• Membrane Journal
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• v.13 no.4
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• pp.257-267
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• 2003

For the treatment of reactive phenolic resin waste, a simulation model of pervaporative dehydration process has been developed through hollow fiber membrane module. Some of basic parameters were determined directly from dehydration of the waste liquid through a flat sheet membrane to get realistic values. The simulation model was verified by comparing the simulated values with experimental data obtained from hollow fiber membrane module. Hollow fiber membranes with active layer coated on inside fiber were used, and feed flew through inside hollow fiber. Feed flow rate affected membrane performances and reaction by providing a corresponding temperature distribution of feed along with fiber length. Feed temperature is also a crucial factor to determine dehydration and reaction behavior by two competing ways; increasing temperature increases permeation rate as well as water formation rate. Once the permeate pressure is well below the saturated vapor pressure of feed, permeate pressure had a slightly negative effect on permeation performance by slightly reducing driving force. As the pressure approached the vapor pressure of feed, dehydration performances declined considerably due to the activity ratio of feed and permeate.

• Journal of Wetlands Research
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• v.10 no.2
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• pp.39-51
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• 2008

In recent days, the cases of using wetlands in treating waste water, storm events, mining leachate, and agriculture effluents are increasing. But there is the lack of the data for wetlands because of the difficulty in long term monitoring. Such an aspect makes the proper use of wetland impractical. In this study for the purpose of generating a long term hydrologic data, the time series of storage amount for Upo, Mokpo, Sajipo, and Jjokjibeol in Topyeong watershed is simulated using SWAT model. Based on the SWAT-Topyeong model involved in several scenarios for constructing new washlands in Topyeong watershed, the temporal behavior of new washlands is analyzed. It is also revealed that the constructed washland can affect the Upo in some degrees.

• Membrane and Water Treatment
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• v.14 no.2
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• pp.95-106
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• 2023

In the developing country like India, groundwater is the main sources for household, irrigation and industrial use. Its contamination poses hydro-geological and environmental concern. The hazardous waste sites such as landfills can lead to contamination of ground water. The contaminants existing at such sites can eventually find ingress down through the soil and into the groundwater in case of leakage. It is necessary to understand the process of migration of pollutants through sub-surface porous medium for avoiding health risks. On this backdrop, the present paper investigates the behavior of pollutants' migration through porous media. The laboratory experiments were carried out on a soil-column model that represents porous media. Two different types of soils (standard sand and red soil) were considered as the media. Further, two different solutes, i.e., non-reactive and reactive, were used. The experimental results are simulated through numerical modeling. The percentage variation in the experimental and numerical results is found to be in the range of 0.75- 11.23 % and 0.84 - 1.26% in case of standard sand and red soil, respectively. While a close agreement is observed in most of the breakthrough curves obtained experimentally and numerically, good agreement is seen in either result in one case.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.10 no.4
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• pp.159-171
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• 1990

The purpose of this study was development and application of a multiple box model for long term prediction and control of water quality in estuary reservoir. The model was composed of one main model and two sub models for hydrology and water quality. Water quality constituents for modeling were temperature, chlorophyll-a, BOD, DO, N, and P. The model had been applied to Asan reservoir, and the reservoir had been devided into three boxes-two boxes for a upper layer and one box for a lower layer-to represent stratification. The model appeared satisfactory in representing long term trend of water quality variations by comparing measured and simulated results. According to the application of the model to study alternatives for water quality improvement to deal with increase in future pollution load, use of non-phosphorous detergent for chlorophyll-a, advanced sewage treatment for BOD and T-N, reduction of livestock waste for T-P were evaluated as more effective ones than any others, respectively.

• Journal of the Korean Society of Groundwater Environment
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• v.3 no.2
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• pp.51-59
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• 1996

In case waste disposal site is to be constructed close to the underground facilities such as LPG storage cavern which is completely maintained by groundwater pressure, it is generally requested that the possibility on leachate contamination of cavern area be reviewed and the countermeasure, if it is estimated cavern area is severely affected by leachate, be taken into consideration. Prediction was performed and leachate control plan was made using by analytical and the numerical analysis on the leachate migration which is likely to happen at the area between the proposed waste disposal site and the underground LPG storage cavern located at the U petrochemical complex. Analytical solutions were obtained by the conservative mass advection-diffusion equation and the effect of advection and dispersion factor on the leachate migration was reviewed through peclet number calculation and the functional relationship between the factors and leachate transport velocity was established, which leads to enable us to predict the leachate transport velocity without difficulties when different parameters (factors) are used for analytical solution. Numerical solutions were obtained by FEM using AQUA2D which is for the simulation of groundwater flow and contaminant transport. 3-D discrete fracture models were simulated and fracture flow analysis was performed and feasibility study on the water-curtain system was conducted through the fracture connectivity analysis in rock mass. As results of those analyses, it was interpreted that the leachate would trespass on the LPG storage cavern area in 30 years from the proposed wate disposal site and the vertical water-curtain system was effective mathod for the prevention of leachate's migration further into the cavern area.

• Korean Journal of Mineralogy and Petrology
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• v.36 no.1
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• pp.19-32
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• 2023

This study was conducted to remove fluorine (F) (initial concentration of 9.5 mg/L) from leachate of reclaimed mine waste dump site via different methods: (1) co-precipitation using Ca-based materials; (2) adsorption using activated carbon and fly ash; and (3) coagulation and sedimentation using alum. The F removal efficiencies of each case were estimated as 65.6% (Ca co-precipitation), 27.9% (adsorption of activated carbon), 71.5% (adsorption of fly ash), and 96.6% (alum coagulation and sedimentation). In addition, the applicability of the continuous treatment process using alum coagulation was evaluated by lab-scale experiments using simulated mine drainage containing F of lower (6.4 mg/L) and higher (15.7 mg/L) concentrations, and it was confirmed that the treatment of both cases met the domestic standard (below 3 mg/L) for discharged water in clean areas. Furthermore, the results of bench-scale field tests indicated that the water quality standard of discharged water could be satisfied with the proper operation and management of the process.

