• 한국세라믹학회지
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• 제42권12호
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• pp.808-815
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• 2005

[ $Bi_xCe_{l-x}O_{2-x/2}$ ](BD C : Bismuth Doped Ceria) powders with x = 0.1, 0.2, and 0.3 were synthesized using the Glycine Nitrate Process (GNP). They were then calcined at $500^{\circ}C$ for 2 hand sintered in a pellet or rod form at 900, 1000 or $1100^{\circ}C$ for 4 h for characterization as the alternative electrolyte material for intermediate temperature solid oxide fuel cells. The BDC powder consisted of a single phase of $CeO_2-Bi_2O_3$ solid solution in the as-synthesized state as well as in the as-calcined state with a mean powder size of 4.5nm in the former state and 6.5 - 10.1nm in the latter. On the contrary, the second phase of $\alpha-Bi_2O_3$ was observed to have been formed in the sinter with its amount increasing roughly with increasing temperature or $Bi_2O_3$ content. The BOC powder was superior in sinterability to other alternative electrolyte materials such as GDC, ScSZ, and LSGM with the minimum sintering temperature for a relative density of $95\%$ or larger as low as $1100^{\circ}C$. The ionic conductivity of BOC increased with $Bi_2O_3$ content and the maximum value of 0.119 S/cm was obtained at $800^{\circ}C$ for $Bi_{0.3}Ce_{0.7}O_{1.85}$.

• 대한기계학회논문집A
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• 제35권9호
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• pp.1035-1040
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• 2011

본 논문은 세라믹과 금속파우더를 이용한 복합소재를 플라즈마 용사 방식으로 개발한 결과를 수록하였다. 사용된 세라믹 파우더는 $Al_2O_3+40TiO_2$ 이고 입자 크기는 $20{\mu}m$, $Al_2O_398+$파우더의 입자 크기는 $45{\mu}m$를 사용하였다. $20{\mu}m$, $30{\mu}m$ 및 $50{\mu}m$ 금속필터 입자는 SIKA-R 20IS, 30IS 및 50IS(소결금속필터)을 사용 했으며, $75{\mu}m$ 금속필터 입자는 5 겹 소결메쉬 필터를 사용��다. 용사 공정으로 가공된 복합 필터는 세라믹 파우더의 종류, 크기 및 코팅 두께에 따라 성능의 차이를 보였으나, 전반적으로 필터링 가능 능력은 향상되었다.

• 한국세라믹학회지
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• 제37권4호
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• pp.395-401
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• 2000

In this study, we chose the basic composition which indicated the best electrical properties by change of x content(0, 0.05, 0.1, 0.15, 0.2, 0.25 mol respectively) in xPb(Mn1/3Sb2/3)O3-(1-x)Pb(Zr0.52Ti0.48)O3 ceramics. And we substituted Cd2+ for Pb2+ site, then observed the sintering behavior, microstructure and electrical propertties according to the various sintering temperature. The basic composition was the 0.05PMS-0.95PZt, and it showed single perovskite phase and excellent properties. In case of Cd2+ substitution, we were able to sinter at 90$0^{\circ}C$ which was lower than conventional sintering temperature(1200~130$0^{\circ}C$). Especially, when the 2mol% substituted PMS-PZT specimens were sintered at 90$0^{\circ}C$ for 2h, we obtained the p=7.6g/㎤, kp=56%, Qm=520 and made sure of a position of Cd2+ substitution by observing lattice parameter, phase transition temperature. From this results, we could infer that because Cd2+ substituted fro A-site, low temperature sintering of Cd2+ substituted PMS-PZT without any loss of electrical properties shows its applicability for the piezoelectric ceramic transformer.

