• Title/Summary/Keyword: Sodium Chlorite

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Total Utilization of Woody Biomass by Steam Explosion(I) -Delignification of pine and oak exploded wood- (폭쇄법(爆碎法)을 이용(利用)한 목질계(木質系) Biomass의 종합적(綜合的) 이용(利用)(I) -소나무와 신갈나무 폭쇄재(爆碎材)의 탈(脫)리그닌처리(處理)-)

  • Lee, Jong-Yoon;Chang, Jun-Pok;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.3
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    • pp.11-20
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    • 1992
  • Steam explosion is one of the most effective pretreatment for fractionating wood. This leads to the total utilization of wood basic components; cellulose, hemicellulose and lignin. The amount of sugar and lignin extracted with the hot water method was very low. The lignin content of residues after extraction with using a sodium hydroxide treatment, increased delignification of carbohydrate as the concentration of alkali was increased. Oak, pretreated with steam exploded at 25kg/$cm^2$ for 6 min. then 1% alkali for 2hrs. showed a delignification rate up to 95%. A sodium chlorite treatment of steam exploded pine and oak also afforded a high deligninfication effect. Pine, treated 10% sodium chlorite for 2hrs. showed high delignification. However, by using a sodium hydroxide treatment, a 2% retreatment for Ihr. after a 2% for 2hrs. afforded remarkable delignification effect on exploded wood at 30kg/$cm^2$ for 9min. and at 35kg/$cm^2$ for 3-6min. In oak, an initial 2hrs. treatment of 2% sodium chlorite was followed by a second 2hrs. treatment at 10%. This showed a delignification rate of 96%.

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The Enzymatic Hydrolysis of Exploded Woody Biomass(I) -Effects of Lignin Contents and Cellulose Crystallinity on the Enzymatic Hydrolysis- (폭쇄처리(爆碎處理)된 목질계(木質系) Biomass의 산소가수분해(酸素加水分解)(I) -리그닌의 함량(含量)과 섬유소(纖維素)의 결정화도(結晶化度)가 산소가수분해(酸素加水分解)에 미치는 영향)

  • Park, Young-Ki;Oh, Jung-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.21 no.3
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    • pp.53-60
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    • 1993
  • Substrates used were hardwood-Suwon poplar-(Populus alba${\times}$glandulosa L.) and softwood-pitch pine-(Pinus rigida M.). And these substrates were steam exploded then treated with sodium chlorite at 75$^{\circ}C$ with occasional stirring in order to obtain samples which had different lignin contents and crystallinity. And then this resulting samples incubated with a commercial cellulase derived from Trichoderma ressei. The contents of Klason lignin were decreased as the increasing of the ratio of sodium chlorite in the two species. The effect of hardwood was more effective than that of softwood in the same ratio of sodium chlorite. The minimum contents of Klason lignin were 0.8% and 5.1% respectively. And the crystallinities of cellulose were increased very little as increasing of the ratio of sodium clorite. The hydrolysis extent of the two species were increased as the increasing of delignification. Especially, the hydrolysis extent of hardwood was more higher than that of softwood. The maximum hydrolysis extent were 89.8% and 71.1%, respectively.

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Utilization of Ligno-cellulosic Biomass(III)-Acid Hydrolysis of Exploded Wood after Delignification (목질계 바이오매스의 이용(제3보)-탈리그닌 처리한 폭쇄재의 산가수분해-)