• Clean Technology
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• v.23 no.2
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• pp.163-171
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• 2017

Currently, researches on recycling and reuse of waste energetic materials have recently gained a great attention from advanced countries due to ever tightening environmental regulations. In this study, as a part of a recycling technology, the experiments and dynamic simulation of simulated moving bed (SMB) process were performed to efficiently separate TNT and RDX from their mixture, which are main components of ammunition. In order to determine the operation zone of SMB process, the retention times of TNT and RDX were measured using HPLC at different flow rates and the adsorption equilibrium of each component was obtained by using a moment method. According to the adsorption equilibrium and the triangle theory of SMB process, four operation points were determined and separation experiments were carried out by the SMB process using the solvent consisting of acetonitrile and water. Two different mixing ratios (6:4 and 1:1) of acetonitrile and water were chosen for the experiment due to the great impact of mixing ratio of the solvent on separation. The performance of SMB process was evaluated by purity, recovery, productivity and solvent consumption. Pure TNT and RDX were successfully obtained from the SMB process and the dynamic simulation for the SMB process agreed well with the experimental results. Therefore, the dynamic model could be applied for predicting the dynamic behavior of the SMB process and designing a large scale SMB process.

• Korean Journal of Environmental Agriculture
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• v.19 no.3
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• pp.218-222
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• 2000

Wasted${\cdot}$rested mine areas give lots of effect on around-environmental changes after mining development. Leaching water at reclaimed land has been eluted from the solid components through physical, chemical, biological procedures by waters percolated through reclaimed site. The element analysis of waste tungsten ore tailing, leaching water analysis and removal of heavy metal by zeolite were performed to investigate the influent of acid rain on the released contents of H. M. The heavy metal contents in leaching water were determined to be As $1.21\;{\sim}\;1.54\;ppm$, Pb $0.11\;{\sim}\;0.15\;ppm$ and $SO_4\;^{2-}$ was $302\;{\sim}\;378ppm$. As deionized water and simulated acid rain (pH 3,4) were percolated through columns packed tungsten ore tailing, the amount of Mn, Na, Ca which were dissolved by pH4 solution was higher than those by distilled water. However, W and Mo were eluted easily by high pH solution. The change of heavy metal concentration by column experiment packed zeolite was effective a little because heavy metals were adsorved much more by zeolite.

• Journal of Soil and Groundwater Environment
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• v.16 no.4
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• pp.1-9
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• 2011

Bentonite has been generally used as vertical cutoff barrier material and reported to have several problems regarding its low workability, drying shrinkage cracking by particle cohesion, and ineffective waterproof ability under sea water condition. In this study, the particle sealant, the furnace slag coated by the mixture of bentonite, sepiolite and guargum, was developed to compensate these weak points and the hydraulic conductivity of the particle sealant was evaluated. Drying shrinkage cracking and swelling index was estimated to find the optimal mixing ratio of bentonite, sepiolite and guargum. The hydraulic conductivity of the particle sealants having different amount of sealant (bentonite-sepioliteguargum mixture) coating the furnace slag was estimated using the rigid wall permeameter and flexible wall permeameter. The results showed that drying shrinkage cracking was not found in the bentonite-sepiolite mixture with 20% sepiolite contents and the results from free swelling tests for the sealant having 1 : 0.025, 1 : 0.05 and 1 : 0.075 of weight ratios of bentonite-sepiolite mixture and guargum under simulated sea water condition were higher than those for the bentonitesepiolite mixture without guargum under tap water condition. These three sealants were coated on the furnace slag with 50% and 60% of sealant in the particle sealant and the hydraulic conductivity was estimated. In the cases of the particle sealants having 20% sepiolite in the bentonite-sepiolite mixture and 1 : 0.075 weight ratio of the bentonite-sepiolite mixture and guargum, the hydraulic conductivity from the rigid wall permeameter was below $1.0{\times}10^{-7}$ cm/sec under simulated sea water condition. The hydraulic conductivity of the particle sealant having $1.0{\times}10^{-6}$~$1.0{\times}10^{-7}$ cm/sec by the rigid wall permeameter was estimated using the flexible wall permeameter and found to be below $1.0{\times}10^{-7}$ cm/sec.

• Journal of Soil and Groundwater Environment
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• v.10 no.4
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• pp.54-61
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• 2005

An aquifer thermal energy storage (ATES) system can be very cost-effective and renewable energy sources, depending on site-specific parameters and load characteristics. In order to develop the ATES system which has certain hydrogeological characteristics, understanding the thermohydraulic process of an aquifer is necessary for a proper design of an aquifer heat storage system under given conditions. The thermohydraulic transfer for heat storage was simulated according to two sets of simple pumping and waste water reinjection scenarios of groundwater heat pump system operation in a two-layered aquifer model. In the first set of the scenarios, the movement of the thermal front and groundwater level was simulated by changing the locations of injection and pumping wells in a seasonal cycle. However, in the second set the simulation was performed in the state of fixing the locations of pumping and injection wells. After 365 days simulation period, the shape of temperature distribution was highly dependent on the injected water temperature and the distance from the injection well. A small temperature change appeared on the surface compared to other simulated temperature distributions of 30 and 50 m depths. The porosity and groundwater flow characteristics of each layer sensitively affected the heat transfer. The groundwater levels and temperature changes in injection and pumping wells were monitored and the thermal interference between the wells was analyzed to test the effectiveness of the heat pump operation method applied.