• 한국세라믹학회지
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• 제44권7호
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• pp.343-348
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• 2007

Alumina/silver nanocomposites were fabricated using a soaking method through a sol-gel route to construct an intra-type nanostructure. The pulse electric-current sintering (PECS) technique was used to sinter the nanocomposites. Several specimens were annealed after sintering. The microstructure, mechanical properties, critical frontal process zone (FPZ) size, and thermo-mechanical properties of the nanocomposites were estimated. The relative densities of the specimens sintered at 1350 and $1450^{\circ}C$ were 95% and 99%, respectively. The maximum value of the three-point bending strength was found to be 780 MPa for the $2{\times}2{\times}10 mm$ specimen sintered at $1350^{\circ}C$. The fracture toughness of the specimen sintered at $1350^{\circ}C$ was measured to be $3.60 MPa{\cdot}m^{1/2}$ using the single-edge V-notched beam (SEVNB) technique. The fracture mode of the nanocomposites was transgranular, in contrast to the intergranular mode of monolithic alumina. The fracture morphology suggested that dislocations were generated around the silver nanoparticles dispersed within the alumina matrix. The specimens sintered at $1350^{\circ}C$ were annealed at $800^{\circ}C$ for 5 min, following which the maximum fracture strength became 810 MPa and the fracture toughness improved to $4.21 MPam^{1/2}$. The critical FPZ size was the largest for the specimen annealed at $800^{\circ}C$ for 5 min. Thermal conductivity of the alumina/silver nanocomposites sintered at $1350^{\circ}C$ was 38 W/mK at room temperature, which was higher than the value obtained with the law of mixture.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 추계학술대회 논문집
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• pp.280-280
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• 2007

Lead oxide-based ferroelectrics are the most widely used materials for piezoelectric actuators, sensors and transducers due to their excellent piezoelectric properties. Considering lead toxicity, there is great interest in developing lead-free piezoelectric materials, which are biocompatible and environmentally friendlier. Recently alkali oxide materials, including sodium - potassium niobate (NKN), have been given attention in view of their ultrasonic application and also as promising candidates for piezoelectric lead-free system. However, it is difficult to sinter such NKN-based materials via conventional sintering process. In this reason, many researchers have investigated hot press, hot isostatic press or spark-plasma sintering of NKN-based ceramics. In this study, as candidates for lead-free piezoelectric materials, dense (Na,K,Li)(Nb,Sb)$O_3$ systems were developed by conventional sintering process. The microstructures and piezoelectric properties of the (Na,K,Li)(Nb,Sb)$O_3$ systems were investigated as a function of variable compositions. The excellent piezoelectric and electromechanical properties indicate that this system is potentially good candidate as lead-free material for a wide range of electro-mechanical transducer applications.

• Nuclear Engineering and Technology
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• 제46권1호
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• pp.117-124
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• 2014

The effect of various process variables on the powder properties of recycled $U_3O_8$ from MnO-$Al_2O_3$ doped large grain $UO_2$ pellets and the effect of those recycled $U_3O_8$ powders on the sintered density and grain size of MnO-$Al_2O_3$ doped large grain $UO_2$ pellets have been investigated. The evolution of morphology, size, and BET surface area of the recycled $U_3O_8$ powders according to the respective variation of the thermo-mechanical treatment variables of oxidation temperature, powder milling, and sequential cyclic heat treatment of oxidation and then reduction was examined. The correlation between the BET surface area of recycled $U_3O_8$ powder and the sintered pellet properties of MnO-$Al_2O_3$ doped pellets showed that the pellet density and grain size of doped pellets were increased and then saturated by increasing the BET surface area of the recycled $U_3O_8$ powder. The density and grain size of the pellets were maximized when the BET surface area of the recycled $U_3O_8$ powder was in the vicinity of $3m^2/g$. Among the process variables applied in this study, the cyclic heat treatment followed by low temperature oxidation was a potential process combination to obtain the sinter-active $U_3O_8$ powder.

• 한국결정성장학회지
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• 제32권5호
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• pp.205-211
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• 2022

GSV (Granule Spray in Vacuum)는 상온의 진공하에서 나노 크기의 치밀한 세라믹 코팅층을 형성하는 방법이다. 일반적으로, 단사정의 지르코니아는 1150℃에서 정방정으로 변태하며, 이때 6.5 %의 체적변화를 일으켜 치밀한 단사정의 지르코니아를 만들기 어렵다. 본 연구에서는 코팅 효율에 대한 두 가지 처리 변수의 효과를 조사하는 데 중점을 두었다. 아울러, 특별한 가열과정 없이 형성된 필름의 미세구조에 관찰하였다. 샘플 기판에 증착된 지르코니아 필름에 대한 X-ray diffractometer (XRD) 분석은 단사정 지르코니아 필름이 성공적으로 증착되었음을 보여주었다.

