• Title/Summary/Keyword: Simultaneous Absorption

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Miscibility Gap in Cu-Zr-Ag Alloy System and its Effect on the Structure and Plasticity of Metallic Glass (Cu-Zr-Ag계 비정질 합금의 불혼화 영역이 구조 및 소성에 미치는 영향)

  • Lee, Jin-ju;Park, Kyoung-Won;Kim, Do-Hyang;Fleury, Eric
    • Korean Journal of Metals and Materials
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    • v.49 no.12
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    • pp.930-936
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    • 2011
  • In the present study, we show that the addition of Ag, an element having a positive enthalpy of mixing with Cu in the liquid state, enables the simultaneous enhancement of the glass forming ability and the plasticity in Cu-Zr-Ag bulk metallic glasses (BMGs). Rods of 4 mm diameter could be prepared with a fully amorphous structure and values of plastic strain up to 18% were measured under a compression mode for compositions around $Cu_{42.5}Zr_{47.5}Ag_{10}$. The possible role of Ag in the change of the atomic structure and the enhancement of the plastic strain in the ternary Cu-Zr-Ag BMGs is discussed based on analyses from transmission electron microscopy and EXAFS (extended X-ray absorption fine structure).

Magnetic Field Strengths of Flaring Region in the Jet of CTA 102

  • Kim, Sang-Hyun;Lee, Sang-Sung
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.32.1-32.1
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    • 2021
  • We present the magnetic field strengths of CTA 102 using multi-frequency data at 2.6-343.5 GHz in order to study the physical origins of radio flares. The observations at 22 and 43 GHz were conducted using the single-dish radio telescopes of the Korean VLBI Network (KVN) from December 2012 until May 2018 (MJD 56200-58400). We used multi-frequency data obtained from the Effelsberg 100-m, OVRO 40-m, Metsähovi 14-m, IRAM 30-m, SMA, ALMA, and VLBA telescopes. During the period of the observations, two major flares (R1 and R2) are seen clearly at 15 and 37 GHz during MJD 57500-57800 and MJD 58000-58300, respectively. The source shows typical variability with time-scales ranging from 20-161 days at 15 GHz. The variability Doppler factor is in the range of 11.51-31.23. The quasi-simultaneous radio data are used to investigate the synchrotron spectrum of the source, finding that the synchrotron radiation is self-absorbed. The turnover frequency and the peak flux density of the synchrotron self-absorption (SSA) spectra are in ranges of 38.06-167.86 GHz and 1.49-10.38 Jy, respectively. From the SSA spectra, magnetic field strengths are estimated to be < 10 mG. The equipartition magnetic field strengths are larger than the SSA magnetic field strengths by a factor of > 100. This indicates that the radio flares may be related to a particle energy-dominated emission region.

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Effects of Multiple-CycleOperation and $SO_2$ Concentration on the Absorption Characteristics of $CO_2$ by means of Limestone (석회석의 $CO_2$의 흡수특성에 미치는 흡수/재생 반응의 반복횟수와 $SO_2$ 농도의 영향)

  • Ryu Ho-Jung
    • Journal of Energy Engineering
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    • v.14 no.3 s.43
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    • pp.203-211
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    • 2005
  • To investigate the effects of the number of multiple-cycles and $SO_2$ concentration on $CO_2$ absorption characteristics by means of limestone, $CO_2$ capture capacity has been measured in a bubbling fluidized bed reactor (0.1m 1.D., 1.17m high). Danyang limestone was used as a $CO_2$ sorbent and the number of cycles $(\~10th\;cycle)$ and $SO_2$ concentrations (0, 2000, 4000 ppm) were considered as variables. The measured $CO_2$ capture capacity decreased as the number of cycles increased and it showed $50\%$ or initial value after 10 cycles. Moreover, $CO_2$ rapture capacity decreased with 501 concentrations. For three different $SO_2$ concentrations, the total CaO utilization was almost the same but $SO_2$ capture capacity increased and $CO_2$ capture capacity decreased as $SO_2$ concentration increased. These results suggest that $SO_2$ capture reaction is predominant over $CO_2$ capture reaction in the simultaneous $CO_2/SO_2$ capture conditions.

