• 한국대기환경학회:학술대회논문집
• /
• 한국대기환경학회 2003년도 춘계학술대회 논문집
• /
• pp.49-50
• /
• 2003

To know the properties of single aerosol particle is an essential prerequisite for understanding its chemical reactions in the atmosphere. Single particle analysis has the advantage of providing a great amount of information that cannot otherwise be obtained using methods of bulk analysis. And single particle analysis needs the short sampling time and the small sampling mass for analysis. This allows for a better determination of the temporal variation of the component concentrations in aerosol particles. (omitted)

• Mass Spectrometry Letters
• /
• 제2권2호
• /
• pp.57-60
• /
• 2011

As background significantly affects measurement accuracy and a detection limit in determination of the trace amounts of uranium, it is necessary to determine the impurities in the Lexan detector film for single particle measurements by thermal ionization mass spectrometry coupled with fission track technique (FT-TIMS). We have prepared various micro sizes of the blank Lexan detector film using a micromanipulation technique for uranium measurements by TIMS. Few tens of fg of uranium background with no remarkable dependency on the film sizes were observed in the blank Lexan films with the sizes from $50{\times}50\;{\mu}m^2$ to $300{\times}300\;{\mu}m^2$. Based on the determination of the uranium background in the Lexan film, any background correction is necessary in the isotopic analysis of a uranium single particle with micron sizes when the particle bearing Lexan film is dissected with less than $300{\times}300\;{\mu}m^2$ size. The isotopic analysis of a uranium particle in U030 standard material using TIMS was carried out to verify the applicability of the Lexan film to the single particle analysis with high accuracy and precision.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
• /
• pp.301-304
• /
• 2015

With the experiment observation of single particle combustion, this model is built for the numerical analysis of the process. It's about the single coal particle combustion process under different conditions with reasonable assumptions. The model can express the mass, radius, density, temperature changing with different particle sizes, oxygen concentration and gas temperature. It also includes the flame sizes change in different condition and the diffusion of each species. The result shows the characters of the combustion.

• 한국대기환경학회지
• /
• 제20권6호
• /
• pp.823-832
• /
• 2004

Atmospheric aerosol particles collected in Seoul on four single days, each in every seasons of 2001, were characterized and classified on the basis of their chemical species using low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA). Low-Z particle EPMA technique can analyze both the size and the chemical species of individual aerosol particles of micrometer size and provide detailed information on the size distribution of each chemical species. The major chemical species observed in Seoul aerosol were aluminosilicate, silicon dioxide, calcium carbonate, organic, carbon-rich, marine originated, and ammonium sulfate particles, etc. The soil originated species, such as aluminosilicate, silicon dioxide, and calcium carbonate were the most popular in the coarse fraction, meanwhile, carbonaceous and ammonium sulfate were the dominant species found in the fine fraction. Marine originated species such as sodium nitrate was frequently encountered, up to 30% of the analyzed aerosol particles.

• 대한기계학회논문집B
• /
• 제21권11호
• /
• pp.1509-1517
• /
• 1997

Charged and uncharged particle motions and collection characteristics around a bipolar charged rectangular shape electret fiber are studied numerically. Particle inertia, fluid drag, Coulomb force and polarization force are considered to predict the particle motion around the electret fiber. The effects of particle sizes, flow velocities, number of charges and polarities are also systematically investigated. For small size particles, the single fiber collection efficiency is greatly dependent on the charge polarity and the number of charges on a particle. However, particles larger than 5.mu.m do not show charging effect on collection efficiencies in the flow velocity ranges from 1.5 cm/s to 150 cm/s when the maximum charges are within +5 to -10. The results show that a strong electric field gradient at the corner of the bipolar charged fiber plays a very important role on collecting particles regardless of its charge polarity because of the polarization force. It also shows that the most penetrating particle size for a single electret fiber decreases as the flow velocity increases and the number of charges of a particle decreases.

