• The Korean Journal of Quaternary Research
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• v.5 no.1
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• pp.15-31
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• 1991

A total of 90 surface sediment samples, collected from the continental margin area bordering east and southeast coast of Korea, were subject to the geochemical analyses with the aim of filling the gap in our knowledge of this environment. The analyzed items included the major elements (Al, Fe, Mg, Ca, K, Na, p and Mn), organic carbon, and some trace metals (Ba, Co, Cu, Sr and Zn). The sediment grain-size exerted a predominant influence on the contents of most elements, with the exceptions of Ca, K, Sr and Ba. The Ca and Sr contents, being closely interrelated each other, were mainly controlled by the calcium carbonate content. The K content, on the other hand, appeared to be influenced by both illite and feldspar. The Ba content showed a certain relationship with that of K, suggesting a common source of these two elements; potassium feldspar. The R-mode factor analysis result also reaffirmed the above-mentioned controlling factors on the sediment geochemistry. The grain-size dependency of trace metals obscures their areal distribution pattern from the total contents. However, with the metal/aluminum ratios we could differentiate the subtle difference in the metal enrichment. Hence, sediments of the southern coastal area appear to receive some anthropogenic inputs of metals, though the effect is still negligible.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.5
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• pp.525-534
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• 2005

A column experiment was performed to investigate the influence of the sludge cake development on the riverbed and the hydraulic gradient imposed by the drawdown at the well on the filtrate quality in order to offer a guideline in the design and operation of the riverbed filtration. Results show that the sludge cake on the riverbed plays an important role in the removal of the organic matter. Under the conditions of this study the COD removal rate increased from 17% to 50% along with the sludge cake development, which was equivalent to the BCOD removal of 22% and 67%, respectively. The active removal of the organic matter took place in the sludge cake and the upper 40 cm of the riverbed. As the flow rate increased owing to the increase in the head difference imposed on the column, the slope of the COD profile near the column inlet decreased, however, the profiles converged in about 40 cm from the inlet. In 10 days of sludge cake formation the dissolved oxygen was depleted at the depth of 70 cm, which suggests the denitrification can take place beyond the depth. This depth was further reduced to $20{\sim}40\; cm$ as the sludge cake developed. From this study the removal of organic matter can be expected through the riverbed filtration even with the depth of as shallow as 3 m, which is frequently met in Korea, while the removal of nitrogen through denitrification is not expected to be active under the condition.

• Journal of the Korean Electrochemical Society
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• v.19 no.2
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• pp.39-44
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• 2016

Oxygen reduction reaction in the fuel cell (ORR) plays a dominant role in the overall reaction. In addition, the low compatibility between the membrane and the binder consisted of different materials, greatly reduces the efficiency of the fuel cell performance. In view of these two problems, geometrically modified copolymers with 9.9_Bis (4-hydroxyphenyl) were synthesized via condensation reaction instead of conventional biphenol and were adopted as hydrocarbon ionomer binders. By utilizing these binders, two kinds of MEAs using fluorinated Nafion membrane and hydrocarbon based membrane were manufactured in order to electrochemical performance evaluation. With current-voltage curves, there was no significant difference in the 0.6 V when two types of membrane were applied. Also, tafel slope became considerably lower as compared to the Nafion membrane. Thus, it is determined that the new hydrocarbon binder is expected to contribute the improvement in performance of fuel cells.

• Journal of the Korean Geotechnical Society
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• v.32 no.11
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• pp.43-50
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• 2016

A reinforcement is required to ensure the structural safety in case of railway embankment excavation under railway load. A large diameter soil nailing with concrete wall is applied as the reinforcement method instead of the conventional soil nailing system. In this study, a series of 3 dimensional numerical analyses are performed to investigate the optimum reinforcement considering 15 different conditions based on the length, lateral spacing, diameter, and inclination of the reinforcement. The interface between soil nail and perimetric grout is considered by means of cohesion, stiffness and perimeter of the grout. 0.3 m of reinforcement diameter is assessed as the most appropriate based on the economical viewpoint though ground displacement decreases with the increase of diameter, however the difference of displacement is negligible between 0.4 m and 0.3 m of diameter. Surface settlement, lateral displacement of wall, and stress of reinforcement are calculated and economic viewpoint to reinforce embankment considered. Consequently, the optimum reinforcement conditions considering those factors are evaluated as 3 m in length, 0.3 m in diameter, 1.5 m in lateral spacing, and 10 degree of inclination angle in the case of 3 m of excavation depth. Additionally, inclined potential failure surface occurs with approximately 60 degrees from the end of nails and the surface settlement and wall lateral displacement are restrained successfully by the large diameter soil nailing, based on the result of shear strain rate.

