Trichloroethylene(TCE) is the organic compound which is used variously at the industrial areas. It contaminates soils and groundwater by leaked storage tank, careless treatment in field and the effluent from waste landfills. This study was carried out to identify adsorptive behavior of TCE by soil. Batch experiments were conducted at different soil-organic matter content and lime treatment to determine Freundlich isothermal adsorption equation constant, k and n, for TCE. Sewage sludge cake was applied to make different soil-organic matter content with the level of Oton/ha(S1), 50ton/ha(S2), 100ton/ha(S3). Lime(calcium hydroxide) was treated with the level of 2ton/ha, 4ton/ha, 6ton/ha, 10ton/ha. Freundlich isothermal adsorption equations obtained from experiment with sewage sludge cake were as follows (on condition that the level of TCE applied to soil ranged from 0.5ng/g soil to 2.5 ng/g soil.) : S1 :x/m = 0.393 $C^2$, S2 : x/m = 0.436 $C^2$, S3 : x/m = 0.636 $C^2$Value of k was increased in higher order of 51, 52, 53 with increased level of sewage sludge cake application. From this results, soil which was applied higher level of sewage sludge cake had a good ability on TCE adsorption. With increased the level of lime application, pH of the soil was increased and the ability of the soil in TCE adsorption was decreased.
Journal of Korean Society of Environmental Engineers
/
v.28
no.11
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pp.1154-1161
/
2006
Air drying equipment was built as a device for reduction of dewatered cake from wastewater and waterworks sludge and to reproduce it by reusable matter. Dewatered cake was supplied into the air drying equipment which operated by air velocity of 80 m/sec, air rate 30 $m^3/min$ and air temperature of $40^{\circ}C$, and dried to produce the dried powder. The air drying equipment was composed of the air ejector which made high-speed fluid field, and cyclone which made circling fluid field. Dewatered cake was crushed at the high-speed zone as first step, and formed into dried powder of sphere shape by the collision between particles at the circling fluid zone.. Wastewater sludge with water content of 82.5 wt% was supplied 1.0 kg/min into air drying equipment and produced the dried powder which had the water content of 62.3 wt% and mass median diameter of 2.4 mm after process. At that time, it was analyzed that water removal rate was 0.1 $H_2O{\Delta}kg/min{\cdot}DS$ kg and air consumption was 170 $m^3/DS$ kg. Under same experimental conditions, when waterworks sludge was dried, water content of dried powder decrease to 47.5 wt% and mass median diameter decrease 2.1 mm and water removal rate increase 0.13 $H_2O{\Delta}kg/min{\cdot}DS$ kg. Air consumption increase 180 $m^3/DS$ kg with comparison to the results of wastewater sludge. Therefore, this technology was evaluated that drying the dewatered cake of waterworks sludge was more efficient than wastewater sludge, and also economical sludge handling technology due to drying the cake by only air.
The aim of this study is to investigate the membrane fouling in a thermophilic membrane bioreactor (TMBR) operated different sludge retention times (SRTs). For this purpose, TMBR was operated at four different SRTs (10, 30, 60 and 100 days). Specific cake resistance (${\alpha}$), cake resistance, gel resistance, total resistance, MFI (modified fouling index) and FDR (flux decrease ratio) were calculated for all SRTs. It was observed that flux in the membrane increases with rising SRT although the sludge concentrations in the TMBR increased. The steady state flux was found to be 31.78; 34.70; 39.60 and 43.70 LMH ($Liter/m^2/h$) for the SRTs of 10, 30, 60 and 100 days respectively. The concentrations of extracellular polymeric substance (EPS) and soluble microbial product (SMP) decreased with increasing SRT. The membrane fouling rate was higher at shorter SRT and the highest fouling rate appeared at an SRT of 10 d. Both the sludge cake layer and gel layer had contribution to the fouling resistance, but the gel layer resistance value was dominant in all SRTs.