  • 양재경;장준복;임부국;이종윤
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.4
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    • pp.18-27
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    • 1997
  • This study was performed to obtained the optimal delignified condition of exploded wood on the acid hydrolysis with sulfuric acid. Wood chips of pine wood(Pinus desiflora), oak wood(Quercus serrata) and birch wood (Betula platyphylla var. japonica) were treated with a high pressure steam (20-30kgf/$\textrm{cm}^2$, 2-6 minutes). The exploded wood was delignified with sodium hydroxide and sodium chlorite, and then hydrolyzed with sulfuric acid. The result can be summerized as follows ; In the exploded wood treated with sodium hydroxide, the optimal concentration of sodium hydroxide was 1% as content of lignin in the exploded wood. Lignin content of exploded wood treated with sodium chlorite was lower then that sodium hydroxide. The maximum reducing sugar yield of exploded wood treated with 1% sodium hydroxide was lower than non-treated exploded wood. In the case of sodium chlorite treated, the maximum reducing sugar yield was hgher than non-treated exploded wood. Sugar composition of acid hydrolysis solution was composed of xylose and glucose residue, and the rate of glucose residue was increased in high pressure condition.

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Development of High Viscosity Pulping Method for Korean Paper (I) - Atmospheric Pressure Pulping Characteristics of Paper Mulberry White Bast - (고점도 펄프를 위한 새로운 한지 펄프화법의 개발(제1보) - 닥나무 백피의 상압 펄프화 특성 -)

  • Lee, Sang-Hyun;Choi, Tae-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.2
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    • pp.57-65
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    • 2011
  • Pulping of paper mulberry (Broussonetia kazinoki) white bast has been examined by novel atmospheric pressure pulping methods. The viscosity of pulp has been found to be highly sensitive and variable with pulping methods. Therefore, selections of pulping chemicals and conditions are very important. Two kinds of pulping procedures were employed for the high viscosity pulp manufacturing. The one is ammonium oxalate treatment and the other is sodium chlorite and acetic acid treatment. Not only chemical components and pulp yields which of paper mulberry white bast but also water retention value (WRV), whiteness index, yellowness index, and colors of every pulp were examined. The hot water, 1% NaOH, and ethanol-benzene extractives which of paper mulberry white bast were 4.48%, 28.45%, and 2.84%, respectively. The contents of holocellulose, lignin, and ash were 90.66%, 1.05%, and 2.18%, respectively. In the pulp yields, group 1 which treated with only ammonium oxalate were 77.04-81.71%, group 2 which treated with ammonium oxalate and acidified sodium chlorite separately and washed between first and second stages were 64.15-83.90%, group 3 which treated with ammonium oxalate and acidified sodium chlorite separately and not washed between first and second stages were 57.35-73.17%, and group 4 which treated with mixed ammonium oxalate and acidified sodium chlorite were 66.58-68.43%. The pulps treated with acidified sodium chlorite showed high whiteness index, but the pulps treated with only ammonium oxalate showed high yellowness index. Variations in the combinations of treatments resulted in different pulp characteristics.

The Effect of Citric Acid and Sodium Chlorite Mixtures on the Growth of Microorganisms from Broiler Thigh Surface (구연산과 아염소산나트륨 혼합물이 육계 넓적다리 표면의 미생물 증식에 미치는 영향)

  • 김태현;이영현
    • Food Science of Animal Resources
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    • v.22 no.1
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    • pp.44-49
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    • 2002
  • The effect of citric acid and sodium chlorite(NaClO$_2$) mixtures at 100, 200 and 500 ppd(w/v) on the growth of microorganisms from broiler thigh surface was investigated. Absorbance and aerobic plate counts(APC) of inoculated nutrient broth refrigerated storage at 4∼5$^{\circ}C$ were measured after each additive was added. APC on thigh surface after immersion in each selected solution was enumerated during storage at 4∼5$^{\circ}C$ Absorbance of all citric acid and sodium chlorite mixture(0:100, 25:75, 50:50, 75:25 and 100:0, w/w) except 200 and 500 ppm of 100:0 at Day 0 were lower than the control during storage (p<0.05). And higher concentration of mixture tended to have lower absorbance. APC on thigh surface treated with 500 ppm citric acid and sodium chlorite mixture at 50 : 50 and 75 : 25 ratio were lower than others (p<0.05). Similar antimicrobial activity of additives was found in nutrient broth and on broiler thigh surface.

