• 한국화재소방학회논문지
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• 제31권6호
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• pp.8-15
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• 2017

화재발생 시에 대부분의 인명 피해는 연기에 의해 발생되는데, 최근 건축 내장재에서 차지하는 플라스틱의 양이 많아지며 발생되는 연기의 유독성이 점차적으로 증가되고 있다. 연기에 의한 인체피해의 상당부분은 흡입연기의 폐침전과 관련이 있으며, 연기입자의 크기분포는 폐침전 특성에 직접적인 영향을 미친다. 따라서 플라스틱 종류에 따른 연기입자의 크기별 발생량 검토는 폐침전에 의한 인체피해 연구에 필수적으로 요구된다. 최근의 목재와 폴리프로필렌(PP)에 대한 연기입자의 발생특성 연구에서 PP의 연기입자 크기분포 특성이 몇 가지 측면에서 목재와는 확연히 다르게 나타났다. 이에 따라, 본 연구에서는 다른 플라스틱들도 연기입자 크기분포에서 PP와 같은 특성을 보이는지 알아보기 위해서 대표적인 4가지 플라스틱(LDPE, PA66, PMMA, PVC)에 대하여 연기입자 크기분포 측정실험을 수행하였다. 특정 조건에서 연소생성물을 균일하게 생성하고 분석하기 위하여 ISO/TS 19700 기준에 따른 등속튜브연소로를 이용하여 연소로의 온도와 산소공급량에 따라 다양한 화재조건에서 연기입자를 균일하게 발생시키고, 정전저압 임팩터를 사용하여 연기입자의 크기에 따른 개수농도를 실시간으로 측정하였다. 실험 결과 4가지 플라스틱의 연기입자 크기분포 특성은 여러 측면에서 PP와 유사하며 목재와는 확연히 다르게 나타났다.

• 한국산업보건학회지
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• 제25권1호
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• pp.36-44
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• 2015

Objectives: This study aimed to elucidate the physicochemical properties of silica powder and airborne particles as by-products generated from fabrication processes to reduce unknown risk factors in the semiconductor manufacturing work environment. Materials and Methods: Sampling was conducted at 200 mm and 300 mm semiconductor wafer fabrication facilities. Thirty-two powder and airborne by-product samples, diffusion(10), chemical vapor deposition(10), chemical mechanical polishing(5), clean(5), etch process(2), were collected from inner chamber parts from process and 1st scrubber equipment during maintenance and process operation. The chemical composition, size, shape, and crystal structure of silica by-product particles were determined by using scanning electron microscopy and transmission electron microscopy techniques equipped with energy dispersive spectroscopy, and x-ray diffractometry. Results: All powder and airborne particle samples were composed of oxygen(O) and silicon(Si), which means silica particle. The by-product particles were nearly spherical $SiO_2$ and the particle size ranged 25 nm to $50{\mu}m$, and most of the particles were usually agglomerated within a particle size range from approximately 25 nm to 500 nm. In addition, the crystal structure of the silica powder particles was found to be an amorphous silica. Conclusions: The silica by-product particles generated from the semiconductor manufacturing processes are amorphous $SiO_2$, which is considered a less toxic form. These results should provide useful information for alternative strategies to improve the work environment and workers' health.

• 환경위생공학
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• 제17권2호
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• pp.11-17
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• 2002

Diesel particulate matter (DPM) is known to be one of the major harmful emissions produced by diesel engines. The majority of diesel particles are in the range of smaller than $I{\mu}\textrm{m}$. Because of their tiny volume, ultrafine diesel particles contribute very little to the total mass concentration which is currently regulated for automobile emissions. Diesel particles are known to have deleterious effects upon human health because they penetrate human respiratory tract and have negative effects on the health. The measurement of the number distribution of nanometer size particles (nanoparticles) in the diesel exhaust emission is important in order to evaluate their environmental and health impact, and to develop new types of diesel particulate filters. In this study, we directly sampled particulate matters emitted from a diesel truck mounted on the chassis dynamometer by a flow separator and dilution system, and measured the nanoparticles using two types of differential mobility analyzers combined with a Faraday cup electrometer (FCE) and a condensation particle counter (CPC). The particle size distributions were analyzed by changing engine operation condition, i.e. ratio of engine loading. The total number concentration of particles were increased with the engine loading ratio and the nanoparticles (less than 50nm) were affected by hydrocarbon (HC) concentration in the diesel exhaust.

• 한국대기환경학회지
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• 제15권5호
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• pp.575-586
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• 1999

The size-resolved number concentrations of aerosols ranging from 0.3 to 25 $mu extrm{m}$ were observed in Seoul and Anmyondo in the west coast of Korea during an Yellow Sand phenomenon in April 1998. Number size distributions of aerosols observed in both places are characterized by decrease in small particles of diameter less than 1${\mu}{\textrm}{m}$ and increase in large size between 1.35 and 10${\mu}{\textrm}{m}$ in heavy dust period. For particles in this size range, there was a good correlation between number concentrations observed in both places during the Yellow Sand episode. On the other hand, the number of small particles less than 0.82${\mu}{\textrm}{m}$ decreased, but the correlation between these particles in both places was enhanced during more intense dust period. The number of coarse particle larger than 10 ${\mu}{\textrm}{m}$ showed a distince diurnal variation without a significant change in amplitude, which was more visible in Seoul. It suggests that these coarse particles were more affected by local sources. Form these results, it was range of 1~10${\mu}{\textrm}{m}$ originated possibly from the dust source regions and the source signature depended on the degree of dust intensity.

