• Title/Summary/Keyword: Sodium dodecylbenzenesulfonate

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Adsorption and Degradation of Alkylbenzenesulfonate by Soils (Alkylbenzenesulfonate의 토양(土壤)에 의한 흡착(吸着)과 분해(分解))

  • Ha, Sang-Keon;Joo, Jin-Ho;Um, Myung-Ho;Lim, Hyung-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.2
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    • pp.169-175
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    • 1988
  • A laboratory experiment was conducted to investigate the effects of pH, organic matters and anion on the adsorption and degradation of surfactant by different soils; Anmi series (limestone region), Gangseo series (alluvial soil). For this study, Alkyl Benzene Sulfonate (ABS ; Sodium Dodecylbenzenesulfonate) was used as a surfactant. The results were as follows: 1. Adsorption of ABS by soils was correlated positively with the equilibrium concentration of ABS in a soil suspension. (Anmi seris : r=0.9855, Gangseo series : r=0.9931). 2. Adsorption rate of ABS by soils was about 70% of the treated concentration ($600{\mu}g$ ABS/g soil) in a range of pH 4 to pH 5, and about 20% for pH 8. 3. Addition of electrolytes increased ABS adsorption by soils in a soil suspension; the higher concentration, the higher adsorption. But the influence among electrolytes was not significant. 4. Adsorption of ABS by soils was not affected by soil organic matter content in this experiment. 5. Degradation rate of ABS in a soil suspension was about 85% at $30^{\circ}C$, and about 10 to 15% at $10^{\circ}C$. Addition of sewage accelerated the degradation rate regardless of temperature and reached about 85% in a week.

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Synthesis and characterization of three-dimensional monodispersed NiO/NiCo2O4 via Ni3[Co(CN)6]2 PBA nanocubes (Ni3[Co(CN)6]2 PBA 나노큐브를 통한 단분산된 3차원 구조의 NiO/NiCo2O4 제조 및 특성 평가)

  • Kwag, Sung Hoon;Lee, Young Hun;Kim, Min Seob;Lee, Chul Woo;Kang, Bong Kyun;Yoon, Dae Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.3
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    • pp.110-114
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    • 2017
  • $NiO/NiCo_2O_4$ nanocubes were successfully synthesized via the calcination process of $Ni_3[Co(CN)_6]_2$ PBAs. The prepared monodispersed $Ni_3[Co(CN)_6]_2$ PBAs were aggregated by 'self-assembly' of the nuclei generated during the synthesis reaction. The self-assembly rate of the particles is affected by the temperature and the amount of surfactant SDBS (sodium dodecylbenzenesulfonate). FESEM analysis shows that monodispersed 200 nm PBA nanocubes are obtained at 0.25 g SDBS and $60^{\circ}C$ temperature. Thermal behavior was confirmed by thermogravimetric-differential thermal analysis (TG-DTA) to determine optimal calcination conditions. Then, field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD) analyzes were performed to investigate the morphology and crystallinity of the particles precursors and $NiO/NiCo_2O_4$ nanocubes.