• 마이크로전자및패키징학회지
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• 제30권1호
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• pp.1-16
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• 2023

전기차용 전력변환모듈의 성능향상 요구와 종래의 Si 전력반도체의 한계 극복을 위해 차세대 전력반도체인 wide-bandgap (WBG) 기반 전력반도체로의 전환이 가속화되고 있다. WBG 전력반도체로의 전환을 위해 전력변환모듈 패키징 소재 역시 높은 고온 내구성을 요구받고 있다. 전력변환모듈 패키징 공정 중 하나인 Ag 소결 다이접합 기술은 종래의 고온용 Pb 솔더링의 대체 기술로 주목받고 있다. 본 논문에서는 Ag 소결 다이접합 기술 관련 최신 연구동향에 대해 소개하고자 한다. 소결 다이접합 공정 조건에 따른 접합부 특성을 비교하고 Ag 소결층의 3차원 이미지 구현에 따른 다공성 Ag 소결 접합부의 물성 측정 방법론에 대해 고찰하였다. 또한 열충격 및 파워사이클 신뢰성 평가 연구동향을 분석하였다.

• 한국결정성장학회지
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• 제30권5호
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• pp.200-207
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• 2020

SHS 법으로 MoSi₂ 분말, (Mo_1/2W_1/2)Si₂ 분말 및 WSi₂ 분말을 합성하고 이 분말들을 500℃, 1,000℃, 1,200℃, 1,300℃, 1,400℃, 1,500℃ 및 1,600℃에서 열처리한 다음, 결정구조 및 열중량 변화 등을 관찰하였다. Mo-W-Si계의 silicide 분말은 500℃의 저온에서도 산화 반응이 일어나며, 저온 산화 및 분해로 생성되는 결정상은 MoO₃이었다. 1,200℃ 이상에서 열처리를 한 경우에 분해반응으로 생성된 SiO₂의 결정상은 상온에서 흔히 관찰되는 α-quartz가 아닌 α-cristobalite 상으로 생성되었다. W이 포함되면 저온과 고온에서 분해 반응이 더 많이 일어나는 것으로 나타났으며, 분말을 성형하여 소결한 시편의 경우에 MoSi₂와 (Mo_1/2W_1/2)Si₂는 저온이나 고온에서 1시간 열처리를 하더라도 저온산화에 의한 분해와 그에 따른 질량 변화 반응을 관찰하기 어려웠지만 WSi₂는 저온 산화에 의하여 소결 자체가 어려웠다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.360-363
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• 2006

We synthesized $(La,\;Sr)MnO_{3+{\delta}$ as a cathode for SOFC by glycine nitrate process(GNP) and knew the different properties of $(La_{1-x}Sr_x)MnO_3$ by using nitrate solution and oxide solution as starting material. In case of using nitrate solution as a starting material, main crystal phase peak of $LaMnO_3$ increased as Sr content added up and a peak of $Sr_2MnO_4\;and\;La_2O_3$ was showed as a secondary phase. We added Mn excess to control a crystal phase. In this case, the electrical conductivity had a high value 210.3S/cm at $700^{\circ}C$ On the other side, when we used oxide solution as a starting material, we found main crystal phase of $LnMnO_3$ to increase as Sr content added up and a peak of $La_2O_3$ as a secondary phase. Similary, we added Mn excess to control a crystal phase in this case. We knew $(La,\;Sr)MnO_3$ powder to sinter well and the electrical conductivity of the sintered body at $1200^{\circ}C$ for 4hrs was 152.7s/cm at $700^{\circ}C$. The sintered $(La,\;Sr)MnO_3$ powder at $1000^{\circ}C$ for 4hrs got the deoxidization peak, depending on the temperature md in case of using nitrate solution as a start ing material the deoxidization peak was showed at $450^{\circ}C$ which is lower than used a oxide solution as a starting material. As a result, when $(La,\;Sr)MnO_3$ powder was synthesized to add Mn excess and to use nitrate solution as a starting material, we found it to have the higher deoxidization property and considered it as a cathode for m properly. And we found it to have different electrical conduct ivity the synthesized $(La,\;Sr)MnO_3$ powder by using different start ing materials like nitrate solution and oxide solution which influence a sintering density and crystal phase.