• Title/Summary/Keyword: SmCo

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Cyclic Co-oligomeric Ferroelectric Liquid Crystals with Fast Switching Properties, Wide SmC* Temperature Range and de Vries-type SmA*-SmC* Transition

  • Park, Seung-Beom;Cho, Tai-Yon;Yoon, Kyung-Hwan;Chang, Ji-Young;Zentel, Rudolf;Yoon, Do-Y.
    • Bulletin of the Korean Chemical Society
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    • v.32 no.spc8
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    • pp.3057-3062
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    • 2011
  • We have synthesized and characterized the first cyclic co-oligomeric ferroelectric liquid crystals (FLCs) based on cyclic siloxanes and found that the co-oligomer containing two different mesogenic units exhibits $SmC^*$ mesophase over a wide temperature range from $65^{\circ}C$ to $135^{\circ}C$, much wider than those of the monomer counterparts and the cyclic homo-oligomers. The cyclic co-oligomeric liquid crystal readily filled the display cell and exhibited fast switching times in the range of 4 ms to 6 ms over the entire $SmC^*$ phase. Moreover, the practical absence of layer shrinkage, attributed to de Vries-type transition, shows an additional significant advanage for cyclic co-oligomeric FLCs in LCD applications.

The Evaluation of Mixed-welded SM 490A Steel by Acoustic Emission (1) (음향방출법에 의한 SM490A강의 복합용접성 평가 (1))

  • 이장규;우창기;박성완;김봉각;윤종희;인승현
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2002.10a
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    • pp.170-173
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    • 2002
  • The object of this study is to investigate the effect of compounded welding through the AE (Acoustic Emission) characteristics on static tensile test. This study was carried out a SM 490A, high tension steel using the low hydrogen type E4316 of electronic shield metal arc welding and compound wire of $CO_2$gas arc welding. $CO_2$welding, weak in the intensity of HAZ (Heat Affected Zone), can be improved by being combined with coated arc welding, Coated arc welding, weak in the intensity of the bead, can be improved by being combined with $CO_2$welding. Especially, electronic coated arc welding and $CO_2$welding complement the mechanical intensity of HAZ and the bead with each other. So, compounded welding increases the intensity in the special parts and enhances the quality of goods.

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Cathode Properties of Sm-Sr-(Co,Fe,Ni)-O System with Perovskite and Spinel Structures for Solid Oxide Fuel Cell (고체산화물 연료전지의 페로브스카이트와 스피넬 구조를 갖는 Sm-Sr-(Co,Fe,Ni)-O 시스템의 공기극 특성)

  • Baek, Seung-Wook;Kim, Jung-Hyun;Baek, Seung-Whan;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.133-136
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    • 2007
  • Perovskite-structured samarium strontium cobaltite (SSC), which is mixed ionic electronic conductor (MIEC), is considered as a promising cathode material for intermediate temperature-operating solid oxide fuel cell (SOFC) due to its high electrocatalytic property. Cathode material containing cobalt (Co) is unstable at high temperature and has a relatively high thermal expansion property. In this paper, Sm-Sr-(Co,Fe,Ni)-O system with perovskite and spinel structures was investigated in terms of electrochemical property and thermal expansion property, respectively. Area specific resistance (ASR) was measured by ac impedance spectroscopy to investigate the electrochemical property of cathode, and thermal expansion coefficient (TEC) was measured by using dilatometer. Micro structure of cathode was observed by scanning electron microscopy. Perovskite-structured $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ showed the ASR of $0.87{\Omega}/cm^{2}$, and $Sm_{0.5}Sr_{0.5}NiO_{3-\delta}$, which actually has a spinel structure, showed the lowest TEC value of $13.3{\times}10^{-6}/K$.

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Electronic and Magnetic Structures of Rare-earth Permanent Magnets (희토류 영구자석의 전자기적 구조)

  • 민병일;장영록
    • Journal of the Korean Magnetics Society
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    • v.1 no.1
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    • pp.6-11
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    • 1991
  • In order to investigate electronic and magnetic properties of permanent magnets, we have performed self-consistent electronic structure calculations on compounds of rare-earth and transition metals, such as $SmCo_{5},\;NdB_{6},\;NdFe_{5},\;NdFe_{4}B$. Employing the local density LMTO(linearized muffin tin orbital) band method, we have obtained the ground state parameters, such as band structures, density of states, Stoner parameters, and magnetic moments. We have also investigated interactions between d,f-electrons of Nd, Sm rare-earths and d-electrons of Fe, Co transition metals, and the s,p electrons of boron and explored effects of such interactions on the bonding mechanism and the electronic and magnetic structures in these rare-earth compounds.

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Thermal Characteristics of Samarium-based Composite Cathode ($Sm_{0.5}Sr_{0.5}CoO_{3-\delta}/ Sm_{0.2}Ce_{0.8}O_{1.9}$) for Intermediate Temperature-operating Solid Oxide Fuel Cell (고체산화물 연료전지의 Samarium Oxide 혼합 공기극에 대한 열특성 분석)

  • Baek, Seung-Wook;Bae, Joong-Myeon
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2021-2025
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    • 2007
  • Performance of single cell at solid oxide fuel cell (SOFC) system is largely affected by electrocatalytic and thermal properties of cathode. Samarium-based perovskite oxide material is recently recognized as promising cathode material for intermediate temperature-operating SOFC due to its high electrocatalytic property. Perovskite structured $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ and its composite material, $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}/Sm_{0.2}Ce_{0.8}O_{1.9}$ were investigated in terms of area specific resistance (ASR), thermal expansion coefficient (TEC), thermal cycling and long term performance. $Sm_{0.2}Ce_{0.8}O_{1.9}$ was used as electrolyte material. Electrochemical ac impedance spectroscopy (EIS) and dilatometer were used to measure the cathodic properties. Composite cathode ($Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$: $Sm_{0.2}Ce_{0.8}O_{1.9}$ = 6:4) showed a good ASR of 0.13${\Omega}$ $cm^2$ at 650$^{\circ}C$ and its TEC value was 12.3${\times}$10-6/K at 600$^{\circ}C$ which is similar to the value of ceria-based electrolyte of 11.9${\times}$10-6/K. Performance of composite cathode was maintained with no degradation even after 13 times thermal cycle test.

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