Industrial and municipal wastewater treatment plants produce large amounts of sludge cakes for final disposal. This problem is an inevitable drawback inherent to the activated sludge process. Both the reduction of the amount of sludge produced and improvement of its dewaterability are presently very important issue also in Korea. So many pre-treatment processes have been developed in order to improve sludge dewatering efficiency. In this study the effects of hydrogen peroxide and paper sludge mixing processes were considered as reasonable alternatives to enhance sludge dewaterability. The CST of sludge was significantly decreased, and dewaterability improved by hydrogen peroxide oxidation treatment. The optimum dosage of hydrogen peroxide was proved to be 10mg/g-TS (when TS of sludge was 2%) with the conditions of pH 4 and only 1~2 minutes of reaction time. The mixing of paper sludge with sewage sludge was turned out to be very effective in reduction of sludge cake; 30% of sludge cake reduction was accomplished. Optimum mixing ratio of paper sludge was about 30%(v/v). This process also could save 25% of polymer to be required. These two alternatives are somewhat realistic, but it was concluded that paper sludge mixing process will be the best choice.
Journal of Korean Society of Environmental Engineers
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v.27
no.5
/
pp.525-534
/
2005
A column experiment was performed to investigate the influence of the sludge cake development on the riverbed and the hydraulic gradient imposed by the drawdown at the well on the filtrate quality in order to offer a guideline in the design and operation of the riverbed filtration. Results show that the sludge cake on the riverbed plays an important role in the removal of the organic matter. Under the conditions of this study the COD removal rate increased from 17% to 50% along with the sludge cake development, which was equivalent to the BCOD removal of 22% and 67%, respectively. The active removal of the organic matter took place in the sludge cake and the upper 40 cm of the riverbed. As the flow rate increased owing to the increase in the head difference imposed on the column, the slope of the COD profile near the column inlet decreased, however, the profiles converged in about 40 cm from the inlet. In 10 days of sludge cake formation the dissolved oxygen was depleted at the depth of 70 cm, which suggests the denitrification can take place beyond the depth. This depth was further reduced to $20{\sim}40\; cm$ as the sludge cake developed. From this study the removal of organic matter can be expected through the riverbed filtration even with the depth of as shallow as 3 m, which is frequently met in Korea, while the removal of nitrogen through denitrification is not expected to be active under the condition.
Kim, Jahyun;Kim, Seogku;Hwang, Injoo;Ahn, Jaehwan;Kang, Sungwon;Lee, Wontae;Lim, Junhyuk;Lee, Jeakun;Lee, Taeyoon
Journal of the Korean GEO-environmental Society
/
v.15
no.9
/
pp.5-12
/
2014
Anaerobic digestion was investigated for the stabilization of sludge, decrease of volatile solids, production of biogas for wastewater sludge. In this study, total solids and volatile solids, elemental analysis were conducted to determine characteristics of various types of sludges and investigate the feasibility of biogas production of Municipal Wastewater Sludge (MWS), Industrial Wastewater Sludge (IWS), mixed sludge (Mix), and Municipal Wastewater Sludg Cake (MWSC). Total solids, volatile solids, and C/N ratio were determined in the range of 11.2~20.6 %, 62.1~83.1 % of TS and 4.96~8.33 %. Using the biochemical methane potential (BMP test), mixed sludge and wastewater sludge finished the methane production within approximately 20 day and 16~17 day. Sludge cake finished within 10 day. Mixed sludge produced 395.5 mL $CH_4$ per g of Volatile Solid (VS) and resulted in the highest methane production. For carbon dioxide production, five sludges had similar value of accumulated carbon dioxide production except for sludge cake.