Preparation Method for Atomic Absorption Spectrophotometry of Food Samples -Comparison of Dry, Wet and Aqua-regia Methods- (원자흡광분석(原子吸光分析)을 위한 식품시료(食品試料) 전처리방법(前處理方法) -왕수액(王水液) 처리법(處理法)과 건식(乾式) 및 습식분해법과(濕式分解法)의 비교(比較)-)

  • Woo, Soon-Ja;Ryoo, Si-Saeng
    • Korean Journal of Food Science and Technology
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    • v.15 no.3
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    • pp.225-230
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    • 1983
  • Aqua-regia method is reported for simultaneous determination of potassium, sodium, calcium, magnesium, zinc, manganese, copper and iron in high-fat fish tissue. Samples are digested with conc nitric and conc hydrochloric acid in a volumetric flask. After digestion, aqua-regia extracts of samples are analyzed by direct flame atomic absorption spectrophotometry. The aqua-regia method is compared with dry ashing method and $H_{2}SO_{4}-HNO_{3}$ method. For quantiative determination of calcium, magnesium and zinc, the aqua-regia method and dry ashing method are superior to $H_{2}SO_{4}-HNO_{3}$ method. In case of the other elements-potassium, sodium, manganese, copper and iron-the three methods gave the similar results. Because samples can be processed by aqua-regia method easily, rapidily, cheaply and safely, aqua-regia method is suitable for the routine preparation of a large number of samples simultaneously.

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A Study on the boiler efficiency with selecting the uppermost burners in the 870MW opposite wall fired boiler (870MW 대향류 보일러에서 최상부층 버너 선택운전에 따른 보일러 효율변화 고찰)

  • Woo, Gwang-Yoon;Kim, Soo-Seok;Park, In-Chan;Ham, Young-Jun;Lee, Eung-Yoon
    • Plant Journal
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    • v.13 no.2
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    • pp.46-51
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    • 2017
  • In this study, the boiler efficiency and the change of boiler combustion state with the burner operation of the uppermost layer of 870MW opposite fired coal boiler were measured. Test results showed that the boiler efficiency was high in the order of the uppermost layer simultaneous operation of the front and rear burners, the front burner, and the rear burner operation. When the front and rear burners were operated simultaneously, the heat absorption rate of water walls in the boiler furnace was uniform at four side, and the temperature deviation of the left and right steam on the convection front surface decreased. As the heat absorption rate of the boiler improved, the loss of boiler exhaust gas decreased and the coal supply amount decreased by 8 tons/hour compared to the operation of the rear burner. This will contribute not only to the reduction of fuel cost but also to the reduction of greenhouse gas emissions.

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Simultaneous Determination of Chromium (III) and Chromium(VI) by High Performance Liquid Chromatography(HPLC) (고성능 액체크로마토그래피(HPLC)를 이용한 3가, 6가 크롬의 동시정량에 관한 연구)

  • Roh, Jae Hoon;Kim, Chi Nyon;Kim, Choon Sung;Kim, Kyoo Sang
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.4 no.2
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    • pp.189-197
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    • 1994
  • Analytic methods for Cr(VI) level in industrial hygienic field were suggested by the National Institute for Occupational Safety and Health(NIOSH method 7600, 7604). There were growing needs for measurement of Cr(III) and Cr(VI) levels simultaneously. Two analytical methods were suggested to determine Cr(III) and Cr(VI) levels simultaneously. The one is method by using reversed phase high peformance liquid chromatography(HPLC) and the other is by using ion exchange HPLC. The purpose of this work was to evaluate the usefulness of these two analytic methods. For the difference of ionic charges of Cr(III)-ethylendiamine tetraacetic acid(EDTA) chelate and $CrO_4{^-2}$, we could detect them simultaneously by ion exchange HPLC. Also, we attempted to determine the levels of Cr(III) and Cr(VI) chelated with sodium diethyldithiocarbamate(NaDDTC) by using reversed phase HPLC. The confirmation of Cr(III) and Cr(VI) were checked by fraction collector and nameless atomic absorption spectrometer. The optimal conditions for the formation of Cr(III)-EDTA chelate were two hours incubation period with pH 5. Cr(III)-EDTA and Cr(VI) in EDTA solution were successfully separated by anion exchange column using $Na_2CO_3/NaOH$ mixture as mobile phase. Peaks of Cr(III)-EDTA and Cr(VI) in EDTA were identified at 5 minutes and 7 minutes of retention time respectively by the ion exchange HPLC. The formation of Cr(III)-NaDDTC and Cr(VI)-NaDDTC chelates were twelve hours incubation period. Cr(III)-NaDDTC and Cr(VI)-NaDDTC chelates were separated by reversed phase column using methanol and water mixture as mobile phase. Peaks of Cr(VI)NaDDTC and Cr(III)-NaDDTC chelates were identified at 13 minutes and 26 minutes of retention time respectively by the reversed phase HPLC. Due to reduction of Cr(VI) to Cr(III), it seems to be not suitable for simultaneous determination of Cr(III)-NaDDTC and Cr(VI)-NaDDTC chelates by reversed phase HPLS. Simultaneos determination of Cr(III) and Cr(VI) by ion exchange HPLC was more accurate and simple method.