• Korean Journal of Environment and Ecology
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• v.12 no.1
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• pp.78-90
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• 1998

An objective of this study was to provide database for the planting disign of buffer green space. Types, planting structure, and effect of vuffer green space were investigated in five housing complexes of newtown of metropolitan area, Korea. Buffer green space in the study sites were constructed as mounding, slope, and plate. The number of species was found 20 tree and sub-tree species(10 evergreen and 20 deciduous species ) and 13 shrub species. These species were planted in one-storyed planting structure and there was no difference with ornamental species in the urban parks. Effect of sound proof by the buffer green space was recognized but sound level in four types among the seven types was observed above standard sound level for housing complex(65dB). Effect of sound proof was especially most effective in the mounding type. It was found that planting density and index of plant crown volume were mot satisfied to the function of buffer green space because of lower density and crown volume than natural vegetation per unit. Based on these results, this study suggested that buffer green space is desirable to be developed in the mounding type over two meters height with multi-layer planting model. In addition, there is needed to consider vegetation structure of natural forest around the developing site.

• Korean Journal of Environment and Ecology
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• v.23 no.4
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• pp.346-352
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• 2009

This study was conducted in order to provide as a basic materials of sea cliff vegetation structure through distribution related with the landform and growth pattern of mixed growth plants by ordination method in the Peucedanum japonicum community of Korea. The mixed growth plants of frequency over 10% growth with Peucedanum japonicum community of sea cliff was investigated as a total 26 species, and the frequency of appearing plants was the highest in the Aster spathulifolius(55.7%). Growing pattern of mixed growth plants was a difference by the landform factors as such the inland side, coastline side, flat and slope. Growing pattern was classified into typicality type, one-sided type and complex type. Growing pattern of the typicality type was good distribution in total landform factors, the one-sided type was good distribution in 1 landform factor and the complex type was good distribution in 2 landform factors. In growing pattern of mixed growth plants with Peucedanum japonicum, Artemisia capillaris and Sedum oryzifolium was typicality type, Elymus dahuricus and Artemisia princeps was one-sided type, and Aster spathulifolius, Miscanthus sinensis, Calystegia soldanella and Lysimachia mauritiana was complex type. In total plants of mixed growth, growing pattern of 16 species of 61.5% was good as complex type.

• Bulletin of the Korean Chemical Society
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• v.30 no.11
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• pp.2691-2696
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• 2009

Effects of representative group II and transition metal ions on the stability of the $poly(dA){\cdot}[poly(dT)]_2$ triplex were investigated by the van’t Hoff plot constructed from a thermal melting curve. The transition, $poly(dA){\cdot}[poly(dT)]_2\;{\rightarrow}\;poly(dA){\cdot}poly(dT)\;+\;poly(dT)$, was non-spontaneous with a positive Gibb’s free energy, endothermic (${\Delta}H^{\circ}$ > 0), and had a favorable entropy change (${\Delta}S^{\circ}$ > 0), as seen from the negative slope and positive y-intercept in the van’t Hoff plot. Therefore, the transition is driven by entropy change. The $Mg^{2+}$ ion was the most effective at stabilization of the triplex, with the effect decreasing in the order of $Mg^{2+}\;>\;Ca^{2+}\;>\;Sr^{2+}\;>\;Ba^{2+}$. A similar stabilization effect was found for the duplex to single strand transition: $poly(dA){\cdot}poly(dT)\;+\;poly(dT)\;→\;poly(dA)\;+\;2poly(dT)$, with a larger positive free energy. The transition metal ions, namely $Ni_{2+},\;Cu_{2+},\;and\;Zn_{2+}$, did not exhibit any effect on triplex stabilization, while showing little effect on duplex stabilization. The different effects on triplex stabilization between group II metal ions and the transition metal ions may be attributed to their difference in binding to DNA; transition metals are known to coordinate with DNA components, including phosphate groups, while group II metal ions conceivably bind DNA via electrostatic interactions. The $Cd_{2+}$ ion was an exception, effectively stabilizing the triplex and melting temperature of the third strand dissociation was higher than that observed in the presence of $Mg_{2+}$, even though it is in the same group with $Zn_{2+}$. The detailed behavior of the $Cd_{2+}$ ion is currently under investigation.