• Nuclear Engineering and Technology
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• 제50권6호
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• pp.842-848
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• 2018

Motivated by reducing the uncertainties in quantification of debris bed coolability, this paper reports an experimental study on two-phase flow resistances and interfacial drag in packed porous beds. The experiments are performed on the DEBECO-LT (DEbris BEd COolability-Low Temperature) test facility which is constructed to investigate the adiabatic single and two phase flow in porous beds. The pressure drops are measured when air-water two phase flow passes through the porous beds packed with different size particles, and the effects of interfacial drag are studied especially. The results show that, for two phase flow through the beds packed with small size particles such as 1.5 mm and 2 mm spheres, the contribution of interfacial drag to the pressure drops is weak and ignorable, while the significant effects are conducted on the pressure drops of the beds with bigger size particles like 3 mm and 6 mm spheres, where the interfacial drag in beds with larger particles will result in a descent-ascent tendency in the pressure drop curves along with the fluid velocity, and the effect of interfacial drag should be considered in the debris coolability analysis models for beds with bigger size particles.

• 한국대기환경학회지
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• 제10권1호
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• pp.57-63
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• 1994

In order to comprehension of the behaviour of PAHs in air which is known as carcinogens and/or mutagens suspended Particulates in ambient air were collected by Anderson air sampler from 1992. 6 to 1993. 5 in Seoul. Ten species of PAHs( Phen, An, Fl, R, Py, BaAn, BaP, Chry, BeP, DiB(a, h)An, I123p) were analyzed to understand monthly variations of PAHs distribution of PAHs concentration according to particle size, and correlation between PAHs and independent charactierstics of PAHs The highest concentration of TSP was 155.58$\mu\textrm{g}$/㎥ in May and the lowest was 60$\mu\textrm{g}$/㎥ in August. Concentration of TSP was more affected by coarse particles in spring, otherwise which was more affected by fine particles in winter. According to results of anaylsis of samples that were collected by Anderson air sampler, concentration of PAHs was more high in winter than that in summer. In almost samples collected by Anderson air sampler, concentration of PAHs was more high in coarse particles than in fine particles, but BaP well known as carcinogenic matter had more high concentration in fine particles(56-97.5%) than that in coarse particles(2.5-46%). Correlation between concentrations of TSP and PAHs was more high in fine Particles than in coarse Particles. Both fine particles and coarse particles have negative correaltion with radiation.

• 한국세라믹학회지
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• 제50권6호
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• pp.434-438
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• 2013

Monodispersed 3Y-$ZrO_2$ spherical agglomerates were synthesized by thermal hydrolysis process followed by crystallization processes (hydrothermal treatment and calcination). The crystallization process affected the properties of the final particles, such as the primary particle size, the agglomeration state, and the fraction of $ZrO_2$ monoclinic phase. The hydrothermal treated spherical particles were porous microstructures (weak agglomerates) composed of small primary particles with a size of 14 nm, but the calcined spherical particles had a dense microstructure due to the hard aggregation between primary particles. While the calcined particles had a low green density due to the hard aggregation, hydrothermal treated ones were soft agglomerates and had a deflection point at 50 MPa due to the rearrangement of secondary spherical particles and the filling of the interstices with the primary particles. Finally, the green density of hydrothermally treated $ZrO_2$ particles was 58% at 200 MPa.

• 한국전산유체공학회지
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• 제18권2호
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• pp.93-98
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• 2013

In this paper, we reported the verification of numerical simulation approach for sedimentation of the multi-size particles in a container. The comparison between experimentally measured values and numerically evaluated values on settle down process of fully mixed mixture is carried out. In an attempt to represent the natural particle size distribution, various diameters of single particles are simulated and the results are compared with the outcome of the multi-size computation. When the empirical formula for mean particle size estimation is adopted to define the sediment diameter, computation and comparison are conducted.

• Asian-Australasian Journal of Animal Sciences
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• 제5권1호
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• pp.13-18
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• 1992

Three cattle, a sheep and a goat were slaughtered to determine the distribution of digesta particles and mean size of digesta particles. Aliquot samples of digesta in the diverse sites of the digestive tracts were fractionated by a wet sieving technique. Fractionated particles were analyzed by the magnetic grid analyzer system constructed by authors. Results showed that the proportion of particles in digesta was similar among the omasum, abomasums cecum, colon and rectum, but that for the reticulo-ruminal digesta was different from the others. The pattern of the mass base frequency distribution of particles was also similar in the post-ruminal digesta. Average Heywood's diameter (the diameter equivalent to that of a circle with equal area to a projected area of a given particle) was about 1.2 mm in the reticulo-ruminal digesta and decreased to 0.65 mm for cattle or to about 0.35 mm for sheep and goat in the omasal digesta. Average Heywood's diameter was about the same in the post-ruminal digesta. It is concluded that mean particle size and particle distribution in digesta of the rectum or feces reflect those in digesta of the omasum.

• 한국표면공학회지
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• 제38권1호
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• pp.37-43
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• 2005

Nanosized titanium-colloid particles were prepared by sol-gel method. The physical properties, such as thermal stability, crystallite size and crystallinity according to synthesis condition have been investigated by TEM, XRD, SEM, TGA and DTA. In addition, Zinc phosphating has been studied in order to compare the phosphating characterization of prepared nanosized titanium-colloid particles. The major phase of all the prepared titanium-colloid particles was an amorphous structure regardless of synthesis temperature and the structure was composed of phoshate complex and titanium. The micrographs of HR- TEM showed that nanosized titanium-colloid particles possessed a spherical morphology with a narrow size distribution. The crystallite size of the titanium-colloid particles synthesized at 80℃ was 4-5 nm and increased to 8-10 nm with an increase of synthesis temperature (150℃). In addition, the coating weight increased with an increase of temperature of phosphating solution and when the concentration of titanium-colloid was 2.0 g/l, the coating weight was 1.0 g/㎡.