• 세라미스트
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• 제22권1호
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• pp.96-106
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• 2019

Semiconducting carbon-based nanomaterials including single-walled carbon nanotubes(SWCNTs), multi-walled CNT(MWCNTs), graphene(GR), graphene oxide(GO), and reduced graphene oxide(RGO), are very promising sensing materials due to their large surface area, high conductivity, and ability to operate at room temperature. Despite of these advantages, the semiconducting carbon-based nanomaterials intrinsically possess crucial disadvantages compared with semiconducting metal oxide nanomaterials, such as relatively low gas response, irreversible recovery, and poor selectivity. Therefore, in this paper, we introduce a variety of strategies to overcome these disadvantages and investigate principle parameters to improve gas sensing performances.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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• pp.97-98
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• 2009

Here, we describe a versatile strategy for precise control of the optoelectrical properties of the single walled carbon nanotube (SWNT)/silane binder hybrid films by noncovalent hybridization. Stable SWNT/silane binder solutions were prepared by direct mixing of high concentration CNT solutions and silane sol solutions. The critical binder content was determined by varying the amount of binder in the SWNT/binder solutions. A binder content of 50 wt% was used to prepare the other SWNT/binder solutions. This study demonstrates how the intermolecular interactions between the SWNTs and the silanes can affect the conductivity of the CNT/binder network films by characterizing the optoelectrical and Raman spectroscopic properties of the SWNT/silane films containing silane binders with various functional groups. The use of the PTMS binder with phenyl groups was found to be most effective in the fabrication of transparent and conductive films on glass substrates. Such a precise control of the optoelectrical properties of SWNT/binder films can be useful to fabricate the high performance conductive thin films, with ramifications for understanding the fundamental intermolecular interaction in carbon materials science.

• Advances in nano research
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• 제13권3호
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• pp.207-216
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• 2022

In this paper, a novel model is developed for frequency behavior of single walled carbon nanotubes. The governing equation of motion is constructed method based on the Sander theory using Rayleigh-Ritz's method The frequencies enhances on increasing the power law index using simply supported, clamped and clamped free end conditions. The frequency curve for C-F is less than other conditions. It is due to the physical constraints which are applied on the edge of the CNT. It is observed that the C-F boundary condition have less frequencies from the other two conditions. The frequency phenomena for zigzag are insignificant throughout the aspect ratio. Moreover when index of power law is increased then frequencies increases for all boundary conditions. The natural frequency mechanism for the armchair (10, 10) for various values of power law index with different boundary conditions is investigated. Here frequencies decrease on increases the aspect ratio for all boundary conditions. The frequency curves of SS-SS edge condition is composed between the C-C and C-F conditions. The curves of frequency are less significant from small aspect ratio (L/d = 4.86 ~ 8.47) and decreases fast for greater ratios. It is found that the frequencies via aspect ratios, armchair (10, 10) have higher values from zigzag (10, 0). It is due to the material structure which is made by the carbon nanotubes. The power law index have momentous effect on the vibration of single walled carbon nanotubes. The present frequency result is also compared numerically experimentally with Raman Spectroscopy.

• Advances in nano research
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• 제9권3호
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• pp.211-220
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• 2020

This paper investigates the effect of linear and non-linear distribution of carbon nanotube volume fraction in the FG-CNTRC beams on the critical buckling by using higher-order shear deformation theories. Here, the material properties of the CNTRC beams are assumed to be graded in the thickness direction according to a new exponential power law distribution in terms of the carbon nanotube volume fractions. The single-walled carbon nanotube is aligned and distributed in the polymeric matrix with different patterns of reinforcement; the material properties of the CNTRC beams are described by using the rule of mixture. The governing equations are derived through using Hamilton's principle. The Navier solution method is used under the specified boundary conditions for simply supported CNTRC beams. The mathematical models provided in this work are numerically validated by comparison with some available results. New results of critical buckling with the non-linear distribution of CNT volume fraction in different patterns are presented and discussed in detail, and compared with the linear distribution. Several aspects of beam types, CNT volume fraction, exponent degree (n), aspect ratio, etc., are taken into this investigation. It is revealed that the influences of non-linearity distribution in the beam play an important role to improve the mechanical properties, especially in buckling behavior. The results show that the X-Beam configuration is the strongest among all different types of CNTRC beams in supporting the buckling loads.

• 한국전기전자재료학회논문지
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• 제23권10호
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• pp.782-787
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• 2010

Recently the solution-based thin film technology has often been treated in the field of device fabrication owing to easy process and convenience for the development of various semiconductor devices and sensors. We deposited on glass substrate single-walled carbon nanotubes (SWNTs)/silane hybrid thin films by multiple spray-coating which is one of solution-based processes, and examined their electrical response for humidity. Generally silane binders which are often mixed in carbon nanotube (CNT) solution to adhere CNTs to substrate well form easily each own functionalized group on the surface of CNTs after they are hardened by way of the hydrolysis reaction. In this work, we investigated how silane binders (TEOS (tetraethoxy silane), MTMS (methyltrimethoxysilane) and VTMS (vinyltrimethoxysilane)) in CNT thin films make effect to their electrical response on humidity. As the result, we found that the resistance in the samples using TEOS was changed dramatically while it was almost invariant in the samples using MTMS and VTMS for increasing humidity.