• Asian Journal of Atmospheric Environment
• /
• 제4권3호
• /
• pp.115-140
• /
• 2010

Great concerns about atmospheric aerosols are attributed to their multiple roles to atmospheric processes. For example, atmospheric aerosols influence global climate, directly by scattering or absorbing solar radiations and indirectly by serving as cloud condensation nuclei. They also have a significant impact on human health and visibility. Many of these effects depend on the size and composition of atmospheric aerosols, and thus detailed information on the physicochemical properties and the distribution of airborne particles is critical to accurately predict their impact on the Earth's climate as well as human health. A single particle analysis technique, named low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA) that can determine the concentration of low-Z elements such as carbon, nitrogen and oxygen in a microscopic volume has been developed. The capability of quantitative analysis of low-Z elements in individual particle allows the characterization of especially important atmospheric particles such as sulfates, nitrates, ammonium, and carbonaceous particles. Furthermore, the diversity and the complicated heterogeneity of atmospheric particles in chemical compositions can be investigated in detail. In this review, the development and methodology of low-Z particle EPMA for the analysis of atmospheric aerosols are introduced. Also, its typical applications for the characterization of various atmospheric particles, i.e., on the chemical compositions, morphologies, the size segregated distributions, and the origins of Asian dust, urban aerosols, indoor aerosols in underground subway station, and Arctic aerosols, are illustrated.

• 한국대기환경학회지
• /
• 제21권3호
• /
• pp.367-375
• /
• 2005

Low-Z particle Electron Probe X-ray Microanalysis was applied to characterize MSW fly- and bottom -ash particle samples originated from two municipal incinerators (denoted as A and B) in Korea. According to their chemical composition, many distinctive particle types were identified. In A fly ash, the major chemical species are carbon-rich, aluminosilicates and many particles are composed of as a mixture of $ CaCO_3$ and other chemical species such as $CaSO_4$ or $CaCl_2$. For B fly ash, Fe, iron oxide, NaCl and NaCl-containing particles are the most abundant. In bottom ash, A and B were composed of similar chemical species such as carbon-rich, Fe, iron oxide, $CaCO_3$, and aluminosilicates. It was demonstrated that the single-particle characterization using this low-Z particle EPMA technique provided detailed information on various types of chemical species in the MSW ash samples. In addition, the technique has advantage over conventional analytical techniques in the point that both crystalline and glass-like ash particles can be analyzed at the same time.

• 한국대기환경학회지
• /
• 제19권4호
• /
• pp.415-425
• /
• 2003

A single particle analysis, called low-Z electron probe X-ray microanalysis was applied to characterize the atmospheric aerosols collected during Asian Dust storm events in the year of 2000 and 2001. Most frequently encountered chemical species were the soil-originated species such as aluminosilicates, silicon dioxide, and calcium carbonate. Also various species such as carbon -rich, organics, sea salts, and some reacted calcium carbonate were identified. The observation of internally mixed particles oi calcium carbonate, calcium nitrate and/or calcium sulfate shows the occurrence of the heterogeneous reaction between Asian Dust particles and NO$_{x}$ and/or SO$_{x}$ species in the atmosphere.ere.

• Journal of Mechanical Science and Technology
• /
• 제15권1호
• /
• pp.108-116
• /
• 2001

The in-cylinder flow field of gasoline engine comprises unsteady compressible turbulent flows caused by the intake port, combustion chamber geometry. Thus, the quantitative analysis of the in-cylinder flow characteristics plays an important role in the improvement of engine performances and the reduction of exhaust emission. In order to obtain the quantitative analysis of the in-cylinder gas flows for a gasoline engine, the single-frame particle tracking velocimetry was developed, which is designed to measure 2-dimensional gas flow field. In this paper, influences of the swirl and tumble intensifying valves on the in-cylinder flow characteristics under the various intake flow conditions were investigated by using this PTV method. Based on the results of experiment, the generation process of swirl and tumble flow in a cylinder during intake stroke was clarified. Its effect on the tumble ratio at the end of compression stroke was also investigated.

• 한국결정성장학회지
• /
• 제27권1호
• /
• pp.57-63
• /
• 2017

High-purity ${\beta}-SiC$ powders for SiC single-crystal growth were synthesized by direct carbonization. The use of high-purity raw materials to improve the quality of a SiC single crystal is important. To grow SiC single crystals by the PVT method, both the particle size and the packing density of the SiC powder are crucial factors that determine the sublimation rate. In this study, we tried to produce high-purity ${\beta}-SiC$ powder with large particle sizes and containing low silicon by introducing a milling step during the direct carbonization process. Controlled heating improved the purity of the ${\beta}-SiC$ powders to more than 99 % and increased the particle size to as much as ${\sim}100{\mu}m$. The ${\beta}-SiC$ powders were characterized by SEM, XRD, PSA, and chemical analysis to assess their purity. Then, we conducted single-crystal growth experiments, and the grown 4H-SiC crystals showed high structural perfection with a FWHM of about 25-48 arcsec.