• Proceedings of the Korean Nuclear Society Conference
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• 1998.10a
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• pp.180-180
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• 1998

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.3
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• pp.124-128
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• 2013

In this research, cubic zirconia is synthesized with a refined CaO from shells as a stabilizer through Skull melting method. The proper process time and concentration are defined by Hydration reaction to produce the refined CaO after two different treatments using 0.1 mol% of HCl respectively with Cockle shell. The highest purity of CaO is reached when the shell is immersed in 1 mol% HCl. In Hydration reaction step, the pure $Ca(OH)_2$ is produced at $45^{\circ}C$ for 24 hours. The highest purity of CaO is measured when the $Ca(OH)_2$ is treated by heat at $1200^{\circ}C$ for 5 hours. The single crystals are grown through Skull melting method by adding the different contents of the refined CaO from 10 mol% to 30 mol% into $ZrO_2$. The frequency of High-frequency oscillator used for Skull melting method is 3.4 MHz. The descending speed of the single crystal is 3 mm/hour. The grown length of the single crystal is 4 cm. As a result of this study, 15 mol% of CaO has the best crystallinity.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.13 no.5
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• pp.205-210
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• 2003

Alexandrite-like cubic zirconia single crystals were grown by skull melting method. The R.F. generator (output power is 35 ㎾) used for skull melting was operated at 2 MHz. The grown crystals were doped with up to 1 or 1.5 wt% and 0.5 or 1 wt% of rare earth metal ion (Pr, Nd) on$ ZrO_2-Y_2O_3$ (12 mol%). The grown crystals were cut for slice (0.25 mm) and round brilliant (12 mm in diameter). The cut stones were heat treated in air and nitrogen at $1000^{\circ}C$ for 2 hours and their optical absorption spectra ($\lambda$ = 400∼700 nm) data were obtained.

• Journal of the Korean Ceramic Society
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• v.39 no.2
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• pp.190-193
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• 2002

3mol% $Y_2O_3$ Partially-Stabilized Zirconia single Crystals (PSZCs) containing a small quantity (<0.5%) of rare-earth oxides ($CeO_2,\;Tb_2O_3$) were prepared by using a direct high-frequency skull melting technique to evaluate hydrothermal stability in an autoclave. Pole exhibited no $t{\rightarrow}m$ phase transformation during aging for 5h at temperatures from 150 to 250$^{\circ}C$ and 4MPa water vapor pressure in an autoclave, resulting in excellent hydrothermal stability.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.16 no.4
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• pp.141-148
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• 2006

Skull melting method can be a good candidate for growing oxide single crystals with high quality and for mass production because of its low production costs and high yield through recycling of crust. In this study, rutile single crystals were frown by the skull melting method and ingot characteristics with the variation of different growth conditions has been investigated. Conditions for high quality rutile ingot growth were used for producing cold-crucible size of ${\Phi}12cm{\times}H14cm$, capacity of 3000 pF tank condenser, work frequency of 2.84 MHz, melt-dwelling time of 9hrs and growing speed of 2 mm/h.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.4 no.2
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• pp.148-156
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• 1994

Three composition in the system of $YO_{1.5}-BaO-CuO$ were grown using a cold crucible (skull) melting technique with a 50 kW R.F. induction generator operating at 4 MHz as the power source. The starting materials were prepared by conventional ceramic powder processing methods, loaded into the skull, and melted at about $1200^{\circ}C$. For this study, compositions near the $YBa_2Cu_3O_X$ region were selected. The growth rates used ranged from 4 cm/hr to 0.25 cm/hr. The relation between the microstructures and the starting composition of each ingot was determined using metallograph, X-ray diffraction, and energy dispersive X-ray analysis. Both $YBa_2Cu_3O_X$ and $Y_2BaCuO_5$ needle-shaped crystals, aligned with the growth direction, were formed in the $CuO-BaCuO_2$ eutectic matrix of the $YBa_2Cu_7O_x and YBa_5Cu_{11}O_x$ ingot.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.14 no.6
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• pp.262-266
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• 2004

Rutile single crystals were grown by the skull melting method. Ti metal ring was used for initial RF induction heating. The grown crystals were cut into wafer of 5.5 mm diameter and 1mm thickness. The wafers were annealed in air at $1300^{\circ}C$ up to 15 hours and their transmittance spectra $(\lambda= 200~25000 nm)$ were obtained.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.17 no.3
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• pp.108-112
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• 2007

Cubic Zirconia single crystals having changeable color with light source were grown by skull melting method. Strong absorption of yellow color region light by Co and Nd and the absorption in violet color region by Fe led the color change from blue-green to red-purple with the light source from fluorescent to incandescent lamp. Color of crystals varied not only by the dopants but yttria contents and the conditions far heat treatment.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.1
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• pp.24-31
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• 2019

The current study demonstrates an efficient procedure to create ingots from $Al_2O_3$ powder using the skull melting method to use these ingots as a starting material in conventional methods for growing synthetic single-crystal sapphire. Dimension of the cold crucible was 24 cm in inner diameter and 30 cm in inner height, 15 kg of $Al_2O_3$ powder was completely melted within 1 h at an oscillation frequency of 2.75 MHz, maintained in the molten state for 3 h, and finally air-cooled. The areal density and components of the cooled ingot by parts were analyzed through scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS). The areal density and $Al_2O_3$ content of the ingot were related to the temperature distribution inside the cold crucible during high-frequency induction heating, and the area with high temperature was high tends to be high in areal density and purity.

• Journal of Korea Foundry Society
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• v.24 no.6
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• pp.314-322
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• 2004

The CaO crucible is expected to serve as a useful tool for melting Ti and its alloys due to its thermodynamic stability. However, tjere still remain problems that need to be resolved in the melting of Ti and its alloys to enable commerical use. The cause of the defects of Ti-6AI-4V alloy castings melted in the CaO crucible were examined and compared with induction skull melting. The key factors of the melting technique using the CaO crucible, affecting the quality of Ti-6AI-4V alloy castings, were investigated. Defects of the Ti-6AI-4V alloy castings are caused by the chemical reduction of CaO by Ti. Pressurizing with argon gas in a vacuum induction chamber is effective for reducing the defects. Preheating of the charged material in the crucible and quick pouring into a mold of lower temperature, just after melting down, are important for produsing sound Ti-6AI-4V castings.