This study was focused on the manufacturing method of a dewatering aid, which would reduce the water content of the sludge cake by enhancing the dewaterability of sewage sludge. The pretreatment technology for sludge by using radiation and among diverse discarded resources were starfish selected as the material to manufacture the dewatering aid. Starfish went through the process of washing, drying, and pulverizing. The starfish powder made in this process was applied to the digested sludge generated at the sewage treatment plant of D City, and its effects were investigated. The starfish powder that was 300 ${\mu}m$ in particle size was added to the irradiated digested sludge. After the application of the condensation process, the sludge with the starfish powder added was dewatered using the belt press and centrifuge, which were the traditional pressure dewatering devices. As the result, it reduced the water content of the sludge 20% higher than the dewatered cake with no dewatering aid added and irradiation. When the powder was added, it contributed to less use of the coagulant added. The more irradiation dose, the lower water content did the dewatered cake have and the more coagulant was needed for condensation, which seems to be a disadvantage that can be compensated for by the starfish dewatering aid. A small-scaled treatment of the study to a radiation technology and dewatering aid using a discarded resource confirmed the potential of dewaterability. Based on the results saying that the dewatering aid and radiation technology can improve dewatering effects using the traditional dewatering devices, this pretreatment technology will be expected to be applied to sewage treatment plants.
The effects of hydrogen peroxide treatment on the reduction of waterworks sludge were investigated in this study. Sludge treated by peroxidation $H_2O_2$ oxidation) was dewatered using a pressure filter at 3atm. It was observed that $H_2O_2$ treatment at the acidic condition significantly reduce both cake water content and specific resistance to filtration (SRF), indicating the enhancement of dewaterability and filterability. The filterability by hydrogen peroxide treatment at pH 3.5 was better than acidic treatment and became comparable with polymer conditioning. The sludge filterability evaluated by SRF was optimal at a dose 2ml $H_2O_2$/sludge($0.02g\;H_2O_2/gTS$) after adjusting of pH to 3.5. The $H_2O_2$ oxidation at pH 3.5 also produced even more dewatered cake when compared with polymer conditioning. The reduction rate of sludge mass at an optimal condition showed 34% compared with untreated sludge. The effects of peroxidation on sludge properties including zeta potential, bound water and particle size were also evaluated. Peroxidation at the acidic condition reduced both bound water and zeta potential. By $H_2O_2$ combined with sulfuric acid leached iron caused Fenton's reaction, which showed a potential to significantly reduce the amount of solids mass and to produce more compact cake with higher filterability.
Journal of Korea Technical Association of The Pulp and Paper Industry
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v.36
no.4
s.107
/
pp.77-82
/
2004
Expression-deliquoring tests using three types of paper sludges (tissue, newsprint, and paperboard) as deliquoring agent were carried out in order to investigate the effects of sludge dosage and pressure on the expression-deliquoring of slurry. The addition of deliquoring agent causes expression-deliquoring of slurry to be faster than would be the case without the deliquoring agent. In case of the tissue sludge, the highest compression rate was achieved when $5\%$ of deliquoring agent was added, while in cases of the newsprint and the paperboard sludge, $7\%$. Compression rate was increased as pressure increases. Porosity was decreased as pressure increases. The lowest porosity was observed when $5\%$ of tissue sludge was added. When compared the weight of cake where deliquoring agent was not added and the weight of cake that was fastest expression-deliquoring, there was about $17.5\%$ of the weight reduction
Jeong, Soo Il;Sohn, In Shik;Jeong, Seung Hyun;Jeong, Byung Gon
Journal of Korean Society on Water Environment
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v.26
no.2
/
pp.225-230
/
2010
Dumping of waste sludge to ocean will be prohibited in Jananuary, 2012. Thus, various methods of sludge recycling are intensively studied. To present new way of sewage sludge recycling method, feasibility of making porous biological support media was investigated. Porous biological support media was made of sludge cake from sewage treatment plant and loess. They were mixed in varying ratio and burnt in high temperature to ensure sufficient mechanical strength. It was evaluated that about 67% of sewage sludge were ignitible. The ignitible portion play an important role in making pore in biomedia during ignition process. It was evaluated that optimum mixing ratio of loess to sludge cake was 25% in respect of compressive strength. In results of observation using scanning electron microscope (SEM), inner structure of biomedia become simple when the contents of loess are increased.
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