• Title/Summary/Keyword: Sm-Co

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The effect of composition ratio on the surface morphology and superconducting properties of SmBCO films prepared by thermal co-evaporation method (동시 열증발법으로 제조한 SmBCO 고온 초전도에서 박막 조성비가 표면형상 및 초전도 특성에 미치는 영향)

  • Lee, N.J.;Kim, H.S.;Ha, H.S.;Ko, R.K.;Song, K.J.;Ha, D.W.;Yang, J.S.;Kim, T.H.;Jeong, Y.H.;Youm, D.J.;Moon, S.H.;Park, C.;Oh, S.S.
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.1
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    • pp.5-8
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    • 2007
  • We have investigated the superconducting properties and surface morphology of $Sm_xBa_yCu_3O_{6+z}$ thin films deposited on LMO/IBAD-MgO/Hastelloy which prepared with different composition ratio by co-evaporation method(EDDC, Evaporation using Drum in Dual Chambers). We observed the composition ratio of SmBCO thin films by EDS analysis. We fabricated SmBCO thin film with critical current density of $1.5{\times}10^6A/cm^2$ at composition ratio of SM:Ba:Cu=1.10:2.01:3(at 77 K self-field). And, we confirmed that substitution of Sm-Ba did not occur at Cu rich phase by EDS analysis.

Surface Hardening of SM45C Steel by CO2 Laser (CO2 레이저를 이용한 SM45C 강의 표면경화)

  • Park, J.S.;Lee, O.Y.;Song, K.H.;Han, Y.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.1
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    • pp.44-52
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    • 1995
  • The specimen for laser hardening have been carried out using SM45C which is coated with black paint or graphite for better absorption. Segmented mirror was used in order to produce a square beam ($10{\times}10mm$) at the surface with a homegeneous intensity distribution across the beam. $CO_2$-Laser power was changed from 2kW to 4kW and transfer velocity was varied from 0.1m/min to 2.0m/min. The maximum hardness and case depth of SM45C steel are 790Hv and 1.5mm by laser hardening. When the surface of specimens was melted during laser hardening. the surface hardness of SM45C steel was decreased. The surface hardness of 2 layer coated specimen(black paint: $15.4{\mu}m$, graphite coating: $9.5{\mu}m$) was increased than that of 1 layer coated specimen. It is desirable to prepare 2 or more coating layer on the steel surface in order to sufficient case depth and hardness in laser hardening. The graphite coating on the specimen surface was obtained more uniform temperature distribution than black paint coating in laser hardening process.

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Structure and Magnetic Properties of Sm-Co(x nm)/Co(6 nm) Multi-layered Nanocomposite Films

  • Yang, Choong-Jin;You, Cai-Yin;Zhang, Zhi-Dong
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.24-25
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    • 2002
  • Tthe structure and magnetic properties of Sm-Co/co films treated at various annealing temperatures and times are reported, The effects of an externally applied magnetic field during annealing, were also investigated. These result is discussed in terms of magnetization reversal of nano grains which seems to compete with the exchange interaction occurring between the nano grains. (omitted)

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IMPROVEMENT EFFECTS OF ELECTROCHEMICAL STABILITY OF MAGNETIC MATERIALS FOR PROSTHETIC DENTISTRY (치과보철용 자석재료의 전기화학적 안정성 개선효과)

  • Kwack, Jong-Ha;Oh, Sang-Ho;Choe, Han-Cheol;Chung, Chae-Heon
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.5
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    • pp.628-641
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    • 2006
  • Statement of problem: Dental magnetic materials have been applied to removable prosthetic appliances, maxillofacial prostheses, obturator and dental implant but they still have some problems such as low corrosion resistance in oral environments. Purpose: To increase the corrosion resistance of dental magnetic materials, surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels. Materials and methods : Surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels, and then three kinds of electrochemical corrosion test were performed in 0.9% NaCl solution; potentiodynamic, potentiostatic, and electrochemical impedance test. From this study, corrosion behavior, amount of elements released, mean average surface roughness values, the changing of retention force, and magnetic force values were measured comparing with control group of non-coated magnetic materials. Results: The values of surface roughness of TiN coated Sm-Co and TiN coated Nd-Fe-B based magnetic materials were lower than those of non coated Sm-Co and Nd-Fe-B alloy. From results of potentiodynamic test, the passive current density of TiN coated Sm-Co alloy were smaller than those of TiN coated Nd-Fe-B alloy and non coated alloys in 0.9% NaCl solution. From results of potentiostatic and electrochemical impedance test, the surface stability of the TiN coated Sm-Co alloy was more drastically increased than that of the TiN coated Nd-Fe-B alloy and non-coated alloy. The retention and magnetic force after and before corrosion test did not change in the case of TiN coated magnetic alloy sealed with stainless steel. Conclusion: It is considered that the corrosion problem and improvement for surface stability of dental magnetic materials could be solved by ion plating with TiN on the surface of dental magnetic materials and by sealing with stainless steels.