Efficacy of Sodium Hypochlorite and Acidified Sodium Chlorite in Preventing Browning and Microbial Growth on Fresh-Cut Produce

  • Sun, Shih-Hui;Kim, Su-Jin;Kwak, Soo-Jin;Yoon, Ki-Sun
    • Preventive Nutrition and Food Science
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    • v.17 no.3
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    • pp.210-216
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    • 2012
  • The use of suitable sanitizers can increase the quality of fresh-cut produce and reduce the risk of foodborne illnesses. The objective of this study was to compare the washing effects of 100 mg/L sodium hypochlorite (SH) and 500 mg/L acidified sodium chlorite (ASC) on the prevention of enzymatic browning and the growth of microbial populations, including aerobic plate counts, E. coli, and coliforms, throughout storage at $4^{\circ}C$ and $10^{\circ}C$. Fresh-cut zucchini, cucumbers, green bell peppers, and root vegetables such as potatoes, sweet potatoes, carrots, and radishes were used. Compared to SH washing, ASC washing significantly (p<0.05) reduced microbial contamination on the fresh-cut produce and prevented browning of fresh-cut potatoes and sweet potatoes during storage. More effective inhibition of aerobic plate counts and coliforms growth was observed on fresh-cut produce treated with ASC during storage at $10^{\circ}C$. Polyphenol oxidase (PPO) activity of fresh-cut potatoes and sweet potatoes was more effectively inhibited after washing with ASC. The use of 500 mg/L ASC can provide effective antimicrobial and anti-browning treatments of fresh-cut produce, including processed root vegetables.

Studies on the Bleaching of Rice-Straw Chemical Pulp (II) -Two-Stages Bleaching- (볏짚화학펄프의 표백에 관한 연구(제2보) -2단 표백-)

  • 강진하;박성종;박성철
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.84-99
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    • 2001
  • This study was carried out to acquire basic data necessary for the use of rice-straw chemical pulp. It investigated the proper bleaching conditions when rice-straw chemical pulp(alkaline sulfite-${Na_2}{S_2}{O_4}$) was bleached using the various kinds of bleaching agents by the two-stages bleaching methods. And, physical properties of pulps bleached with eight kinds of two-stages bleaching methods were tested. The results of this study were as follow; 1. The first-stage bleaching was conducted under the proper conditions with chlorine(C). And then, the proper conditions related to the calcium chlorite(H), hydrogen peroxide(P) and sodium hydrosulfite(Y) bleaching as the second-stage bleaching were investigated. The proper conditions of CH stage were determined to be 0.3% concentration of calcium chlorite, $30^{\circ}C$ of reaction temperature and 20min. of reaction time. For CP stage, the proper conditions of concentration of hydrogen peroxide, reaction temperature and reaction time were 1.5%, $60^{\circ}C$ and 90min., respectively. And for CY stage, the proper conditions were 0.5% concentration of sodium hydrosulfite, $40^{\circ}C$ of reaction temperature and 90min. of reaction time. 2. The first-stage bleaching was conducted under the proper conditions with chlorine dioxide(D). And then, the proper conditions related to the calcium chlorite(H), hydrogen peroxide(P) and sodium hydrosulfite(Y) bleaching as the second-stage bleaching were investigated. The proper conditions of DH stage were determined to be 0.5% concentration of calcium chlorite, $25^{\circ}C$ of reaction temperature and 5min. of reaction time. For DP stage, the proper conditions of concentration of hydrogen peroxide, reaction temperature and reaction time were 1.0%, $70^{\circ}C$ and 90min., respectively. And for DY stage, the proper conditions were 0.3% concentration of sodium hydrosulfite, $50^{\circ}C$ of reaction temperature and 20min. of reaction time. 3. The first-stage bleaching was conducted under the proper conditions with calcium chlorite(H). kAnd then, the proper conditions related to the hydrogen peroxide(P) and sodium hydrosulfite(Y) bleaching as the second-stage bleaching were investigated. The proper conditions of HP stage were determined to be 0.3% concentration of hydrogen peroxide, $30^{\circ}C$ of reaction temperature and 60min. of reaction time. For HY stage, the proper conditions of concentration of sodium hydrosulfite, reaction temperature and reaction time were 2.5%, $60^{\circ}C$ and 30min., respectively. 4. When the rice-straw chemical pulps were bleached with eight kinds of two-stages bleaching methods in the proper conditions mentioned above, respectively, the final brightnesses after CH, CP, CY, DH, DP, DY, HP, and HY bleachings were 62.0, 74.3, 61.4, 58.9, 66.9, 62.9, 50.4 and 60.1, respectively. And strengthes of pulps bleached with DP and DH methods were comparatively higher than those of pulps bleached with other bleaching methods.

