• Title/Summary/Keyword: Sodium Dodecyl Sulfate

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Dispersion Stability of Pigments in Aqueous Solution of Anionic Oligo-Type Surfactants(IV);Dispersiveness of ${\alpha}-sulfo$ fatty acid vinyl ester oligomers (올리고머형 음이온성계면활성제 수용액에서 안료의 분산안정성(제4보);알파 술폰 지방산 비닐에스테르 올리고머의 분산성)

  • Lee, H.W.;Park, S.Y.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.3
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    • pp.55-60
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    • 1998
  • The sodium ${\alpha}-sulfo$ fatty acid vinyl ester oligomers, which are oligomer type surfactants were prepared by polymerization with fatty acid vinyl acetate. The ${\alpha}-sulfonation$ of fatty acid vinyl ester oligomers were carried by direct addition of sulfur trioxide. The dispersing performance of oligomer type anionic surfactants and sodium dodecyl sulfate(SDS) in the aqueous suspension of iron oxide and titanium dioxide particles was evaluated by particle size distribution and zeta-potential measurement. As results, the particles of iron oxide and titanium dioxide were flocculated by addition of small amount of oligomer type anionic surfactants and sodium dodecyl sulfate(SDS), then the flocks redispersed by more addition of oligomer type anionic surfactants and SDS. The flocculation, redispersion process was observed in lower concentration range of oligomer type anionic surfactants than SDS. Especially, the dispersing action of sodium ${\alpha}-sulfo$ palmitic acid vinyl ester oligomer was better than sodium ${\alpha}-sulfo$ lauric acid vinyl ester oligomer.

Chemical cleaning effects on properties and separation efficiency of an RO membrane

  • Tu, Kha L.;Chivas, Allan R.;Nghiem, Long D.
    • Membrane and Water Treatment
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    • v.6 no.2
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    • pp.141-160
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    • 2015
  • This study aims to investigate the impacts of chemical cleaning on the performance of a reverse osmosis membrane. Chemicals used for simulating membrane cleaning include a surfactant (sodium dodecyl sulfate, SDS), a chelating agent (ethylenediaminetetraacetic acid, EDTA), and two proprietary cleaning formulations namely MC3 and MC11. The impact of sequential exposure to multiple membrane cleaning solutions was also examined. Water permeability and the rejection of boron and sodium were investigated under various water fluxes, temperatures and feedwater pH. Changes in the membrane performance were systematically explained based on the changes in the charge density, hydrophobicity and chemical structure of the membrane surface. The experimental results show that membrane cleaning can significantly alter the hydrophobicity and water permeability of the membrane; however, its impacts on the rejections of boron and sodium are marginal. Although the presence of surfactant or chelating agent may cause decreases in the rejection, solution pH is the key factor responsible for the loss of membrane separation and changes in the surface properties. The impact of solution pH on the water permeability can be reversed by applying a subsequent cleaning with the opposite pH condition. Nevertheless, the impacts of solution pH on boron and sodium rejections are irreversible in most cases.

Solubilization isotherms of MTBE in various surfactant solutions for application of micellar-enhanced ultrafiltration (MEUF)

  • 양지원;백기태
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.103-106
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    • 2002
  • Solubilization isotherms for methyl tort-butyl ether (MTBE) in sodium dodecyl sulfate(SDS), dowfax 8390, sodium dodecylbenzenesulfonate and cetylpyridinium chloride (CPC) were investigated for application to micellar enhanced remediation. Dowfax 8390 showed maximum extent of solubilization among surfactants tested in this study. It seems that sulfate group in anionic surfactants playes a important role in solublization of MTBE. Chemical shiftes in NMR of surfactant and MTBE supports this point.

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Micellar Enhanced Ultrafiltration (MEUF) and Activated Carbon Fiber (ACF) Hybrid Processes for the Removal of Cadmium from an Aqueous Solution

  • Rafique, Rahman Faizur;Lee, Seunghwan
    • Korean Chemical Engineering Research
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    • v.52 no.6
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    • pp.775-780
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    • 2014
  • Micellar enhanced ultrafiltration (MEUF) was used to remove cadmium from an aqueous solution using sodium dodecyl sulfate (SDS) as a surfactant. Operational parameters such as initial permeate flux, retentate pressure, initial cadmium concentration, pH solution, molecular weight cut-off (MWCO), and molar ratio of cadmium to SDS were investigated. Removal efficiency of cadmium from an aqueous solution increased with an increase of retentate pressure, pH solution and molar ratio of cadmium to SDS, and decreased with an increase of initial permeate flux. Higher removal efficiency of cadmium from the aqueous solution was achieved using lower MWCO (smaller membrane pore size). Under optimized experimental condition, cadmium removal efficiency reached 74.6 % within an hour. Using MEUF-ACF hybrid process the removal efficiency of both cadmium and SDS was found to be over 90%.