A Study on the Magnetic Properties of Amorphous Fe-Co-RE-B (RE=Nd, Sm, Gd, Tb) Alloys (비정질 Fe-Co-Re-B(RE=Nd, Sm, Gd, Tb) 합금의 자기적 성질)

  • 김경섭;유성초;김창식;김종오
    • Journal of the Korean Magnetics Society
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    • v.1 no.2
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    • pp.55-59
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    • 1991
  • The temperature-dependent magnetization curves of amorphous Fe-Co-(Nd, Sm, Gd, Tb)-B alloys were measured using a vibrating sample magnetometer from 77 K up to 900 K. The spin wave stiffness constants and the range of the exchange interaction were calculated from the saturation magnetization values at 0 K. Curie temperatures and the Bloch coefficients estimated from the saturation magnetization curves. The low temperature dependence of magnetization is in good agreement with Bloch relation, $M_{s}(T)=M_{s}(O)(1-BT^{3/2}-CT^{5/2})$. The spin wave stiffness constant and the range of exchange interaction are decreased by substitution of heavy rare earth (Tb, Gd).

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Effect of Process Parameters on Microstructure and Magnetic Properties of Sm-Co Alloy Powder Prepared by High Energy Ball Milling (고에너지 볼밀링된 Sm-Co 합금 분말의 미세조직 및 자성특성에 미치는 공정변수의 영향)

  • Kim, Bo-Sik;Chang, Si-Young
    • Journal of Powder Materials
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    • v.17 no.2
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    • pp.130-135
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    • 2010
  • Sm-16.7wt%Co alloy powders were prepared by high energy ball milling under the conditions of various milling time and the content of process control agent (PCA), and their microstructure and magnetic properties were investigated to establish optimum processing conditions. The initial powders employed showed irregular shape and had a size ranging from 5 to $110\;{\mu}m$. After milling for 5 h, the shape of powders changed to round shape and their mean powder size was approximately $5\;{\mu}m$, which consisted of the agglomerated nano-sized particles with 15 nm in diameter. The coercivity was reduced with increasing the milling time, whereas the saturation magnetization increased. As the content of PCA increased, the powder size minutely decreased to approximately $7\;{\mu}m$ at the PCA content of 10 wt%. The XRD patterns showed that the main diffraction peaks disappeared apparently after milling, indicating the formation of amorphous structure. The measured values of coercivity were almost unchanged with increasing the content of PCA.

Study on the Optimization of Reduction Conditions for Samarium-Cobalt Nanofiber Preparation (사마륨-코발트 자성 섬유 제조를 위한 환원 거동 연구 및 환원-확산 공정의 최적화)

  • Lee, Jimin;Kim, Jongryoul;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.26 no.4
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    • pp.334-339
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    • 2019
  • To meet the current demand in the fields of permanent magnets for achieving a high energy density, it is imperative to prepare nano-to-microscale rare-earth-based magnets with well-defined microstructures, controlled homogeneity, and magnetic characteristics via a bottom-up approach. Here, on the basis of a microstructural study and qualitative magnetic measurements, optimized reduction conditions for the preparation of nanostructured Sm-Co magnets are proposed, and the elucidation of the reduction-diffusion behavior in the binary phase system is clearly manifested. In addition, we have investigated the microstructural, crystallographic, and magnetic properties of the Sm-Co magnets prepared under different reduction conditions, that is, $H_2$ gas, calcium, and calcium hydride. This work provides a potential approach to prepare high-quality Sm-Co-based nanofibers, and moreover, it can be extended to the experimental design of other magnetic alloys.

SmBCO superconducting tape fabricated using co-evaporation method on Ni-W substrate (Ni-W 기판 위에 동시증발법으로 제조한 SmBCO 초전도선재)

  • Oh S.S.;Kim H.S.;Ha H.S.;Ko R.K.;Song K.J.;Ha D.W.;Lee N.J.;Yang J.S.;Kim T.H.;Jeong Y.H.;Youm D.
    • Progress in Superconductivity and Cryogenics
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    • v.8 no.3
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    • pp.9-12
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    • 2006
  • Batch type co-evaporation EDDC (Evaporation using Drum in Dual Chambers) system was recently manufactured to fabricate 100m - long SmBCO superconducting coated conductor. As a preliminary study before the fabrication of long tape. short CC samples have been fabricated using the EDDC system and their crystal texture and $I_c$ properties were investigated. $1.2 {\mu}m$-thick SmBCO layers were deposited on $CeO_2/YSZ/CeO_2$ buffered Ni-W tapes. $I_c$ of 128A/cm-w and corresponding $J_c$ of $1.1 MA/cm^2$ at 77K in self-field were obtained for SmBCO CC tape. In-field property of SmBCO CC was confirmed to be better than that of YBCO deposited by PLD.