear at the cutting tool edge was also reduced.

Evaluation of Water Softening with the Removal of Calcium Ion by Ion Flotation Approach

  • Mafi, Azadeh;Khayati, Gholam
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.219-224
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    • 2021
  • Ion flotation is an efficient method to remove metal ions from aqueous solution. In this work, ion flotation was applied to calcium removal from aqueous solution. The parameters used included sodium stearate (SS) and sodium dodecyl sulfate (SDS) as collectors, 1-butanol and 1-propanol as frothers, pH, and air-flow rate. An L16 orthogonal array was chosen according to the mentioned factors and levels, and experimental tests were conducted according to the Taguchi orthogonal array. The results showed that all of the factors except one had significant effect on the flotation performance. The percentage contribution of parameters showed that type of frother and type of collector made the greatest (43.14%) and the lowest (9.86%) contribution, respectively. In optimal conditions, the recovery of Ca (II) ion was 45.67%. Also, the results illustrated that the Taguchi method could predict calcium removal from aqueous solution by ion flotation with 2.63%. This study showed that the use of ion flotation was an effective method for Ca (II) ion removal from aqueous solution.

Effect of $P_2O_5$ on the Phase Separation of $PbO-B_2O_3$ Glasses ($PbO-B_2O_3$ 계 유리의 상분리에 미치는 $P_2O_5$의 영향)

  • 최춘식;김철영
    • Journal of the Korean Ceramic Society
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    • v.22 no.4
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    • pp.47-53
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    • 1985
  • Various amount of $P_2O_5$ were added to $PbO-B_2O_3$ binary glass system to investigate its effect on the phase separation and physical properties of the glass. Experiments such as infrared spectroscopy scanning electron microscopy thermal expansion softening point and microhardnesses were done. Phase separation with $B_2O_3$ rich phase matrix and PbO rich phase droplet was observed for the glasses con-taining less than 10m/o of PbO while the opposite morphology of phase separation for the glasses containing more than 11m/o of PbO. By adding increasing amount of $P_2O_5$ their phase separation region was extended to the glass containing more than 20m/o of PbO. These effects can be interpreted in terms of the inoic field strength difference of each ions in the glasses. The abrupt changes of physical properties such as softening point thermal expansion and microhardness were observed for the glass with around 10m/o of PbO in this system. These changes are by the matrix composition change from TEX>$B_2O_3$ rich phase to PbO rich phase depending on PbO concentration.

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