• Journal of the Korea Concrete Institute
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• v.13 no.4
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• pp.336-345
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• 2001

The construction of underwater structures has been increased, but underwater concrete hassome problems of quality deterioration and contamination around in-situ of civil and architecture; therefore, new materials and methods for them are demanded. In this paper in-situ application of underwater antiwashout concrete which is manufactured for trio purpose of not only decreasing suspended solids and the heat of hydration but also increasing long term strength was studied. In the case of mock-up test(Ⅰ), when underwater antiwashout concrete, whose slump flow was 58 cm, was placed in the mock-up test at a speed of 24 ㎥/hr, it took about a minute to flow to the side wall, and the surface was maintained at horizontal level. In this case, compressive strength of the core specimens in each section was higher than the standard design compressive strength of 240 kgf/㎠. In the case of mock-up test(II), pH value and suspended solids of high strength underwater antiwashout concrete were 10.0∼11.0 and 51 mg/ℓ at 30 minutes later, initial and final setting time were about 30, 37 hr, and the slump flow of that was 53$\pm$2 cm. In the placement at a speed of 27 ㎥/hr, there was no large difference in flowing velocity, with or without reinforcement and flowing slope was maintained at horizontal level. In this case, compressive strength and elastic modulus of the core specimens somewhat decreased as flowing distance was far : however, those of central area showed the highest value.

• Journal of Korea Water Resources Association
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• v.50 no.11
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• pp.725-734
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• 2017

The main purpose of this study is to analyze runoff aggregation structure and energy expenditure pattern of Choyang creek basin within the framework of power law distribution. To this end geomorphologic factors of every point in the basin of interest, which define tractive force and stream power as well as drainage area, are extracted based on GIS, and their complementary cumulative distributions are graphically analyzed through fitting them to power law distribution. The results indicate that three distinct behavioral regimes are observed from the complementary cumulative distributions of three geomorphogic factors. Based on the parameter estimation of power law distribution by maximum likelihood drainage area and stream power can be judged as scale invariance factor without finite scale while tractive force as scale dependence factor with finite scale. Furthermore, it is judged that tractive force would not follow power law distribution because it shows limited complex system behaviors only within the small extent of scale. The exponent of power law distribution for drainage area obtained in this study by maximum likelihood is larger than the previous researches due to the difference of parameter estimation methodologies. And the exponent for stream power is smaller than the previous researches due to the scaling property of channel slope for the basin of interest.

• Korean Journal of Soil Science and Fertilizer
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• v.37 no.6
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• pp.383-387
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• 2004

Effects of oyster shell powder as a liming material were investigated in an apple orchard. Soil texture of the apple orchard was silty clay loam (Upyeong series with 7% of slope) and topsoil pH was 5.6. Treatments of 1,590 kg oyster shell powder $ha^{-1}$ and calcium-magnesium carbonate as much as oyster shell powder were included in the experiment. With treatments of oyster shell powder and calcium-magnesium carbonate, the length, number and diameter of new branches and the diameter of main, secondary and side branches increased in comparison with control. With oyster shell powder application, soil pH increased from 5.6 to 6.8 at the harvest. In addition, it increased exchangeable Ca from 2.6 to $4.2cmol_c\;kg^{-1}$. But it didn't make any difference in chlorophyll, sugar and malic acid contents. The apple weight per fruit of oyster shell powder application was 9 g more than that of control. Apple yield was highest ($37,000kg\;ha^{-1}$) in the oyster shell powder treatment, and the yield increase was significantly different at 5% level LSD. We concluded that the oyster shell powder can be an alternative of lime and effective to restore soil nutrient balance in apple orchard soil.