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The Simultaneous removal of NOx using Wet Scrubber (습식 스크러버를 이용한 NOx 제거에 관한 연구)

  • Kim, Jae-Gang;Lee, Ju-Yeol;Park, Byung Hyun;Choi, Jin-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.296-301
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    • 2015
  • The experiment was performed for in order to remove NOx which is generated in the Ship's engine. it was performed test in order to remove NOx which is generated in the Ship's engine. It was used as the oxidizing agent sodium chlorite. Use the oxidizer is nitrogen monoxide was oxidized to nitrogen dioxide. and was tested pH adjustment to increase the efficiency of oxidizing. An aqueous solution of sodium hydroxide was used for the nitrogen dioxide absorbent. Low concentration of the solution, it showed a high efficiency. improves the absorption efficiency by add additives.

Antimicrobial Effect of Acidified Sodium Chlorite (ASC) on Whole Croaker

  • Lee, Byung-Doo;Koo, Ja-Heon;Jahncke, Michael L.;Kim, Du-Woon;Chung, Dong-Ok;Eun, Jong-Bang
    • Preventive Nutrition and Food Science
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    • v.13 no.4
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    • pp.266-268
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    • 2008
  • The antimicrobial effect of acidified sodium chlorite (ASC) solution on whole croaker skin was evaluated. Whole croaker skin was treated with ASC (50, 100, 200, 400, and 600 ppm) and distilled water. After 10-minute exposure to 600 ppm ASC, 8% of Gram-negative bacteria survived on the whole croaker sample. Treatment with 50 ppm ASC eliminated all coliforms in the initial load. Immersion treatment with 600 ppm ASC resulted in $1.3\;log\;CFU/cm^2$ greater kill of the initial mesophile loads of control ($2.8\;log\;CFU/cm^2$) than distilled water. Fifty ppm ASC solution produced a 1.6-log reduction of psychrotrophic bacteria. ASC treatment was an effective method for reducing naturally occurring microflora on whole croaker skin.

Simultaneous and quantitative determination of anion biocides in soil by liquid chromatography-tandem mass spectrometry (토양 중 음이온 바이오사이드의 HPLC-MS/MS 동시 정량분석법)

  • Yang, Eun-Young;Shin, Ho-Sang
    • Analytical Science and Technology
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    • v.28 no.5
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    • pp.317-322
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    • 2015
  • Simultaneous analytical method has developed for the determination of anion biocides in soil by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Chlorite and chlorate in soil were extracted with pure water, and cyanuric acid and sodium dodecylbenzenesulfonate (Na-DBS) were extracted with mobile phase (0.25 mM ammonium formate in 20 mM formic acid : acetonitrile (1:1)). The extract was injected into the LC-MS/MS system after filtration. The method detection limits in this study were 0.04 mg/kg for chlorite, 0.04 mg/kg for chlorate, 0.27 mg/kg for cyanuric acid, and 0.05 mg/kg for Na-DBS, respectively. The method was applied to the analysis of 50 soil samples collected from 40 sites sprayed with biocides and 10 background sites. As a result, anion biocides were not detected in all sites.