• Title/Summary/Keyword: Sodium Cabonate

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The Improvement of Denitrofication by Using Sodium Salts in the SNCR Process (SNCR 공정에서 Sodium Salts 첨가제를 이용한 탈질반응 개선에 관한 연구)

  • Lee, Seung Moon;Park, Kwinam;Kwak, Tae-Heon;Park, Jin-Won;Makin, Sanjeev;Kim, Byung-Hwan
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.324-329
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    • 2005
  • The efficiency of reducing nitric oxide using urea combined with alkali salt additives is reported in this study. The inlet concentration of NO is 500 ppm with air flow rates of 3 and 5 L/min. Reduction of NO was studied from 650 to $1,050^{\circ}C$ with urea concentrations of 0.3 to 1 mol/L. The efficiency for the reduction of NO increased by 44% when urea is added alone. A further increase in efficiency was observed in the presence of NaOH as additive in fact, the efficiency was increased by more than 25% and 75% when 0.5 mol/L and 1 mol/L NaOH were added with the urea. The efficiency for the reduction of NO increased with all additives, but descended in the order NaOH, $Na_2CO_3$, $NaNO_3$, HCOONa, and CHCOONa. The maximum efficiency of NaOH and $Na_2NO_3$ are 74% and 73%, respectively. All these additives did not alter the comparatively wide operating temperature window for reducing NO. However, sodium compounds do not shift the maximum NO concentration towards lower temperatures when the NO removal activity enhances.

Characteristics of Recycled Fine Aggregate by Sodium Carbonated Water (탄산나트륨을 이용하여 제조한 순환잔골재의 품질 특성)

  • Hong, Sung-Rog;Kim, Ha-Seog;Kwak, Eun-Gu;Park, Sun-Gyu;Kim, Jin-Man
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.2
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    • pp.97-102
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    • 2011
  • Amount of disposed construction materials like waste concrete is growing fast and use of the recycled aggregate for concrete has been seriously considered. But the use of the recycled aggregate is very limited because recycled aggregate has very low quality. Therefore, quality of recycled aggregate is very important in the manufacturing of recycled aggregate concrete. We have studied a series of research according to chemical processes and investigate the alkaline elimination effect of recycled aggregate and quality variation of recycled aggregate by sodium carbonate. Thereafter we have evaluated quality of recycled fine aggregate and experimented quality of this aggregate. As a results, we find that it is easy to eliminate the calcium hydroxide in recycled aggregate by sodium carbonate and the quality of recycled aggregate increase by elimination of alkaline.

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Recovery of Valuable Metals from the Desulfurizing Spent Catalyst Used in Domestic Petrochemical Industry (국내 석유공장의 탈황 폐촉매로부터 유가금속의 회수에 관한 연구)

  • 김종화;양종규
    • Resources Recycling
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    • v.4 no.3
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    • pp.2-9
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    • 1995
  • The rccoverg and separation pracess of nikcl, vanadium and molybdenum from spent dcsulfilrizing catalyst ofpetrochemical rndustries was studied. Tnis process was canied out wet process which is consist of roasting, ammonialeaching and solve111 exDaction techniqcs. The metal ions of NI, V and Mo as vduable compollents were treated byroasting them a1 low lernperatuc, 400$^{\circ}$C in first dep, and then dlssah'ed nu1 at 80$^{\circ}$C wlth ammonium cabonate mlulion.Aftcr cooling them a1 room tempertaure, vanadium wa rccavered from mathcr iiquur in thc f n m of precipitate, sodiumvanadales The Secand slep, roasting the catalyst which is added sodium carbonate ul IOOO"C, was employed. Leachingwith distilled ~ a l e rga ve a iwo phase resultant, solutio~c~a ntaning Ni, V and Mo and solid residue containing sibca,alurmniu~n and iron. A solvcnt exlclction technique uslng vvriuus extractanls, MSP-8, TOIUC, LIX64Pi was eflecnve farthc extraclion and scparation ol thrcc mcfals from thc ammonical 11qou1 thc ammonical 11qou1.

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