• Structural Engineering and Mechanics
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• 제59권3호
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• pp.431-454
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• 2016

In this paper, the nonlinear static and free vibration analysis of Euler-Bernoulli composite beam model reinforced by functionally graded single-walled carbon nanotubes (FG-SWCNTs) with initial geometrical imperfection under uniformly distributed load using finite element method (FEM) is investigated. The governing equations of equilibrium are derived by the Hamilton's principle and von Karman type nonlinear strain-displacement relationships are employed. Also the influences of various loadings, amplitude of the waviness, UD, USFG, and SFG distributions of carbon nanotube (CNT) and different boundary conditions on the dimensionless transverse displacements and nonlinear frequency ratio are presented. It is seen that with increasing load, the displacement of USFG beam under force loads is more than for the other states. Moreover it can be seen that the nonlinear to linear natural frequency ratio decreases with increasing aspect ratio (h/L) for UD, USFG and SFG beam. Also, it is shown that at the specified value of (h/L), the natural frequency ratio increases with the increasing the values amplitude of waviness while the dimensionless nonlinear to linear maximum deflection decreases. Moreover, with considering the amplitude of waviness, the stiffness of Euler-Bernoulli beam model reinforced by FG-CNT increases. It is concluded that the R parameter increases with increasing of volume fraction while the rate of this parameter decreases. Thus one can be obtained the optimum value of FG-CNT volume fraction to prevent from resonance phenomenon.

• 패션비즈니스
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• 제25권5호
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• pp.99-113
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• 2021

This study aimed to produce sensors for measuring thigh motor skills. A textile stretch sensor was manufactured using a CNT(Carbon Nano Tube) 0.1 wt% water SWCNT(Single-Walled Carbon Nano Tube) solution, and different designs were applied to increase the sensitivity of the sensor, and different GF(Gauge Factor) values were compared using UTM devices. The same design was applied to fabrics and weaves to observe changes in performance according to fibrous tissue, and the suitability of sensors was determined based on tensile strength, elongation, and the elongation recovery rate. Sensitivity was found to vary depending upon the design. Thus the manufactured sensor was attached to a pair of fitness pants as a prototype, divided into lunge position and squat position testing, and the stretch sensor was used to measure thigh movements. It was shown that stretch sensors used to measure thigh motor skills should have light and flexible features and that elongation recovery rates and tensile strength should be considered together. The manufactured stretch sensor may be applicable to various sports fields that use lower limb muscles, wearable healthcare products, and medical products for measuring athletic ability.

• Computers and Concrete
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• 제34권3호
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• pp.297-305
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• 2024

This study investigates the buckling behavior of CNTRC beams on a Winkler-Pasternak elastic foundation, considering their stiffness. To achieve the highest accuracy, the shear stiffness is taken into account based on the Higher-order Shear Deformation Theory (HSDT). A novel exponential power-law distribution of the CNT volume fraction across the beam thickness is employed to model CNTRC beams. Various reinforcement patterns are incorporated into the polymer matrix, featuring single-walled carbon nanotubes (SWCNT) that are both aligned and distributed. The effective mechanical properties of the CNTRC beam are predicted using the rule of mixtures. Hamilton's principle is applied to derive the differential equations of motion. This theoretical framework enables the validation of the approach by comparing numerical simulation results with previous studies. The impact of the exponent order (n), CNT volume fraction, geometrical ratio, and Winkler-Pasternak parameters on buckling analysis is thoroughly presented and discussed. The results indicate that, among the different types of analyzed CNTRC beams, the X-Beam pattern demonstrates the highest buckling load capacity.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.492-492
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• 2011

단일벽 탄소나노튜브(Single-Walled Carbon Nanotubes, SWCNTs)는 매우 우수한 전기적, 광전자적 특성을 가지고 있어 차세대 나노 전자소자 물질로 각광받고 있다. 특히, 이들의 전기적 특성은 직경과 카이랄리티(chirality)에 따라 금속성(metallic)과 반도체성(semiconducting)으로 구분된다. 각 특성에 따라 금속성은 투명전극, 반도체성은 전계효과 트랜지스터(CNT-FET)로 활용가능성이 높다. 하지만, 일반적으로 단일벽 탄소나노튜브는 이 두 가지의 특성이 혼재되어 합성되기 때문에, 그들의 선택적 분리는 나노튜브 기반 전자소자 응용을 위해 매우 중요한 과정 중 하나이다. 최근에는 반응 가스를 이용한 선택적 제거, 밀도차를 이용한 원심분리법(density gradient ultracentrifugation) 등 다양한 방법들이 보고된 바 있다. 본 연구는 대기 중에서 마이크로웨이브 조사하여 금속성 나노튜브만을 선택적으로 제거하였다. 마이크로웨이브 조사는 CVD 방법과 전기 방전법으로 성장된 단일벽 탄소나노튜브에 800W로 조사 시간을 변화하며 수행하였다. 실험 결과, 조사 시간이 증가할수록 두 종류의 나노튜브에서 반도체성 나노튜브는 남아있는 반면 금속성 나노튜브는 점차 제거되었다. 이러한 원인은 각 전기적 특성에 따른 유전상수 차이에 의하여 기인한 것이다. 전기적 특성과 결정성은 라만 분광법(Raman spectroscopy)을 통하여 분석하였으며, 직경 및 분산정도는 주사전자현미경(scanning electron microscope), 투과전자현미경(tunneling electron microscope)으로 관찰하였다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.1535-1538
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• 2005

We present a mass productive and reproducible assembly technique of a single bundle of single-walled carbon nanotubes (sb-SWNTs) using dielectrophoresis (DEP). Gold electrodes with 10 gaps made via microlithography were used to align the carbon nanotubes (CNTs). The magnitude and type of applied electric field were investigated to verify their effects on CNT assembly. The optimum assembling conditions in which sb-SWNTs could be positioned at a desired site were experimentally identified, and the characteristics of the assembled sb-SWNTs were evaluated from AFM, Raman spectroscopy, and I-V curve. This assembly method has potential for applications such as gas sensors or electronic devices.