• Journal of the Korean earth science society
• /
• v.22 no.1
• /
• pp.65-74
• /
• 2001

To evaluate the influence of meteorological conditions on the performance of DOAS (Differential Optical Absorption Spectroscopy) system, we analyzed the concentrations of three criteria pollutants and relevant environmental parameters measured during 14 month periods between Jun. 1999 and Oct. 2000. According to our study, the performance of DOAS can be sensitively influenced via various manners (such as among different chemicals and/or between different time periods). It turns out that O$_3$ exhibits most frequently the weakest agreement between two systems. When comparison was made among different meteorological parameters, the strongest variability was seen from such ones as windspeed, wind direction, and irradiance. In addition, the absolute differences in measured concentrations between two systems were compared against various environmental parameters by means of linear regression analysis. Results of this analysis indicated that the differences between the two tend to decrease with the increase of such parameters as windspeed. It is thus concluded on the basis of our study that the simultaneous evaluation of meteorological data should be an essential step toward the accurate assessment of pollutant concentration data obtained by DOAS measurement system.

• Journal of The Korean Astronomical Society
• /
• v.56 no.2
• /
• pp.231-252
• /
• 2023

We present the analysis results of the simultaneous multifrequency observations of the blazar 4C +28.07. The observations were conducted by the Interferometric Monitoring of Gamma-ray Bright Active Galactic Nuclei (iMOGABA) program, which is a key science program of the Korean Very Long Baseline Interferometry (VLBI) Network (KVN). Observations of the iMOGABA program for 4C +28.07 were conducted from 16 January 2013 (MJD 56308) to 13 March 2020 (MJD 58921). We also used γ-ray data from the Fermi Large Array Telescope (Fermi-LAT) Light Curve Repository, covering the energy range from 100 MeV to 100 GeV. We divided the iMOGABA data and the Fermi-LAT data into five periods from 0 to 4, according to the prosody of the 22 GHz data and the presence or absence of the data. In order to investigate the characteristics of each period, the light curves were plotted and compared. However, a peak that formed a hill was observed earlier than the period of a strong γ-ray flare at 43-86 GHz in period 3 (MJD 57400-58100). Therefore, we assumed that the minimum total CLEANed flux density for each frequency was quiescent flux (S_q) in which the core of 4C +28.07 emitted the minimum, with the variable flux (S_var) obtained by subtracting S_q from the values of the total CLEANed flux density. We then compared the variability of the spectral indices (α) between adjacent frequencies through a spectral analysis. Most notably, α_22-43 showed optically thick spectra in the absence of a strong γ-ray flare, and when the flare appeared, α_22-43 became optically thinner. In order to find out the characteristics of the magnetic field in the variable region, the magnetic field strength in the synchrotron self-absorption (B_SSA) and the equipartition magnetic field strength (B_eq) were obtained. We found that B_SSA is largely consistent with B_eq within the uncertainty, implying that the SSA region in the source is not significantly deviated from the equipartition condition in the γ-ray quiescent periods.

• Applied Chemistry for Engineering
• /
• v.18 no.3
• /
• pp.239-244
• /
• 2007

For the simultaneous methane recovery and $CO_2$-stripping, we have been developed dual vent auto circulation bubble lift column reactor, and evaluate optimum conditions for monoethanolamine (MEA) solutions as a $CO_2$ absorbent. At the 5 wt% MEA solution, we investigated the pH change during $CO_2$-stripping and absorption reaction, $CO_2$-stripping rate with reaction time, methane recovery efficiency for various inflow rates of air, $CO_2$-stripping rate for flow liquid over flow height, and $CO_2$-stripping dependency on the temperature of absolvent solutions. The suggested optimum conditions for $CO_2$ recovery with MEA in the dual vent auto circulation bubble lift column reactor were 40 mm over flow liquid height, 1.5 L/min of air inflow rate, and $25^{\circ}C$ of absorbent solution temperature.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.246-246
• /
• 2016

Tungsten-nitrogen (W-N) co-doping has been known to enhance the photocatalytic activity of anatase titania nanoparticles by utilizing visible light. The doping effects are, however, largely dependent on calcination or annealing conditions, and thus, the massive production of quality-controlled photocatalysts still remains a challenge. Using density functional theory (DFT) thermodynamics and time-dependent DFT (TDDFT) computations, we investigate the atomic structures of N doping and W-N co-doping in anatase titania, as well as the effect of the thermal processing conditions. We find that W and N dopants predominantly constitute two complex structures: an N interstitial site near a Ti vacancy in the triple charge state and the simultaneous substitutions of Ti by W and the nearest O by N. The latter case induces highly localized shallow in-gap levels near the conduction band minimum (CBM) and the valence band maximum (VBM), whereas the defect complex yielded deep levels (1.9 eV above the VBM). Electronic structures suggest that substitutions of Ti by W and the nearest O by N improves the photocatalytic activity of anatase by band gap narrowing, while defective structure degrades the activity by an in-gap state-assisted electron-hole recombination, which explains the experimentally observed deep level-related photon absorption. Through the real-time propagation of TDDFT (rtp-TDDFT), we demonstrate that the presence of defective structure attracts excited electrons from the conduction band to a localized in-gap state within a much shorter time than the flat band lifetime of titania. Based on these results, we suggest that calcination under N-rich and O-poor conditions is desirable to eliminate the deep-level states to improve photocatalysis.