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Effects of Non-protein Energy Intake on Whole Body Protein Synthesis, Nitrogen Retention and Glucose Turnover in Goats

  • Fujita, Tadahisa;Kajita, Masahiro;Sano, Hiroaki
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.4
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    • pp.536-542
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    • 2007
  • The responses of whole body protein and glucose kinetics and of nitrogen (N) metabolism to non-protein energy intake (NPEI) were determined using an isotope dilution approach and measurement of N balance in three adult male goats. The diets containing 1.0, 1.5 and 2.0 times ME maintenance requirement, with fixed intake of CP (1.5 times maintenance) and percentage of hay (33%), were fed twice daily for each 21 d experimental period. After an adaptation period of 11 d, N balance was determined over 3 d. On day 17, whole body protein synthesis (WBPS) and glucose irreversible loss rate (ILR) were determined during the absorptive state by a primed-continuous infusion of [$^2H_5$]phenylalanine, [$^2H_2$]tyrosine, [$^2H_4$]tyrosine and [$^{13}C_6$]glucose, with simultaneous measurements of plasma concentrations of metabolites and insulin. Ruminal characteristics were also measured at 6 h after feeding over 3 d. Nitrogen retention tended to increase (p<0.10) with increasing NPEI, although digestible N decreased linearly (p<0.05). Increasing NPEI decreased (p<0.01) ammonia N concentration, but increased acetate (p<0.05) and propionate (p<0.05) concentrations in the rumen. Despite decreased plasma urea N concentration (p<0.01), increased plasma tyrosine concentration (p<0.05), and trends toward increased plasma total amino N (p<0.10) and phenylalanine concentrations (p<0.10) were found in response to increasing NPEI. Increasing NPEI increased ILR of both glucose (p<0.01) and phenylalanine (p<0.05), but did not affect ($p{\geq}0.10$) that of tyrosine. Whole body protein synthesis increased (p<0.05) in response to increasing NPEI, resulting from increased utilization rate for protein synthesis (p<0.05) and unchanged hydroxylation rate of phenylalanine ($p{\geq}0.10$). These results suggest that increasing NPEI may enhance WBPS and glucose turnover at the absorptive state and improve the efficiency of digestible N retention in goats, with possibly decreased ammonia and increased amino acid absorption. In addition, simultaneous increases in WBPS and glucose ILR suggest stimulatory effect of glucose availability on WBPS, especially when sufficient amino acid is supplied.

Simultaneous Flotation and Determination of Trace Cobalt, Copper and Total Chromium in Sea water by $La(OH)_3$ Coprecipitation ($La(OH)_3$ 공침에 의한 해수중 흔적량 코발트, 구리, 및 전체 크롬의 동시 부선 및 정량)