Electrochemical Investigation of Bovine Hemoglobin at an Acetylene Black Paste Electrode in the Presence of Sodium Dodecyl Sulfate

  • Zhan, Guoqing;Li, Chunya;Luo, Dengbai
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1720-1724
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    • 2007
  • Electrochemical behaviors of bovine hemoglobin (Hb) at an acetylene black paste electrode based on the enhancement effect of sodium dodecyl sulfate (SDS) were investigated. In the optimal conditions, a very weak reduction peak was observed at an acetylene black paste electrode for hemoglobin in the absence of SDS. However, the reduction peak current increased remarkably after the addition of 4.0 × 10?4 mol L?1 SDS, suggesting that SDS exhibits obvious enhancement effect to the determination of hemoglobin. All the experimental parameters, such as pH value, concentration of SDS, accumulation time and accumulation potential were optimized for hemoglobin analysis. The proposed method possesses high sensitivity (detection limit is 3.0 × 10?9 mol L?1), wide linearity (6.0 × 10?9 to 6.0 × 10?7 mol L?1), rapid response and low cost. Finally, the method was successfully employed to determine hemoglobin in a spiked sample.

Electrochemistry of Tris(2,2'-bipyridyl)Ruthenium(II)-Sodium Dodecyl Sulfate in 300 mM $H_2SO_4$ Solution

  • Ko, Young Chun
    • Journal of Integrative Natural Science
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    • v.2 no.1
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    • pp.24-27
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    • 2009
  • Electrochemistry of 1.0 mM tris(2,2'-bipyridyl)ruthenium(II) ($Ru(bpy)_3{^{2+}}$) in 300 mM $H_2SO_4$ solution with and without sodium dodecyl sulfate (SDS) is studied. In the presence of SDS, $E_{pa}$ of $Ru(bpy)_3{^{2+}}$ shifts to positive direction compared to the SDS free case. The intersection of two lines on ${\Delta}E_p$ vs. -log[SDS] plot is measured as a critical micelle concentration (CMC), which is 3.67 mM SDS.

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Solubilization Isotherms of Chlorobenzene in ionic Surfactant Solutions

  • Baek, Ki-Tae;Yang, Ji-Won
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.201-204
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    • 2003
  • Solubilization isotherms of 1-chlorobenzene (MCB) and 1, 2-dichlorobenzene (DCB) were investigated in ionic surfactant solutions such as sodium dodecyl sulfate (SDS), cetylpyridinium chloride (CPC), and dedecyltrimethylammonium chloride (DMAC). The solubilization extent of DCB was much higher than that of MCB because of the main driving force of solubilization Is hydrophobic interactions between chlorobenzenes and hydrophobic interior of ionic micelles and DCB is more hydrophobic than MCB. CPC showed highest solubilization capacity because of longest hydrophobic tails. Simultaneous solubilization of MCB and DCB decreased slightly the extent solubilization of both MCB and DCB because the solubilization locus in the micelles is same.

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STUDIES ON THE I LABELLING OF CASTOR OIL, AND THE DETERGENCY OF SODIUM DODECYL SULFATE

  • Heo, Yong-Cheol;Mun, Byeong-Yeol;Kim, Yeong-Guk
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.10 no.1
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    • pp.42-48
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    • 1984
  • The comparative detergency of Sodium dodecyl sulfate (SDS) solution near the first critical micelle concentration (CMC) was measured by means of a 131 I-labelled castor oil as a soil. More than 95% radiochemical purity of 131 I-labelled castor oil was obtained using potassium lidide as a carrier. Polyester test fabric was soiled with 131 I-labelled castor oil, and washed in a conventional washing apparatus mounted on appropriate devices. Fabric radioactivities were measured before and after washing by a scintilation counter. Near the first CMC, the detergency of SDS was increased with decreasing of surface tension of SDS. It was also shown that 131 I-labelled castor oil was useful for studying the detergency of SDS.

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Fast Protein Staining in Sodium Dodecyl Sulfate Polyacrylamide Gel using Counter ion-Dyes, Coomassie Brilliant Blue R-250 and Neutral Red

  • Choi, Jung-Kap;Yoo, Gyurng-Soo
    • Archives of Pharmacal Research
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    • v.25 no.5
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    • pp.704-708
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    • 2002
  • A fast and sensitive protein staining method in sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) using both an acidic dye, Coomassie Brilliant Blue R-250 (CBBR) and a basic dye, Neutral Red (NR) is described. It is based on a counter ion-dye staining technique that employs oppositely charged two dyes to form an ion-pair complex. The selective binding of the free dye molecules to proteins in an acidic solution enhances the staining effect of CBBR on protein bands, and also reduces gel background. It is a rapid staining procedure, involving fixing and staining steps with short destaining that are completed in about 1 h. As the result, it showed two to fourfold increase in sensitivity comparing with CBBR staining. The stained protein bands can be visualized at the same time of staining.