• Environmental Mutagens and Carcinogens
• /
• v.21 no.1
• /
• pp.51-56
• /
• 2001

Kimchi is a major Korean traditional fermented food, as a supplying source of vitamin and minerals which is prepared with various vegetables and condiments such as red pepper, garlic and salted fish etc. There are many types of Kimchi depending on the ingredients and preparation methods used. To investigate the clastogenicity and anticlastogenicity of Baechu (Chinese cabbage) Kimchi and Buchu (leek, Allium odorum) Kimchi in mouse, it was performed acridine orange supravital staining of micronucleus (AOSS-MN) assay using mouse peripheral reticulocytes. Baechu Kimchi and Buchu Kimchi were cultivated by organic agricultural technique, and Kimchi samples were prepared by methanol extraction and lyophilization. First of all, it was studied the clastogenicity of two Kimchi samples themselves (250-1,000 mg/kg) after oral adminstration in mouse. And also to study the anticlastogenic effect of oral administration of Kimchi samples, mitomycin C (MMC, 1 mg/kg, i.p.) was used as micronucleus inducing agent in this study. Dosing scheme was performed as simultaneous (co-treatment), 3 hr before (pre-treatment) and 3 hr after (post-treatment) with MMC treatment. Two Kimchi samples in the range of 250-1,000 mg/kg did not reveal any clastogenic effect in AOSS-MN assay in mouse. They also revealed anticlastogenic effects in post-treatment of Baechu Kimchi (1,000 mg/kg), and in pre-treatment of Buchu Kimchi (500 and 1,000 mg/kg) with statistical significance. The anticlastogenic effect revealed 1 and 6 hr after treatment of Baechu Kimchi, and Buchu Kimchi with 3 and 6 hr pretreatment. Consequently, it is suggested that antimutagenic and anticlastogenic mechanisms of Baechu and Buchu Kimchi in vivo attributed to sipindle formation and kinetic behavior of mutagens such as absorption and metabolism etc.

• Journal of Korean Society for Atmospheric Environment
• /
• v.26 no.2
• /
• pp.190-201
• /
• 2010

Fine particulate matter < $1.8{\mu}m$ was collected as a slurry using the Semicontinuous Elements in Aerosol Sampler with time resolution of 30-min between May 23 and 27, 2002 at the Sydney Supersite, Florida, USA. Concentrations of 11 elements, i.e., Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Se, and Zn, in the collected slurry samples were determined off-line by simultaneous multi-element graphite furnace atomic absorption spectrometry. Temporal profiles of $SO_2$ and elemental concentrations combined with meteorological parameters such as wind direction and wind speed indicate that some transient events in their concentrations are highly correlated with the periods when the plume from an animal feed supplement processing facility influenced the Sydney sampling site. The peaking concentrations of the elemental species during the transient events varied clearly as the plume intensity varied, but the relative concentrations for As, Cr, Pb, and Zn with respect to Cd showed almost consistent values. During the transient events, metal concentrations increased by factors of >10~100 due to the influence of consistent plumes from an individual stationary source. Also the multi-variate air dispersion receptor model, which was previously developed by Park et al. (2005), was applied to ambient $SO_2$ and 8 elements (Al, As, Cd, Cr, Cu, Fe, Pb, and Zn) measurements between 20:00 May 23 and 09:30 May 24 when winds blew from between 70 and $85^{\circ}$, in which animal feed processing plant is situated, to determine emission and ambient source contributions rates of $SO_2$ and elements from one animal feed processing plant. Agreement between observed and predicted $SO_2$ concentrations was excellent (R of 0.99; and their ratio, $1.09{\pm}0.35$) when one emission source was used in the model. Average ratios of observed and predicted concentrations for As, Cd, Cr, Pb, and Zn varied from $0.83{\pm}0.26$ for Pb to $1.12{\pm}0.53$ for Cd.

• Bulletin of the Korean Space Science Society
• /
• 2008.10a
• /
• pp.31.2-31.2
• /
• 2008

We present the results offar ultraviolet (FUV, 1350-1750 ${\AA}$) auroral observations made by the Far-ultraviolet IMaging Spectrograph (FIMS) instrument on the Korean microsatellite STSAT-1. The instrument was capable of resolving spatial structures of a few kilometers with the spectral resolution of 2-3 ${\AA}$. The observations were carried out simultaneously with the measurement of precipitating electrons using an electrostatic analyzer (ESA, 100 eV-20 keV) and a solid state telescope (SST, 170 keV-360 keV) on board the same satellite. With a careful mapping of the field lines, we were able to correlate the particle spectrum to the corresponding FUV spectrum of the footprints of the FIMS image that varied significantly in fine scales. We divided the FIMS spectral band into the LBH long (LBHL, 1640-1715 ${\AA}$) and LBH short (LBHS, 1380-1455 ${\AA}$) bands, and compared the electron energies with the intensities of LBHL and LBHS for the well-defined inverted-V structures. The result shows a strong correlation between the total LBH intensity and the energy flux measured by ESAwhile the peak energy itself does not correlate well with the LBH intensity. On the other hand, it was observed that the ratio of the LBHL intensity to that of LBHS increased significantly as the peak electron energy increased, primarily due to a smaller absorption by O2 at LBHL than at LBHS.