  • Jo, Man Sik;Im, Heung Bin;Kim, Yeong Sang
    • Journal of the Korean Chemical Society
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    • v.38 no.9
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    • pp.667-675
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    • 1994
  • The precipitate flotation using $La(OH)_3$ as a coprecipitant was studied for the simultaneous determination of trace three elements in a sea water. Several experimental conditions such as pH, coprecipitant and surfactant were investigated with an artificial sea water. To remove the influence of Cr(VI) the Cr(VI) was reduced to Cr(III) using $NaBH_4$ prior to the flotation. Trace amounts of Cu(II), Co(II) and total Cr in 1.0 l sea water was coprecipitated together with the precipitation of $La(OH)_3$ in the solution of pH 9.8 adjusted with 3.OM NaOH solution. The precipitate was floated by using a mixed surfactant (1 to 8 of each 0.5% ethanolic sodium oleate and sodium dodecylsulfate solution) by bubbling a nitrogen gas. The floats was separated and filtrated from the mother liquor by suction. The precipitate was dissolved in 7.0 M $HNO_3$ solution and then marked to 25.0 ml with a deionized water. These elements were determined by graphite fumace atomic absorption spectrophotometry. This method was applied to determine the elements in the sea water of the Eastern and Western coasts. And the recoveries were over 90.0% in the samples into which given amounts of the analyte elements were spiked.

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Simultaneous Removal of $SO_2$ and NOx Using Ozone Generator and Absorption- Reduction Technique (오존발생장치와 흡수환원법을 이용한 배기가스 동시 탈황 탈질 공정)

  • Mok, Young-Sun;Lee, Joo-Hyuck;Shin, Dong-Nam;Koh, Dong-Jun;Kim, Kyong-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.191-196
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    • 2006
  • The injection of ozone, produced by dielectric barrier discharge, into the exhaust gas gives rise to a rapid oxidation of NO that is the main component of nitrogen oxides($NO_x$) in most practical exhaust gases. Once NO is converted into $NO_2$, it on readily be reduced to $N_2$ in the next step by a reducing agent such as sodium sulfide and sodium sulfite. The reducing agents used ca also remove $SO_2$ effectively, which makes it possible to treat $NO_x\;and\;SO_2$ simultaneously. The present two-step process made up of an ozonizing chamber and an absorber containing a reducing agent solution was able to remove about 95% of the $NO_x$ and 100% of the $SO_2$, initially contained in the simulated exhaust gas. The formation of $H_2S$ from sodium sulfide was prevented by using a strong basic reagent(NaOH) together with the reducing agent. The removal of $NO_x$\;and\;SO_2$ was more effective for $Na_2S$ than $Na_2SO_3$.

Effect of Excipients on the Stability and Transport of Recombinant Human Epidermal Growth Factor (rhEGF) across Caco-2 Cell Monolayers

  • Kim, In-Wha;Yoo, Ho-Jung;Song, Im-Sook;Chung, Youn-Bok;Moon, Dong-Cheul;Chung, Suk-Jae;Shim, Chang-Koo
    • Archives of Pharmacal Research
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    • v.26 no.4
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    • pp.330-337
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    • 2003
  • The effect of sixteen excipients on the transport of recombinant human epidermal growth factor (rhEGF) across Caco-2 cell monolayers was examined at $37^{\circ}C$. The apparent apical to basolateral (A-B) permeability ($P_{app}$) of 30 $\mu$ M rhEGF was $8.15\times 10^{-7}$ cm/sec, indicative of a poor level of absorption in the GI tract. The Papp was 1.7- and 6.3-fold greater than the $P_{app}$ in the basolateral to apical (B-A) direction and the A-B permeability of mannitol, respectively, and decreased dramatically to a negligible level at $4^{\circ}C$, consistent with a receptor mediated transcytosis of rhEGF. The stability of rhEGF was very poor, undergoing more than 85% degradation in 2 h in the transport medium at $37^{\circ}C$. A significant increase in the $P_{app}$ could be achieved by the addition of certain excipients, as exemplified by 23, 21, 20 and 16-fold increases, in the presence of sodium taurochenodeoxycholate (NaTCDC), sodium taurodeoxycholate (NaTDC), sodium glycodeoxycholate (NaGDC) and sodium laurylsulfate (SLS) (all at a concentration of 1 % w/v), respectively. A significant increase in stability could also be achieved by the addition of some of the excipients, as represented by 1 % SLS, which nearly completely stabilized the rhEGF. Unfortunately, however, an increase in the $P_{app}$ of rhEGF could not be achieved without a simultaneous and extensive decrease in the integrity of the cell membranes. Thus, more efficient excipients, that specifically enhance the permeation of rhEGF and do not alter the membrane integrity, should be pursued in order to safely enhance the permeation of rhEGF.