• Environmental Engineering Research
• /
• v.20 no.1
• /
• pp.89-97
• /
• 2015

Remediation of wastewater contaminated with metal(II)-complexed species (Cu(II)-NTA (NTA: nitrilotriacetic acid), Cu(II)-EDTA (EDTA: ethylenediamine tetraacetic acid) and Cd(II)-EDTA is attempted using the potential applicability of ferrate(VI). Kinetics of pollutant degradation is obtained with the removal of ferrate(VI) studied at wide range of pH (8.0-10.0) and the concentration of metal(II)-complexed species (0.3 to 15.0 mmol/L) employing a constant dose of ferrate(VI) i.e., 1.0 mmol/L. Pseudo-first-order and pseudo-second-order rate constants were obtained in the reduction of ferrate(VI) which was then employed to obtain the overall rate constants of the pollutant degradation. The mineralization of NTA and EDTA was obtained with the change in TOC (total organic carbon) values collected by the ferrate(VI) treated pollutant samples. Decrease in pH and molar pollutant concentrations was greatly favored the percent mineralization of NTA or EDTA by the ferrate(VI) treatment. The treated pollutant samples were filtered and subjected for AAS (atomic absorption spectrophotometric) analysis to assess the simultaneous removal of copper and cadmium from aqueous solutions at the studied pH as well at the elevated pH 12.0. Results show that an enhanced removal of cadmium or copper was achieved at pH 12.0. Overall, ferrate(VI) possesses multifunctional application in wastewater treatment as it oxidizes the degradable impurities and removes metallic impurities by coagulation process.

• The Bulletin of The Korean Astronomical Society
• /
• v.39 no.2
• /
• pp.113.1-113.1
• /
• 2014

We propose a three-year Key Science Program (KSP) consisting of VLBI monitoring observations and single dish (SD) rapid response observations (RRO). The VLBI monitoring observations are comprised of ten 24-hr observations per year (every month) of about 30 gamma-ray brigt active galactic nuclei (AGNs) with Korea VLBI Network (KVN) at 22, 43, 86, and 129 GHz. The SD RROs may consist of twelve 7-hr observations per source (every week for 3 months after triggering) of gamma-ray flaring sources with two KVN SD telescopes at 22, 43, and 86 GHz in dual polarization. We expect one or two sources per year for the SD RROs. Gamma-ray flares of AGNs are known to be occured in innermost regions of relativistic jets which radiate in whole ranges of electromagnetic spectra due to synchrotron radiation, syschrotron self absorption, inverse-compton scttering, doppler boosting etc. Possible explanations of the gamma-ray flares in AGNs are a) shocks-in-jets propagating within jet flow and b) bending of the whole jets. For both cases, we should expect changes in polarization, luminosity, particle distribution, and structures of jets at mas-scale. The multifrequency simultaneous VLBI/SD observations with KVN are the best tool for detecting such changes correlated with gamma-ray flares. This KSP proposal aims to answer the fundamental questions about the basic nature of the flares of AGNs.

• Archives of Pharmacal Research
• /
• v.23 no.2
• /
• pp.178-181
• /
• 2000

In order to study the simultaneous determination of (+)- and (-)-cetirizine in human urine we have developed a chiral separation method by HPLC. A chiral stationary phase of $\alpha$$_1$-acidglycoprotein, the AGP-CSP was used to separate the enantiomers. The pH of the phosphate buffer, as well as the content of the organic modifier in the mobile phase, markedly affected the chromatographic separation of (+)- and (-)-cetirizine. A mobile phase of 10 m㏖/1 phosphate buffer (pH 7.0)-acetonitrile (95 : 5, v/v) was used for the urine assays. Ultraviolet absorption was monitored at 230nm and roxatidine was employed as the internal standard for quantification. (+)-Cetirizine, (-)-cetirizine and the internal standard were eluted at retention times of 12, 16, and 32 mins, respectively. The detection limit for cetirizine enantiomers was 400 ng/$m\ell$ of urine. A pharmacokinetic study was conducted with the help of 5 healthy female volunteers who were administered with a single oral dose of racemic cetirizine (20 mg). The peak area ratios provided by the cetirizine enantiomers were linear(r>0.997) over a concentration range of 2.5-200 ${\mu}g/ml$. The peak of the excreted cetirizine enantiomers appeared in the urine sample during the period of 1-2 hrs following the administration of the oral dose. The excreted level of (+)-cetirizine was slightly higher than (-)-cetirizine but the difference was not statistically significant. However, this method appears to have applications for enantioselective pharmacokinetic studies of racemic drugs.